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The Effects of SO2 and NH3 on the N2O Reduction with CO over MMO Catalyst (MMO 촉매와 CO 환원제에 의한 N2O 분해에서 SO2 및 NH3 영향 연구)

  • Chang, Kil Sang;You, Kyung-Chang
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.653-657
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    • 2009
  • Nitrous oxide is a typical greenhouse gas which is produced from various organic or fossil fuel combustion processes as well as chemicals producing plants. $N_2O$ has a global worming potential of 310 times that of $CO_2$ on per molecule basis, and also acts as an ozone depleting material in the stratosphere. However, its removal is not easy for its chemical stability characteristics. Most SCR processes with several effective reducing agents generally require the operation temperature higher than $450^{\circ}C$, and the catalytic conversion becomes decreased significantly when NOx is present in the stream. Present experiments have been performed to obtain basic design data of actual application concerning the effects of $SO_2$ and $NH_3$ on the interim and long term activities of $N_2O$ reduction with CO over the mixed metal oxide (MMO) catalyst derived from a hydrotalcite-like compound precursor. The MMO catalysts used in the experiments, have shown prominent activities displaying full conversions of $N_2O$ near $200^{\circ}C$ when CO is introduced. The presence of $SO_2$ is considered to show no critical behavior as can be met in the $NH_3$ SCR DeNOx systems and the effect of $NH_3$ is considered to play as mere an impurity to share the active sites of the catalysts.

The Impact of Monsoon Rainfall on the Water Quality in the Upstream Watershed of Southern Han River (하절기의 집중강우가 남한강 상류수계 수질에 미치는 영향)

  • Park, Sung-Min;Shin, Yoon-Keun
    • Korean Journal of Ecology and Environment
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    • v.44 no.4
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    • pp.373-384
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    • 2011
  • The objective of this was to determine how the seasonal intensive rainfall influenced the water quality, and to analyze the long-term temporal trend of water chemistry and spatial heterogeneity in the upstream watershed of Southern Han River using water quality dataset from 1997 to 2007. The largest seasonal variability in most parameters occurred during the two month July and August and there were closely associated with a large spate of summer monsoon rain. Total phosphorus (TP), chemical oxygen demand (COD), and suspended solids (SS) were greater during summer than any other seasons, and had a direct correlation with precipitation (r>0.4, p<0.01, n-120). In addition, dissolved oxygen (DO) had and inverse function with precipitation (r=-0.542, p<0.01). Overall, the data of total phosphorus (TP) and suspended solids (SS) showed that water quality was worst in Site I1, compared to the others. This was due to continuous effluents from the highlands' fields and cattle farms within the upstream area of Doam lake (Song stream). Based on the overall dataset, an efficient water quality management is required in the highlands and farms areas for better water quality with precipitation (r.0.4, p<0.01, n=120).

The Nonlinear Motions of Cylinders(I) (주상체의 비선형 운동(I) -강제동요문제, 조파저항문제-)

  • H.Y. Lee;J.H. Hwang
    • Journal of the Society of Naval Architects of Korea
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    • v.29 no.4
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    • pp.114-131
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    • 1992
  • In the present work, a two-dimensional boundary-value problem for a large amplitude motion is treated as an initial-value problem by satisfying the exact body-boundary and nonlinear free-surface boundary conditions. The present nonlinear numerical scheme is similar to that described by Vinje and Brevig(1981) who utilized the Cauchy's theorem and assumed the periodicity in the horizontal coordinate. In the present thesis, however, the periodicity in the horizontal coordinate is not assumed. Thus the present method can treat more realistic problems, which allow radiating waves to infinities. In the present method of solution, the original infinite fluid domain, is divided into two subdomains ; ie the inner and outer subdomains which are a local nonlinear subdomain and the truncated infinite linear subdomain, respectively. By imposing an appropriate matching condition, the computation is carried out only in the inner domain which includes the body. Here we adopt the nonlinear scheme of Vinje & Brevig only in the inner domain and respresent the solution in the truncated infinite subdomains by distributing the time-dependent Green function on the matching boundaries. The matching condition is that the velocity potential and stream function are required to be continuous across the matching boundary. In the computations we used, if necessary, a regriding algorithm on the free surface which could give converged stable solutions successfully even for the breaking waves. In harmonic oscillation problem, each harmonic component and time-mean force are obtained by the Fourier transform of the computed forces in the time domain. The numerical calculations are made for the following problems. $\cdot$ Forced harmonic large-amplitude oscillation(${\omega}{\neq}0,\;U=0$) $\cdot$ Translation with a uniform speed(${\omega}=0,\;U{\neq}0$) The computed results are compared with available experimental data and other analytical results.

