• Title/Summary/Keyword: DSC analysis

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A Study on Transformation of Dynamic DSC Results into Isothermal Data for the Formation Kinetics of a PU Elastomer

  • Ahn, WonSool
    • Elastomers and Composites
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    • v.53 no.2
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    • pp.52-56
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    • 2018
  • The present study examines the transformation of dynamic DSC data into the equivalent isothermal data for the formation kinetics of a polyurethane elastomer. The reaction of 2'-dichloro-4,4'-methylenedianiline (MOCA) with a PTMG/TDI-based isocyanate prepolymer was evaluated. DSC measurement was performed in the dynamic scanning mode with several different heating rates to obtain the reaction thermograms. Then, the data was transformed into the isothermal data through a procedure based on Ozawa analysis. The main feature of this procedure was the transformation of $({\alpha}-T)_{\beta}$ curves from dynamic DSC into $({\alpha}-t)_T$ curves using the isoconversional $(t-T)_{\alpha}$ diagram. Validity was discussed for the relationship between the dynamic DSC data and the transformed isothermal results.

Kinetic Analysis of Energetic Materials Using Differential Scanning Calorimetry (DSC를 이용한 고에너지 물질의 반응속도식 추출과 활용)

  • Kim, Yoocheon;Park, Jungsoo;Yang, Seungho;Park, Honglae;Yoh, Jai-Ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.1
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    • pp.33-41
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    • 2015
  • The kinetic analysis of energetic materials using Differential Scanning Calorimetry (DSC) is proposed. Friedman Isoconversional method is applied to DSC experiment data and AKTS software is used for analysis. The proposed kinetic scheme has considerable advantage over the standard method based on One-Dimenaionl Time to Explosion (ODTX). Reaction rate and product mass fraction simulation are conducted to validate extracted kinetic scheme. Also a slow cook-off simulation is implemented on $B/KNO_3$ for validating the applicability of the extracted kinetics scheme to a practical thermal experiment.

FE analysis of RC structures using DSC model with yield surfaces for tension and compression

  • Akhaveissy, A.H.;Desai, C.S.;Mostofinejad, D.;Vafai, A.
    • Computers and Concrete
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    • v.11 no.2
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    • pp.123-148
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    • 2013
  • The nonlinear finite element method with eight noded isoparametric quadrilateral element for concrete and two noded element for reinforcement is used for the prediction of the behavior of reinforcement concrete structures. The disturbed state concept (DSC) including the hierarchical single surface (HISS) plasticity model with associated flow rule with modifications is used to characterize the constitutive behavior of concrete both in compression and in tension which is named DSC/HISS-CT. The HISS model is applied to shows the plastic behavior of concrete, and DSC for microcracking, fracture and softening simulations of concrete. It should be noted that the DSC expresses the behavior of a material element as a mixture of two interacting components and can include both softening and stiffening, while the classical damage approach assumes that cracks (damage) induced in a material treated acts as a void, with no strength. The DSC/HISS-CT is a unified model with different mechanism, which expresses the observed behavior in terms of interacting behavior of components; thus the mechanism in the DSC is much different than that of the damage model, which is based on physical cracks which has no strength and interaction with the undamaged part. This is the first time the DSC/HISS-CT model, with the capacity to account for both compression and tension yields, is applied for concrete materials. The DSC model allows also for the characterization of non-associative behavior through the use of disturbance. Elastic perfectly plastic behavior is assumed for modeling of steel reinforcement. The DSC model is validated at two levels: (1) specimen and (2) practical boundary value problem. For the specimen level, the predictions are obtained by the integration of the incremental constitutive relations. The FE procedure with DSC/HISS-CT model is used to obtain predictions for practical boundary value problems. Based on the comparisons between DSC/HISS-CT predictions, test data and ANSYS software predictions, it is found that the model provides highly satisfactory predictions. The model allows computation of microcracking during deformation leading to the fracture and failure; in the model, the critical disturbance, Dc, identifies fracture and failure.

The Design of Robust DSC-PLL under Distorted Grid Voltage Contained Unbalance on Frequency Variation (주파수 변동시 불평형 전압에 강인한 DSC-PLL 설계 연구)

  • Lee, Jae Do;Cha, Han Ju
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.11
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    • pp.1447-1454
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    • 2018
  • In this paper, the design of robust DSC-PLL(Delayed Signal Cancellation Phase Locked Loop) is proposed for coping with frequency variation. This method shows significant performance for detection of fundamental positive sequence component voltage when the grid voltage is polluted by grid unbalance and frequency variation. The feedback frequency estimation of DSC-PLL is tracking the drift in the phase by unbalance and frequency variation. The robust DSC PLL is to present the analysis on method and performance under frequency variations. These compensation algorithms can correct for discrepancies of changing the frequency within maximum 193[ms] and improve traditional DSC-PLL. Linear interpolation method is adopted to reduce the discretized errors in the digital implementation of the PLL. For verification of robust characteristic, PLL methods are implemented on FPGA with a discrete fixed point based. The proposed method is validated by both Matlab/Simulink and experimental results based on FPGA(XC7Z030).

