• 한국환경과학회지
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• 제29권4호
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• pp.395-402
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• 2020

This study was conducted to analyze seasonal variations of de-icing salt ions harvested from soils and plants according to salt damage of Pinus densiflora f. multicaulis, a evergreen conifer, on roadsides. Pinus densiflora f. multicaulis was divided into three groups referred to SD, ND, and WD (serious salt damage (SD) = 71-100%, normal salt damage (ND) = 31-70%, and weak salt damage (WD) = 0-30%) based on the degree of visible foliage damage, and measured acidity (pH), electrical conductivity(EC), and de-icing salt ions (K⁺, Ca²⁺, Na⁺, and Mg²⁺) harvested from soils and plants. The results indicated that acidity, electrical conductivity, and de-icing salt ions of soils and plants were significantly affected by seasonal variation and salt damage. In addition, a strong positive liner relationship was observed in plants between the concentration of de-icing salts and salt damage in spring, while the relationship among seasonal variation and salt damage in soil were not significant. The results from this study has important implications for the management of conifer species in relation to salinity and roadsides maintenance.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.507-510
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• 2005

In winter, a large amount of de-icing salts such as $CaCl_2$, NaCl have been used on highways for road safety. They make concrete structures deteriorated. In this study, the chloride diffusion of concrete in presence of de-icing salt was investigated. The diffusion coefficient of chloride in presence of $CaCl_2$ solution was larger than in presence of NaCl solution. Therefore, it is necessary to assess chloride profile in presence of $CaCl_2$ by different way from the case in presence of NaCl solution or seawater.

• 한국도로학회논문집
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• 제19권4호
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• pp.9-18
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• 2017

PURPOSES : This study evaluates the reasonableness of the recommended amount of deicing chemicals based on historical data for snow removal. The result can be used to aid decision-making for the reservation of cost-effective de-icing chemicals. METHODS : First, the recommended amount of de-icing chemical to use and historical usage data were evaluated to identify specific usage characteristics for each region. Road maintenance length and snow-removal working days were analyzed over the past five winter seasons. Next, differences in the recommended amount of chemical to use and actual use were compared using the Kolmogorov-Smirnov test. Last, the two types of data were analyzed using a chi-square test to verify if the two distributions of variation pattern are statistically significant. We found that there are significant differences between the data from each region during the past five winter seasons. RESULTS : The results showed that the equation for calculating the amount of de-icing chemical to use appears to be revised. CONCLUSIONS : The results imply that the equation for calculating the amount of de-icing chemical to apply as a national standard is very important when the public agency makes decisions related to snow-removal.

• 한국지하수토양환경학회지:지하수토양환경
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• 제9권4호
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• pp.15-23
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• 2004

제설제를 살포하는 것은 도시지역에서 자동차가 겨울철에 운행하는 동안 안전한 운전을 가능하게 한다. 하지만 많은 양의 제설제 (염화칼슘과 소금)를 사용하는 것은 심각한 환경문제를 발생시키고 도로변 퇴적물에 함유된 중금속의 거동을 변화시키게 되며, 결과적으로 염소이온과의 착이온형성에 기인된 중금속의 이동성을 증가시키게 될 것이다. 제설제의 농도가 중금속 (카드뮴, 아연, 구리, 납, 비소, 니켈, 크롬, 코발트, 망간 및 철)의 용출특성과 이동성에 미치는 영향을 연구하기 위하여, 서울시 주요 도로변에서 채취한 퇴적물을 대상으로 제설제의 농도 (0.01-5.0M)를 변화시켜 용출실험을 수행하였다. 연구결과, 도로변 퇴적물에 함유된 아연, 구리 및 망간은 쉽게 용해되어 이동되는 반면, 크롬과 코발트는 도로변 퇴적물에 강하게 고정되어 있음을 관찰하였다. 이번 용출실험에서 검출된 아연 (최대 $118.6{\mu}g/g$). 구리 (최대 $44.9{\mu}g/g$) 및 망간 (최대 $42.2{\mu}g/g$)의 함량은 상대적으로 높은 함량이었다. 제설제는 흡착 (또는 침전)된 금속과 용해된 금속 사이의 분배를 감소시키며, 이는 제설제가 용해된 눈 녹은 물에 용존 중금속 함량을 증가시키게 되어 결과적으로 지표수의 수질을 악화시키게 된다. 또한, 도로에 제설제를 살포하는 것에 의해 중금속이 지하수까지 침투되어 지하수를 오염시키게 될 것이다.