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Literature Review of Key Success Factors of Management Innovation Actions in Domestic - Focused on Six Sigma, TQM, Lean Six Sigma, ERP, TPM, BPR, Project Management, System Engineering - (국내 경영혁신 활동의 핵심 성공요인 문헌 연구 - 6시그마, TQM, 린 6시그마, ERP, TPM, BPR, Project Management, System Engineering 중심으로 -)

  • Mun, JeOk;Yoon, SungPil
    • Journal of Korean Society for Quality Management
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    • v.44 no.3
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    • pp.639-648
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    • 2016
  • Purpose: Existing precedent studies include success factors of individual management innovation activities constantly. However, those studies have limitations about the common key success factors of individual management innovation activities. Methods: For this study, we investigate the key success factors using literature research of the most typical management innovation activities adopted and implemented by many companies in Korea, such as 6sigma, TQM, Lean 6sigma, ERP, TPM, BPR, Project Management, System Engineering. Factors emerging repeatedly was combined into common factors and inherent factors that are necessary for the success of individual management innovation activities are designated to essential factors. Results: 'Essential factors for Six Sigma' consist of 5 items. Black belt operating system, personnel management system linkage, the correct management of the data, perform improvement projects associated with financial performance financial result, linked to financial performance improvement project, project progress management. 'Essential factors of TQM' are arranged 4 items. Quality team's independence and role, goal-setting, Quality Information System, corporate's philosophy of quality first. 'Essential factors of Lean Six Sigma' are the selection of value stream which is based on the customer needs and the value creation and identify the project based on the selected value in the company. 'Essential factors of ERP' are investigated 6 items. Ongoing system maintenance and upgrades, the measurement and support of user satisfaction, the operating systems and the policies for the maintenance, IT infrastructure, change adaption condition monitoring, focusing on improving business performance. 'Essential factors for TPM' are arranged 4 items. Motivated and energetic Bottom-Up, CEO's recognition of the importance facility management, long-term perspective of necessity and ongoing patience. 'Essential factors for BPR' are the pursuit of change process and the staff's sense of crisis management. 'Essential factors for Project Management' are the strategy that reduce the risk management skills through risk management and the understanding and organized management for the project participant's needs. 'Essential factors for System Engineering' consist of 2 items. The first is the design for the best balanced system with pre-analysis about the compromise the cost, schedule and the performance. The second is the analysis of large problem into small problems which can solved. We have found the solution considering components of the interface through the systematic perspective. Conclusion: Common factors and essential factors presented in this study will properly help to introduce the individual management innovation activities for the each business sector and implement management innovation. After this study, new literature research that reflect new studies should accomplish steadily.

Investigation of the Characteristic Velocity of Geomorphologic Instantaneous Unit Hydrograph (지형형태학적 순간단위도의 특성속도에 대한 고찰)