Analysis Thermal Performance of PV/Thermal Collector with Dye-sensitized Solar Cell Module (염료감응형태양전지 모듈 적용 PVT 집열기의 열적 성능 분석)

  • Jang, Han-Bin;Mun, Jong-Hyeok;Gang, Jun-Gu;Kim, Jin-Hui;Kim, Jun-Tae
    • Proceedings of the Korean Society for Emotion and Sensibility Conference
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    • 2009.11a
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    • pp.273-276
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    • 2009
  • Photovoltaic-thermal(PVT) collectors are a combination of photovoltaic modules with solar thermal collectors, forming one device that receives solar radiation and produces electricity and heat simultaneously. Of various PV modules, dye-sensitized solar cell(DSC) is a relatively new type of solar cell technology that can transmit light while they can generate electricity. With this aspect, DSC can be applied into solar thermal collectors. The object of this study is to evaluate the thermal performance of PVT collector with DSC. The thermal performance of the DSC PVT combind collector was measured in outdoor conditions with the solar radiation of over $700W/m^2$. In this study, the PVT collector with the 30% light transmittance of DSC achieved its thermal efficiency of about 36%.

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A Correlation Analysis between DSC (Dye Sensitized Cell) and Daylighting-Focusing on Educational Space (염료감응형 태양전지(DSC)와 자연채광의 상관관계 분석-교육공간을 중심으로)

  • Lee, Eung-Jik
    • Journal of the Korean Solar Energy Society
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    • v.40 no.1
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    • pp.35-47
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    • 2020
  • Due to the large window area, the lighting environment of the educational space between the window and deep part of the room is not uniformly illuminated, and the phenomenon of glare is severe. For this reason, the daylight performance of DSC-BIPV windows was analyzed in order to improve the natural lighting in the educational sector. The method derives the correlation with natural lighting by measurement and simulation. Dynamic simulation confirmed that the average illuminance of the target space was higher at later than the early afternoon. The performance of natural lighting at 40% and 30% transmission of DSC has the effect of significantly reducing the amount of excess light in existing windows. Nevertheless, the actual average illuminance in all seasons corresponds to the standard illuminance of the educational facility, 300 Lux. In addition, the uniformity is also seen through the skylight illuminance ratio.

The Construction of the Fishing-vessel Monitoring System and the Protocol Analysis for the Calling of Location Requirement Using VHF-DSC (VHF-DSC 위치요청 프로토콜 분석과 어선관제시스템 구축)

  • Kim, Jeong-nyun
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2013.10a
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    • pp.929-932
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    • 2013
  • In preperation for the compulsory installation of VHF(Very High Frequency) wireless equipment and fishing vessel automatic identification system according to the revision of "The Ships Safety Act" and "Fishing Vessel act", Fishery Information & Communication Department of National Federation of Fisheries Cooperatives is building VHF communication network and automatic identification system for fishing vessel monitoring. This study suggests the protocol analysis for the calling of location requirement using DSC(Digital Selective Calling) function and show best way for fishing vessel automatic identification system. Also, it suggest way to realize fishing vessel monitoring system.

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DSC and TGA Thermal Analysis for the Interaction between Poly(2-hydroxyethylmethacrylate) and Amino Acids (Poly(2-hydroxyethylmethacrylate)와 아미노산과의 상호작용에 관한 DSC와 TGA 열분석에 관한 연구(Ⅰ))

  • Kim, Ui Rak;Jeong, Bong Jin;Jeong, Sung Uk;Min, Kyung Sub;Lee, Myung Jae;Nam, Won Mo;Park, Hae Jung
    • Journal of the Korean Chemical Society
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    • v.40 no.6
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    • pp.385-393
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    • 1996
  • The interaction between poly(HEMA) which is material of contact lens containing about 45% water and amino acids (alanine, arginine, methionine, proline, glycine, serine, lysine) have been studied by using the thermal analysis methods through DSC and TGA. The experimental results of DSC and TGA were shown that lysine, arginine and alanine have the most stable interaction between poly(HEMA) and amino acids.

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The Construction of the Vessel Monitoring System and the Protocol Analysis for the Calling of Location Requirement Using VHF-DSC (VHF-DSC 위치요청 프로토콜 분석과 선박관제시스템 구축)

  • Kim, Jeong-Nyun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.17 no.12
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    • pp.2800-2805
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    • 2013
  • In preperation for the compulsory installation of VHF(Very High Frequency) wireless equipment and fishing vessel automatic identification system according to the revision of "The Ships Safety Act" and "Fishing Vessel act", Fishery Information & Communication Department of National Federation of Fisheries Cooperatives is building VHF communication network and automatic identification system for fishing vessel monitoring. This study suggests the protocol analysis for the calling of location requirement using DSC(Digital Selective Calling) function and show best way for fishing vessel automatic identification system. Also, it suggest way to realize fishing vessel monitoring system.