• Title/Summary/Keyword: DOC

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Distribution of Phytoavailable Heavy Metals in the Korean Agricultural Soils Affected by the Abandoned Mining Sites and Soil Properties Influencing on the Phytoavailable Metal Pools

  • Lim, Ga-Hee;Kim, Kye-Hoon;Seo, Byoung-Hwan;Kim, Kwon-Rae
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.3
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    • pp.191-198
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    • 2014
  • Absorption and accumulation of heavy metals in plants were determined by phytoavailable contents rather than total contents of heavy metals. Therefore, phytoavailability-based management protocol should be prepared for safe food crop production in contaminated agricultural lands. This study was conducted to understand the distribution and phytoavailability of heavy metal in the Korean agricultural soils affected by abandoned mining sites along with investigation of soil properties (soil pH, OM, DOC, clay content, Al/Fe/Mn content) influencing on the metal phytoavailability. For this, 142 agricultural soils located nearby 39 abandoned mining sites distributed in five province in Korea, were analyzed. Among the four different heavy metals, cadmium (Cd) and zinc (Zn) appeared to exist in more phytoavailable form than cupper (Cu) and lead (Pb). Soil pH was the main factor governing phytoavailable Cd, Pb, and Zn showing positive relationship with partitioning coefficients of the corresponding metals; Cd (r = 0.66, P < 0.001), Pb (r = 0.70, P < 0.001), and Zn (r = 0.62, P < 0.001). This implied higher phytoavailability of the corresponding metals with higher soil pH. In contrast, phytoavailability of Cu (r = 0.41, p < 0.01) was only negatively related with soil DOC (dissolved organic carbon).

High Lift Device Design Optimization and Wind Tunnel Tests (고양력장치 설계 최적화 및 풍동시험)

  • Lee, Yung-Gyo;Kim, Cheol-Wan;Cho, Tae-Hwan
    • Aerospace Engineering and Technology
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    • v.9 no.1
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    • pp.78-83
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    • 2010
  • In the present paper, a flap was optimized to maximize the lift. A 2-element fowler flap system was utilized for optimization with an initial shape of general aviation airfoil and a flap shape designed by Wentz. Response surface method and Hicks-Henne shape function were implemented for optimization. 2-D Navier-Stokes method was used to solve flow field around aGA(W)-1 airfoil with a fowler flap. Commercial programs including Visual-Doc, Gambit/Tgridand Fluent were used. Upper surface shape and the flap gap were optimized and lift for landing condition was improved considerably. The original and optimized flaps were tested in the KARI's 1-m low speed wind tunnel to examine changes in aerodynamic characteristics. For optimized flap tests, the similar trend to prediction could be seen but stall angle of attack was lower than what was expected. Also, less gap than optimized design delayed stall and produced better lift characteristics. This is believed to be the effect of turbulence model.

First-flush Runoff Characteristics of NPS from golf course (골프장에서 발생하는 비점오염원의 초기유출수 특성)