  • Kim, Sang-Dan;Yu, Cheol-Sang;Yun, Yong-Nam
    • Journal of Korea Water Resources Association
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    • v.33 no.3
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    • pp.315-330
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    • 2000
  • The GIUH (Geomorphologic Instantaneous Unit Hydrograph) is to be applied to the ungauged or insufficiently gauged basins. For tIris purpose, an accurate estimation of the charactenstlc velocity is one very important part, but any proper method for this has not been developed yet. In case that we have enough rainfall and runoff clata, the estimation of the characteristic velocity may be an easy job, but it is out of the purpose of the GIUH. Remindmg that the purpose of GIUH the characterisbc veloclty should be estimated based on the geomorpholog1c analysis and also be snnple for easy apphcation. In tIris research analysis cmd application of the GruH was given to several sub-basins in Wi-stream river basin, Gono, Donggok and Hyoryung. After deriving the characteristic velocity througn a optimizatlOn process with real data, it is compared w1th several velOCIties der1ved from geOlnoI1Jhoclimatic instantaneous unit hydrograph theory and several other concentration time formulae. The estimated charactenstic velocities using Kerby, Kim, KInematic Wave, and Brasby- Williams formulae found to g1ve the appropriate results. Hmvever, as the Kerby, and the Kinematic Wave require user's decision of the IvIanning's n value, the K1m and the Braby-Williams seem to be more applicable and recommended as characteristic velocity formula.

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Water temperature assessment on the small ecological stream under climate change (기후변화에 따른 소하천에서의 수온 모의연구)

  • Park, Jung Sool;Kim, Sam Eun;Kwak, Jaewon;Kim, Jungwook;Kim, Hung Soo
    • Journal of Wetlands Research
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    • v.18 no.3
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    • pp.313-323
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    • 2016
  • Water temperature affects physical and biological processes in ecologies on river system and is important conditions for growth rate and spawning of fish species. The objective of this study is to compare models for water temperature during the summer season for the Fourchue River (St-Alexandre-de-Kamouraska, Quebec, Canada). For this, three different models, which are CEQUEAU, Auto-regressive Moving Average with eXogenous input and Nonlinear Autoregressive with eXogenous input, were applied and compared. Also, future water temperature in the Fourchue river were simulated and analyzed its result based on the CMIP5 climate models, RCP 2.6, 4.5, 8.5 climate change scenarios. As the result of the study, the water temperature in the Fourchue river are actually changed and median water temperature will increase $0.2{\sim}0.7^{\circ}C$ in June and could decrease by $0.2{\sim}1.1^{\circ}C$ in September. Also, the UILT ($24.9^{\circ}C$) for brook trout are also likely to occurred for several days.

Sediment Properties and Long-term Bed Change of Munsancheon (문산천의 유사특성 및 장기하상변동 예측)

  • Lee, Jae-Geun;Ahn, Jae-Hyun
    • Journal of Wetlands Research
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    • v.13 no.2
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    • pp.329-341
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    • 2011
  • This study was conducted with the national river, Munsancheon, which is located in Paju-si, Gyeonggi-do. The sediment discharge of Munsancheon was directly measured to analyze the sediment characteristics, and the results were used in the numerical model to predict the long-term river bed variation. The flow-total sediment discharge relation was derived using the measured total sediment discharge, and the results were compared with the total sediment discharge that was calculated using the existing prediction formula to derive a proper sediment discharge prediction method. In the actual measurements, the total annual sediment discharge was 5,478 ton/year, and the specific sediment discharge was 29.23 ton/$km^2$/year. The Ackers & White formula resulted in the values very close to the actual measurements. With the actual sediment discharge, geographical and hydrologic data as the input variables, HEC-6 and GSTARS models were comparatively analyzed. The test results showed that the HEC-6 model is suitable for the reliable prediction of the long-term river bed variation. Accordingly, the model was used for the long-term river bed variation prediction in this study. In the case of Munsancheon, deposition was continued in the downstream area and erosion occurred in the upstream area on the whole. It was expected that the stream would be stabilized in the river bed condition of 20 years later. The river bed variation was within 1 m, which was at the significance level. In the downstream area that is influenced by tide, however, the accumulation was continuously increasing within the section 2,000-7,000 m from the outlet. It seems that this should be considered in establishing the river management plans.