• 한국구조물진단유지관리공학회 논문집
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• 제11권2호
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• pp.85-92
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• 2007

콘크리트 노출 바닥판은 88 고속도로, 호남고속도로 확장, 제1중부고속도로 등의 1980년대에 건설된 고속도로 교량에 널리 적용되었다. 약 20년 정도 공용한 후에 콘크리트 노출 바닥판의 상태를 평가한 결과, 상당수의 교량들이 특별한 유지관리비가 소요되지 않고 공용중이다. 이러한 이유로 시공성, 유지관리 그리고 구조적인 관점에서 기존 콘크리트 노출 바닥판에 대한 공용성에 대한 재평가가 이루어지고 있다. 이러한 일환으로 콘크리트 노출 바닥판의 주요 손상원인 중의 하나인 철근 부식에 의한 박락을 유발시키는 제설 염화물에 침투 특성을 파악하고 바닥판의 수명을 평가하고자 고속도로 상에 공용중인 콘크리트 노출 바닥판에서 코어를 채취하여 깊이별 염화물을 측정하여 표면 염화물량 및 겉보기 확산계수를 구하였다.

• 한국구조물진단유지관리공학회 논문집
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• 제21권6호
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• pp.132-139
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• 2017

한랭지역의 동절기 교통안전을 위하여 제설제 살포가 다량으로 이루어지고 있는데, 그 살포량도 매년 증가하고 있는 실정이다. 일반적으로 사용되는 제설제는 염화칼슘($CaCl_2$), 염화나트륨(NaCl)과 같은 염화물계가 주성분으로, 국내에서는 대부분 염화칼슘을 주로 사용하고 있고, 미국이나 일본의 경우는 소금인 염화나트륨으로 모두 염소이온을 포함하고 있다. 염화칼슘 제설제가 포함하고 있는 염화물 때문에 제설제 살포시 염화물은 도로 구조물로 침투하여 염해에 의한 철근부식을 유발하여 실제 포장이나 손상된 교량 구조물 내에서의 구조적 성능저하를 야기하고, 동절기 동해와 함께 복합적으로 작용하여 표면 스케일링을 발생시키며, 특히 살포제에 의한 수질 오염과 같은 심각한 부작용을 초래하고 있다. 또한 콘크리트 도로포장 표면이 염화칼슘 제설제 사용 후 나타나는 열화현상으로 인하여 기존의 염화칼슘 제설제의 경우 시각적으로 교통 외관상 문제를 가속화시키고 있다. 따라서, 본 연구에서는 산업부산물인 폐유기산과 칼슘계부산물을 반응시켜 친환경 액상 제설제를 제조하고 그 특성을 분석하여 도로시설물에 적용가능성을 검토하였다.

• 한국환경과학회지
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• 제26권8호
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• pp.993-998
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• 2017

De-icing salts applied to roads during winter enable safe driving conditions. However, these salts are eventually displaced to roadside areas at which they can negatively impact soil, vegetation, and water resources. This purpose of this study is to determine the relationship between foliar damage ratio (NY = 0-25%, SY = 26-50%, CY = 51-75%) on roadside trees (Ginko biloba) and seasonal impact of de-icing salts on soil and vegetation. Thirty roadside trees were selected at 8 m intervals between the Konkuk and Judeok intersections in Chung-ju city. The results reveal that seasonal soil acidity is relatively alkaline for foliar damage ratio of Ginko biloba was CY compared to NY. Also, electronic conductivity of each seasonal sampling was recorded as high in winter and spring, whereas the opposite trend is observed in summer. Various plants species were identified in abundance under roadside trees within NY roadside sections. These same species were observed in reduced numbers within CY sections. Strong negative correlations were identified between foliar damage ratio on roadside trees and vegetation. This relationship may be a method to use in predicting the accumulation of de-icing salt and visible injuries on roadside trees.

• 한국구조물진단유지관리공학회 논문집
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• 제25권5호
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• pp.102-113
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• 2021

「시설물의 안전 및 유지관리 실시 세부지침(성능평가편)」의 내구성능 평가에서 열화환경 평가항목으로 제시된 제설제 및 비래염분에 의한 염해환경, 동해환경이 국내 국도 상 콘크리트 도로시설물의 염화물 침투특성에 미치는 영향을 살펴보았다. 강원 고성, 서울, 경기 고양, 부산에 위치한 교량 총 4개소, 강원권 방호울타리 4개소, 부산권 방호울타리 3개소 및 옹벽 1개소를 대상 시설물로 선정하였으며, 제설제에 의한 직접·간접적인 염해환경, 해안거리 및 교각 높이별 비래염분에 의한 염해환경에서 염화물 침투특성을 분석하였다. 분석 결과, (1) 제설제 살포일수(강설일수)에 따른 지역별 특성이 명확하게 구분되었고, (2) 바닥판 관통 누수 혹은 신축이음부를 통한 누수 등이 발생한 경우 침투 염화물량이 유의미한 수준까지 증가하였으며, (3) 부산 해안가에 위치한 교량의 경우 높이 20m까지 비래염분의 영향권에 해당함을 확인하였다. 이로부터, 동일한 시설물이라도 노출된 열화환경, 부재의 위치 및 높이, 열화진전상태에 따라 염화물 침투특성이 달라지기 때문에 시설물 점검 시 점검대상 부재 및 위치의 선정이 매우 중요함을 확인하였으며, 국내 지역별 및 부재별 열화환경에서의 염화물 침투특성에 관한 데이터베이스를 구축한다면 콘크리트 시설물에 대한 선제적인 내구성능 관리가 가능할 것으로 기대된다.