  • Shin, Min-Hwan;Choi, Jae-Wan;Choi, Yong-Hun;Seo, Ji-Yeon;Lee, Jae-Woon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2010.05a
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    • pp.1129-1133
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    • 2010
  • 본 연구에서는 수질오염총량제와 정책제안의 원활하고 합리적인 추진을 위해 토지피복분류체계의 대분류중 초지에 해당하고 중분류 중 골프장에 해당하는 지점을 선정하여 강우에 의해 발생하는 비점오염물질의 유출특성을 분석하였다. 연구기간 동안 총 27번의 강우사상으로 인해 발생하는 강우유출수에 대하여 유량과 수질농도를 측정하였다. 유량측정은 웨어를 통한 수위를 측정하여 유량으로 환산하였고, 수질항목은 $BOD_5$, $COD_{Mn}$, DOC, SS, T-N, T-P, $NH_3$-N, $NO_3$-N, $PO_4$-P 등 9개 항목을 분석하였다. 분석된 결과를 이용하여 골프장에서 발생하는 비점오염원의 초기세척효과 발생여부를 판단하기 위하여 누적오염부하량/누적유출량 그래프를 도식화하였다. 연구기간동안 발생한 5~82 mm의 강우로 인해 6.6~2,082 $m^3$의 유출이 발생하였다. 발생된 유출수의 농도는 $BOD_5$ 1.8~11.3 mg/L, $COD_{Mn}$ 19.2~51.4 mg/L, DOC 11.0~31.0 mg/L, SS 2.2~57.3 mg/L, T-N 1.545~16.098, T-P 0.230~4.528 mg/L, $NH_3$-N 0.076~5.285 mg/L, $NO_3$-N 0.122~2.905 mg/L, $PO_4$-P 0.005~2.631 mg/L로 나타났다. 초기유출수의 세척효과는 27번의 강우사상동안 SS 항목의 경우 17번, $NO_3$-N 11번, $NH_3$-N 4번 등이 발생하였다. 초기세척효과가 발생한 강우사상은 초기의 오염원 농도가 중 후반 농도보다 농도가 높음을 의미하므로, 골프장에서 발생하는 강우유출수는 초기에 발생하는 오염원에 초점을 두고 처리방안을 모색해야 할 것으로 판단된다. 또한 SS와 질소계열의 농도가 높은 것은 골프장의 잔디관리를 위한 농약이나 제초제 등의 사용과 토양유실이 원인인 것으로 판단되며, 이를 저감하기 위한 적절한 사용방안과 저감대책이 필요할 것으로 판단된다.

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Variation in Nitrate Contamination of Shallow Groundwater in a Farmland in Gyeonggi-do, Korea (경기도 지역 농경지의 천부 지하수 내 질산염 오염특성과 변화)

  • Lee, Eun-Jae;Woo, Nam-Chil;Lee, Byung-Sun;Kim, Yang-Bin
    • Economic and Environmental Geology
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    • v.41 no.4
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    • pp.393-403
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    • 2008
  • Hydrogeochemistry of groundwater was studied in order to identify the influence of cow manure, distributed to a farmland as organic fertilizer, on nitrate concentrations in shallow groundwater and its spatio-temporal variations. From monitoring wells, water levels were measured using automatic data loggers, and water samples collected and analyzed in Feb., April, June and Oct. 2007. The average electric conductivity and concentration of nitrate in the groundwater show the highest levels in April and decline in subsequent sampling times. Decreases in dissolved oxygen(DO) and nitrate concentrations from April to Oct. and corresponding increases in $HCO_3$ concentrations indicate denitrification processes by microorganisms. Spatial variation of nitrate concentration appeared to be affected by the redox conditions of groundwater controlled by geochemical reactions of Mn, Fe and DOC contents.

Spatial Distribution of Dissolved Organic Matter Compositions Upstream of Ipobo (이포보 상류 용존 유기물의 공간적 분포 분석)

  • Yoon, Sang Mi;Choi, Jung Hyun
    • Journal of Korean Society on Water Environment
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    • v.34 no.4
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    • pp.399-408
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    • 2018
  • This research investigated the effects of weir (Ipobo) construction on the dynamics and the related spatial distributions of pollutants inflowing from tributaries (Yanghwacheon and Bokhacheon). Conductivity measurements and water sampling were conducted longitudinally, horizontally, and vertically in the waterbody upstream of the area located in Ipobo. Additionally, collected water samples were used for the dissolved organic carbon (DOC) analysis and fluorescence analysis which results in the SUVA, HIX, BIX, and FI calculation and parallel factor analysis (PARAFAC). Consequently, the results of the Conductivity, DOC, SUVA, and HIX showed that high concentration of pollutants that were flowing from the area of Bokhacheon which was mixed along the flow of the main river. The results of the BIX and FI did not show significant difference along the river flow which represented that allochthonous and terrestrial DOM, and for this reason was dominated in the whole waterbody rather than just the autochthonous DOM. The PARAFAC results showed that the two fluorescence components, humic-like and protein-like, constituted the fluorescence matrices of the water samples. The prevailing discipline notes that the two components were inflowing from the tributaries, however, a refractory component, humic-like substances, was relatively accumulated near the weir. From the results, the dynamics and spatial distributions of the DOM are dependent on the DOM characteristics, which induces the application of a specialized DOM analysis method to investigate the effects of a subsequent weir construction on the dynamics and spatial distributions of pollutants inflowing from the tributaries.

