• Korean Chemical Engineering Research
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• v.47 no.4
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• pp.512-517
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• 2009

$SO_2$ concentrations in oxy-fuel combustion flue gases increases about three times as high as that of conventional air combustion system owing to the flue gas recirculation for the control of combustion temperature. So the desulfurization reaction is different from that of the conventional air combustion system due to exceptionally high $CO_2$ and $SO_2$ concentration. In this study, drop tube furnace(DTF) system was used to investigate the desulfurization characteristics of limestone in oxy-fuel combustion furnace. The experiments were performed under $O_2/CO_2$ atmosphere to examine the effect of operating variables such as reaction temperatures, Ca/S ratios and inlet $SO_2$ concentrations on the $SO_2$ removal efficiencies. $SO_2$ removal efficiency increased with reaction temperature, Ca/S ratio and inlet $SO_2$ concentration. And the addition of water vapor resulted in about 4~6% of increase in $SO_2$ removal efficiency.

• Journal of the Korean Society of Safety
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• v.30 no.1
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• pp.8-13
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• 2015

The experimental design methodology was applied in the drop tube furnace (DTF) to predict the various combustion properties according to the operating conditions and to assess the coal plant safety. Response surface method (RSM) was introduced as a design of experiment, and the database for RSM was set with the numerical simulation of DTF. The dependent variables such as burnout ratios (BOR) of coal and $CO/CO_2$ ratios were mathematically described as a function of three independent variables (coal particle size, carrier gas flow rate, wall temperature) being modeled by the use of the central composite design (CCD), and evaluated using a second-order polynomial multiple regression model. The prediction of BOR showed a high coefficient of determination (R2) value, thus ensuring a satisfactory adjustment of the second-order polynomial multiple regression model with the simulation data. However, $CO/CO_2$ ratio had a big difference between calculated values and predicted values using conventional RSM, which might be mainly due to the dependent variable increses or decrease very steeply, and hence the second order polynomial cannot follow the rates. To relax the increasing rate of dependent variable, $CO/CO_2$ ratio was taken as common logarithms and worked again with RSM. The application of logarithms in the transformation of dependent variables showed that the accuracy was highly enhanced and predicted the simulation data well.

• Journal of Energy Engineering
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• v.25 no.4
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• pp.53-61
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• 2016

Unburned Carbon(UBC) and NOx emissions from High-moisture coal and Dried coal were investigated in Drop Tube Furnace(DTF). When the same amount of the High-moisture coal and Dried coal were oxidized in DTF, the results show that UBC and NOx emissions of Dried coal case is higher than High-moisture coal case. As the moisture in coal decreases from 40% to 10%, the average gas temperature increases but the moisture concentration in DTF decreases. As the wall temperature increases from $900^{\circ}C$ to $1500^{\circ}C$, the UBC decreases and NOx emissions increases. Especially, the difference for UBC between High-moisture coal and Dried coal decreases with increasing wall temperature.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1994.05a
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• pp.22-27
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• 1994

6종류의 유연탄을 대상으로 석탄회분의 용융온도와 화학적조성을 측정하고, 대상탄 회분에 대해 Rs 값과 Fs 값을 계산해 봄으로써 각 탄들의 Slagging 성향을 알아보았다. 그리고, 이 자료만으로는 정확한 Slagging 성향의 예측이 어려우므로 분류층 가스화기의 조건을 모사한 DTF(Drop Tube Furnace : 이하 DTF)장치를 이용하여 온도와 체류시간을 달리하면서 생성되는 Slag의 화학적조성, 강도, 점착속도 등을 측정하여 Slagging 형태의 가스화기 운전에 있어서 최적조건을 제시하고자 한다.

• Journal of the Korean Society of Safety
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• v.31 no.4
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• pp.48-54
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• 2016

The prediction of various emissions from coal combustion is an important subject of researchers and engineers because of environmental consideration. Therefore, the development of the models for predicting pollutants very fast has received much attention from international research community, especially in the field of safety assessment. In this work, response surface method was introduced as a design of experiment, and the database for RSM was set with the numerical simulation of a drop tube furnace (DTF) to predict the spatial distribution of pollutant concentrations as well as final ones. The distribution of carbon dioxide in DTF was assumed to have Boltzman function, and the resulted function with parameters of a high $R^2$ value facilitates predicting an accurate distribution of $CO_2$. However, CO distribution had a difference near peak concentration when Gaussian function was introduced to simulate the CO distribution. It might be mainly due to the anti-symmetry of the CO concentration in DTF, and hence Extreme function was used to permit the asymmetry. The application of Extreme function enhanced the regression accuracy of parameters and the prediction was in a fairly good agreement with the new experiments. These results promise the wide use of statistical models for the quantitative safety assessment.

• Journal of the Korean Society of Combustion
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• v.4 no.2
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• pp.85-95
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• 1999

The objective of this study was to obtain basic data for the staged combustion toward the NOx reduction in coal combustion. Combustion and NOx emission/reduction were investigated by using DTF. NOx emission was decreased with decreasing air ratio and with increasing volatile content in coal. In particular, effective NOx reduction was achieved at high temperature at the onset of combustion with fuel rich condition.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2001.11a
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• pp.25-32
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• 2001

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.12
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• pp.963-969
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• 2014

Four coal sources that had different ash contents were evaluated in a drop tube furnace (DTF). Combustion experiments were conducted by using several sources with different particle sizes and excess air ratios under air-staging conditions to determine the optimized combustion conditions of high-ash coal, with an emphasis on the combustion efficiency and NOx emissions. The results show that the higher ash content results in a large amount of carbon remaining unburned, and that this effect is dominant when the largest particle size is used. Furthermore, the ash content of coal does affect the Char-NOx concentration, which decreases with the particle size. The results of this study suggest that an air-staged system can be useful to reduce the NOx emissions of high-ash coal and that control of the air stoichiometric ratio of the primary combustion zone (SR1) is effective for reducing NOx emissions, especially by considering unburned carbon contents.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.43-45
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• 2012

The effect of limestone characteristics on in-furnace desulfurization was experimentally investigated at hot gas combustion condition in a drop tube furnace (DTF). Flue gas was measured by Gas analyzer in order to figure out $SO_2$ content. The experiments were performed under excess sulfur 3000ppm condition to examine the effect of operating variables such as reaction temperatures, Ca/S ratios on the $SO_2$ removal efficiencies. The results show that the $SO_2$ removal efficiency increased with reaction temperature and Ca/S ratio increase. When considering the economics, $1200^{\circ}C$ and Ca/S ratio 2 condition is optimized to reduce $SO_2$ emission.

• Journal of Energy Engineering
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• v.18 no.4
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• pp.239-246
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• 2009

A fundamental investigation has been conducted on the combustion of single particle of a sub-bituminous coal char burning at different temperatures and residence times. The lab-scale test setup consisted of a drop tube furnace where gas temperatures varied from $900^{\circ}C$ to $1400^{\circ}C$. A calibrated two color pyrometer, mounted on the top of the furnace, provided temperature profiles of luminous particle during a char oxidation. An amount of char mass reacted during the reaction is measured with thermogravimetry analyzer by using an ash tracer method. As a result, mass and area reactivity as well as reaction rate coefficients are determined for the char burning at atmospheric pressure condition.