• 한국조경학회지
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• 제35권6호
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• pp.29-36
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• 2008

This study examined the de-icing agents' stresses on Pinus strobus and Pinus thunbergii by chlorophyll fluorescence analysis. The assumption of this study was that photosynthetic efficiency was changed by de-icing agents applied onto highways in winter by altering the concentration of the de-icier, types of de-icer and leaf surface coating liquid application. The practical purpose of this study was to investigate the de-icing gents stresses on Pinus strobus by the highway area where de-icing agents were used frequently and to discover out minimizing stratages to prevent further damages. or this simulation study, a sample plot was established in Bogae-myeon, Anseong, Gyeonggi-do and Pinus strobus and Pinus thunbergii were planted for the examination in April, 2005. Five types of de-icing agents - NaCl, $CaCl_2$, T product(NS40:low cWoride de-icer type), NaCl+$CaCl_2$ and T product+$CaCl_2$ - were selected and the their concentration was altered to 0%, 5%, and 9%. Five types of de-icing agents were applied to both trees treated by a leaf surface coating liquid and trees not treated by leaf surface coating liquid. For the fluorescence analysis, the leaf surface coating liquid, which was diluted by 10 times, was sprkinkled onto the two tree species three days prior to gathering samples. Sample leaves from the two tree species were gathered at 10 o'clock in the morning of mid-August, 2006 and brought to the laboratory within three hours to be dipped in different concentrations (0%, 5%, or 9%) of the five de-icing agents for two minutes. Then the eaves were placed on the filter paper dipped in each solution on a petri dish, sealed with polyethylene film and kept in a growth chamber at $22^{\circ}C$ for 72 hours. Out of the growth chamber, the leaves were treated with a chorophyll fluorescence reaction analyzer for 30 minutes to measure the initial light acceptance rate(Fo), maximum light acceptance ate(Fv/Fm), light acceptance usage(F' q/F' m) and optical electron delivery coefficient(qP). As a result, Pinus strobus' initial light acceptance rate(Fo) decreased as T product and NaCl increased in concentration, and $Cal_2$ did not reduce much with the eaf surface coating liquid application. Maximum light acceptance rate(Fv/Fm) and light acceptance usage(F' q/F' m) decreased sharply as T product and NaCl increased in concentration and NaCl+$CaCl_2$ and T product+$CaCl_2$ did not reduce much with leaf surface coating liquid application. Optical electrons delivery coefficient (qP) decreased as T product increased in concentration on trees without the leaf surface coating liquid application and all other de-icing agents did not show much reduction. As for Pinus thunbergii, the initial light acceptance rate(Fo) decreased as T product increased in concentration, but the maximum light acceptance rate(Fv/Fm) was not reduced much by changes in concentration. light acceptance usage(F' q/F' m) decreased as NaCl increased in concentration and optical electron delivery coefficient(qP) decreased as NaCl increased in concentration in both with and without leaf surface coating liquid application. In conclusion, it was possible to plant Pinus strobus if spraying leaf surface coating liquid or cleaning deicing salt to prevent the damage caused by deicing agents was more economical than replacing the trees. If not, it was better to plant Pinus thunbergii. Another way to decrease the deicing gents stresses of landscape plants would be planting the trees further away from the roads even though it might take longer period to display its planting functions.

• 한국환경복원기술학회지
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• 제21권4호
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• pp.1-10
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• 2018

Use of de-icing salts results in accumulation of high concentrations of ions on roadside soils and tree. The purpose of this study isto determine translocation of seasonal impact of exchangeable cations originating from de-icing salt on roadside surface soil-plant influenced by the intensity of foliar damage (NY = 0-25%, SY = 26-50%, CY = 51-75%) of trees. This paper investigated the concentration of four exchangeable cations ($K^+$, $Ca^{2+}$, $Na^+$, and $Mg^{2+}$) on the roadside surface soil. The tree (Ginko biloba) samples were collected from the Konkuk and Judeok intersections in Chung-ju city. The sequential extraction procedure was applied to 120 soil samples of the soilsurface and 30 tree samples. Four cation exchange ions were determined by ICP-OES. The content of four exchangeable cations present on roadside soil was found to be the lowest in NY but highest in CY from tree pits in the order of NY < SY < CY. Especially, the results were apparent during spring time compared to other seasons. Soil collected from tree pits had the highest concentration of $Ca^{2+}$ possibly due to a higher volume of traffic on those streetsresulting in splashing of more calcium chloride ($CaCl_2$). The analysis of three exchangeable cations ($K^+$, $Mg^{2+}$, and $Na^+$) in the tree leaves revealed higher levels than roadside surface soil when foliar damage ratio increased in the order of NY < SY < CY in summer. In addition, a strong positive linear relationship was observed between the concentration of exchangeable cations in soil and trees. It is hypothesized that the results of this study can be a valuable baseline for managing de-icing salt on roadside soil and trees, in order to mitigate the salt stress that can damage the roadside soil and trees.