Performance evaluation of organic matter adsorption from actual graywater using GAC: OrbitrapTM MS and optimization

  • Ligaray, Mayzonee;Kim, Minjeong;Shim, Jaegyu;Park, Jongkwan;Cho, Kyung Hwa
    • Membrane and Water Treatment
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    • v.10 no.6
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    • pp.471-484
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    • 2019
  • The complex combination of organic contaminants in the wastewater made water treatment challenging; hence, organic matter in water bodies is usually measured in terms of organic carbon. Since it is important to identify the types of compounds when deciding suitable treatment methods, this study implemented a quantitative and qualitative analysis of the organic matter content in an actual graywater sample from Ulsan, Republic of Korea using mass spectroscopy (MS). The graywater was treated using adsorption to remove the organic contaminants. Using orbitrap MS, the organic matter content between an untreated graywater and the treated effluent were compared which yielded a significant formula count difference for the samples. It was revealed that CHON formula has the highest removal count. Isotherm studies found that the Freundlich equation was the best fit with a coefficient of determination ($R^2$) of 0.9705 indicating a heterogenous GAC surface with a multilayer characteristic. Kinetics experiments fit the pseudo-second order equation with an $R^2$ of 0.9998 implying that chemisorption is the rate-determining step between the organic compounds and GAC at rate constant of $52.53g/mg{\cdot}h$. At low temperatures, the reaction between GAC and organic compounds were found to be spontaneous and exothermic. The conditions for optimization were set to achieve a maximum DOC and TN removal which yielded removal percentages of 94.59% and 80.75% for the DOC and TN, respectively. The optimum parameter values are the following: pH 6.3, 2.46 g of GAC for every 30 mL of graywater sample, 23.39 hrs contact time and $38.6^{\circ}C$.

Study on the Removal Characteristics of Diazinon Using Ozone / Hydrogen Peroxide (오존/과산화수소공정(Peroxone AOP)을 이용한 Diazinon 제거 특성 연구)

  • Youn, Hyojin;Han, Ihnsup;Yoon, Woohyun
    • Journal of the Korean Society of Urban Environment
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    • v.18 no.4
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    • pp.391-399
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    • 2018
  • In this study, Diazinon which is the most widely used organophosphorus pesticides (OPPs) among pesticides was removed by ozone/hydrogen peroxide advanced oxidation process (Peroxone AOP). Diazinon is mainly found in groundwater, drinking water, rivers and ponds that are near agricultural areas using the pesticide. Accumulation of Diazinon on the body in the form of metabolites causes neurotoxicity, confusion, dizziness and vomiting. Diazinon is not easily removed by conventional water treatment processes. This study investigated the Diazinon removal characteristics with OH radicals with strong oxidizing power generated by using ozone and hydrogen peroxide. We determined optimal hydrogen peroxide/ozone injection molar ratio and confirmed the elimination reaction to initial Diazinon concentration, pH and DOC concentration, which are factors influencing the removal efficiency. Domestic researches on pesticide removal in the environment are much less than the cases of overseas. This study is expected to provide a basis for the process design for pesticide removal.