Spatial Patterns of Urban Flood Vulnerability in Seoul (도시 홍수 취약성의 공간적 분포 - 서울 지역을 중심으로 -)

  • Kim, Jisoo;Sung, Hyo Hyun;Choi, Gwangyong
    • Journal of the Korean association of regional geographers
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    • v.19 no.4
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    • pp.615-626
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    • 2013
  • In this study, spatial patterns of the urban flood vulnerability index in Seoul are examined by considering climate exposure, sensitivity, and adaptability associated with floodings for recent 5 year (2006~2010) period by the smallest administrative unit called Dong. According to the results of correlation analyses based on the IPCC(Intergovernmental Panel on Climate Change)'s vulnerability model, among many variables associated with urban flooding, rainwater tank capacity, 1-day maximum precipitation and flood pumping station capacity have statistically-significant, and relatively-high correlations with the number of flood damage in Seoul. The flood vulnerability map demonstrates that the extensive areas along Anyang and Joongnang streams show relatively high flood vulnerability in Seoul due to high sensitivity. Especially in case of Joongnang stream areas, climatic factors also contribute to the increase of flood vulnerability. At local scales, several Dong areas in Gangdong-gu and Songpa-gu also show high flood vulnerability due to low adaptability, while those in Gangnam-gu do due to high sensibility and climate factor such as extreme rainfall events. These results derived from the flood vulnerability map by Dong unit can be utilized as primary data in establishing the adaptation, management and proactive policies for flooding prevention within the urban areas in more detail.

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A Utility-Based Hybrid Error Recovery Scheme for Multimedia Transmission over 3G Cellular Broadcast Networks (3G 방송망에서의 효율적인 멀티미디어 전송을 위한 유틸리티 기반 하이브라드 에러 복구기법)

  • Kang Kyung-Tae;Cho Yong-Jin;Cho Yong-Woo;Cho Jin-Sung;Shin Heon-Shik
    • Journal of KIISE:Information Networking
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    • v.33 no.4
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    • pp.333-342
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    • 2006
  • The cdma2000 lxEV - DO mobile communication system provides broadcast and multicast services (BCMCS) to meet an increasing demand from multimedia data services. The servicing of video streams over a BCMCS network must, however, face a challenge from the unreliable and error-prone nature of the radio channel. The BCMCS network uses Reed-Solomon coding integrated with the MAC protocol for error recovery. We analyze this coding technique and show that it is not effective in the case of slowly moving mobiles. To improve the playback quality of an MPEG-4 FGS video stream, we propose the Hybrid error recovery scheme, which combines Reed-Solomon with ARQ, using slots which are saved by reducing the Reed-Solomon coding overhead. The target packets to be retransmitted are prioritized by a utility function to reduce the packet error rate in the application layer within a fixed retransmission budget. This is achieved by considering of the map of the error control block at each mobile node. The proposed Hybrid error recovery scheme also uses the characteristics of MPEG-4 FGS (fine granularity scalability) to improve the video quality even when conditions are adverse: slow-moving nodes and a high error rate in the physical channel.

Riparian Connectivity Assessment Using Species Distribution Model of Fish Assembly (어류군집의 종분포모형을 이용한 수변지역 연결성 평가)

  • Jeong, Seung Gyu;Lee, Dong Kun;Ryu, Ji Eun
    • Journal of Korean Society for Geospatial Information Science
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    • v.23 no.2
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    • pp.17-26
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    • 2015
  • River corridors facilitate dispersal and movement and prevent local extinction of species. As a result of stream restoration projects, which include installation of waterfront and flood control structures, the number of animals, which rely on river corridor, is decreasing. For the study, factors affecting fish assembly were extracted by a species distribution model with the fish data collected from the Seom River in Hoengseong County and City of Wonju, Ganwon Province, Korea between March to October 2013. The riparian connectivity was assessed using species richness and rarity. According to result of the field survey, there were 38 species and 7,061 individuals for fish. The analysis suggests the following. Firstly, factors affecting fish richness in species distribution model results are shown to be velocity, riffle, riparian width, and water width. The accuracy of the model proves to be suitable with the correlation coefficient of 0.83 and MAPE of 19.2%. Secondly, the low rarity area is shown to be straight streams in Jeon river near to Hongseong County and the high rarity area to be streams with large width, existing alluvial area at channel junction between Jeon river and Seom river. Thirdly, according to connectivity results, areas where weirs are installed or riparian buffer area is removed showed low connectivity. The areas where farmland near riparian and forest areas showed high connectivity. The results of this study can be utilized to improve current facilities and enhance connectivity as a restoration guide.