Derivation of Optimal Conditions and Effect of Treated Water Quality for Treatment of Drinking Water using Inorganic Membrane (무기막을 사용한 먹는물 처리 시 최적의 조건 도출 및 처리수질에 미치는 영향)

  • Won, Chan-Hee
    • Journal of the Korean Society for Environmental Technology
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    • v.19 no.6
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    • pp.543-549
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    • 2018
  • In this study, the treatment efficiency of inorganic membrane according to the flux that blending raw water was investigated at the laboratory level. Based on the results of each blending and flux, we obtained the best efficiency according to each measurement item. The treatment efficiencies were different depending on the raw water and treatment amount of the treated water. Especially, turbidity removal efficiency was high. In the case of $UV_{254}$, the removal efficiency according to the concentration of the raw water and the removal efficiency according to the flux of the treated water showed a maximum of 69 % to minimum of 48 %. In the case of TOC and DOC, the processing efficiency was 22 % and 28 %, respectively, because the organic value of the raw water was low. These results suggest that there is an optimal process to effectively remove contaminants from the inorganic membrane process, and it is necessary to optimize it according to operating conditions.

Changes in Spectroscopic and Molecular Weight Characteristics of Dissolved Organic Matter in an Agriculture Reservoir during a Summer Monsoon (장마시기에 따른 농업용 저수지 내 용존 유기물 분광특성과 분자량 변화)

  • Jung, Ka-Young;Lee, Yun Kyung;Yoo, HaYoung;Nam, Gui-Sook;Hur, Jin
    • Journal of Korean Society on Water Environment
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    • v.37 no.6
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    • pp.458-468
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    • 2021
  • In this study, we investigated the variations of dissolved organic matter (DOM) in an agricultural reservoir during the monsoon period (June to October, 2020) with respect to the organic carbon concentration (DOC), molecular weight distribution, and optical properties. The monsoon period was divided into three phases - beginning storm (BS), during storm (DS), and after storm (AS). Our results showed significant differences in the concentrations and characteristics of DOM during the summer monsoon. The DOC concentrations were decreased after the monsoon, probably due to a dilution effect. In contrast, increasing trends were observed in the specific UV absorbance (SUVA), and relative abundances of humic-like fluorescence and larger-sized compounds. These observations implied that the large-sized and humic-like organic components with terrestrial origins strongly affected the reservoir DOM after the summer monsoon. Meanwhile, biopolymer size fraction, which is associated with algal activity, became more abundant after the monsoon. These results suggest that DOM with autochthonous sources became dominant as a result of the inflow of nutrients into the reservoir after the storm. Spatial changes in DOM within the reservoir were not pronounced as much as the temporal variations. All taken, it can be concluded that the summer monsoon simply led to the decrease of DOM concentrations while the sources and the quality of DOM underwent substantial changes, which may enrich refractory organic matter in the reservoir. This study reveals the importance of in-depth DOM quality monitoring before and after summer monsoon for effective water quality management in agricultural reservoirs.

Legal search method using S-BERT

  • Park, Gil-sik;Kim, Jun-tae
    • Journal of the Korea Society of Computer and Information
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    • v.27 no.11
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    • pp.57-66
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    • 2022
  • In this paper, we propose a legal document search method that uses the Sentence-BERT model. The general public who wants to use the legal search service has difficulty searching for relevant precedents due to a lack of understanding of legal terms and structures. In addition, the existing keyword and text mining-based legal search methods have their limits in yielding quality search results for two reasons: they lack information on the context of the judgment, and they fail to discern homonyms and polysemies. As a result, the accuracy of the legal document search results is often unsatisfactory or skeptical. To this end, This paper aims to improve the efficacy of the general public's legal search in the Supreme Court precedent and Legal Aid Counseling case database. The Sentence-BERT model embeds contextual information on precedents and counseling data, which better preserves the integrity of relevant meaning in phrases or sentences. Our initial research has shown that the Sentence-BERT search method yields higher accuracy than the Doc2Vec or TF-IDF search methods.