Browse > Article
http://dx.doi.org/10.15681/KSWE.2018.34.4.399

Spatial Distribution of Dissolved Organic Matter Compositions Upstream of Ipobo  

Yoon, Sang Mi (Department of Environmental Science and Engineering, Ewha Womans University)
Choi, Jung Hyun (Department of Environmental Science and Engineering, Ewha Womans University)
Publication Information
Journal of Korean Society on Water Environment / v.34, no.4, 2018 , pp. 399-408 More about this Journal
Abstract
This research investigated the effects of weir (Ipobo) construction on the dynamics and the related spatial distributions of pollutants inflowing from tributaries (Yanghwacheon and Bokhacheon). Conductivity measurements and water sampling were conducted longitudinally, horizontally, and vertically in the waterbody upstream of the area located in Ipobo. Additionally, collected water samples were used for the dissolved organic carbon (DOC) analysis and fluorescence analysis which results in the SUVA, HIX, BIX, and FI calculation and parallel factor analysis (PARAFAC). Consequently, the results of the Conductivity, DOC, SUVA, and HIX showed that high concentration of pollutants that were flowing from the area of Bokhacheon which was mixed along the flow of the main river. The results of the BIX and FI did not show significant difference along the river flow which represented that allochthonous and terrestrial DOM, and for this reason was dominated in the whole waterbody rather than just the autochthonous DOM. The PARAFAC results showed that the two fluorescence components, humic-like and protein-like, constituted the fluorescence matrices of the water samples. The prevailing discipline notes that the two components were inflowing from the tributaries, however, a refractory component, humic-like substances, was relatively accumulated near the weir. From the results, the dynamics and spatial distributions of the DOM are dependent on the DOM characteristics, which induces the application of a specialized DOM analysis method to investigate the effects of a subsequent weir construction on the dynamics and spatial distributions of pollutants inflowing from the tributaries.
Keywords
Dissolved organic matter; Fluorescence analysis; Ipobo; Spatial distribution;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Andersen, C. M. and Bro, R. (2003). Practical Aspects of PARAFAC Modeling of Fluorescence Excitation-Emission Data, Journal of Chemometrics, 17(4), 200-215.   DOI
2 Baghoth, S. A., Sharma, S. K., and Amy, G. L. (2011). Tracking Natural Organic Matter (NOM) in a Drinking Water Treatment Plant Using Fluorescemce Excitation-emission Matrices and PARAFAC, Water Research, 45(2), 797-809.   DOI
3 Birdwell, J. E. and Engel, A. S. (2010). Characterization of Dissolved Organic Matter in Cave and Spring Waters Using UV-Vis Absorbance and Fluorescence Spectroscopy, Organic Geochemistry, 41(3), 270-280.   DOI
4 Bro, R. (1999). Exploratory Study of Sugar Production Using Fluorescence Spectroscopy and Multi-way Analysis, Chemometrics and Intelligent Laboratory Systems, 46(2), 133-147.   DOI
5 Bro, R. and Kiers, H. A. (2003). A New Efficient Method for Determining the Number of Components in PARAFAC Models, Journal of Chemometrics, 17(5), 274-286.   DOI
6 Chae, S. K., Oh, S. H., and Ahn, H. K. (2016). Study on Change of Algae Occurrence Before& After Gangcheon and Ipoh Weir Construction at Namhan River, Journal of Wetlands Research, 18(4), 394-403. [Korean Literature]   DOI
7 Chen, J., Leboeuf, E. J., Dai, S., and Gu B. (2003). Fluorescence Spectroscopic Studies of Natural Organic Matter Fractions, Chemosphere, 50(5), 639-647   DOI
8 Cory, R. M. and Mcknight, D. M. (2005). Fluorescence Spectroscopy Reveals Ubiquitous Presence of Oxidized and Reduced Quinones in Dissolved Organic Matter, Environmental Science & Technology, 39(21), 8142-8149.   DOI
9 Chen, W., Westerhoff, P., Leenheer, J. A., and Booksh, K. (2003). Fluorescence Excitation-Emission Matrix Regional Integration to Quantify Spectra for Dissolved Organic Matter, Environmental Science and Technology, 37(24), 5701-5710.   DOI
10 Cirpka, O. A., Fiene, M. N., Hofer, M., Hoehn, E., Tessarini, A., Kipfer, R., and Kitanidis. P. K. (2007). Analyzing Bank Filtration by Deconvoluting Time Series of Electric Conductivity, Groundwater, 45(3), 318-328.   DOI
11 Cressie, N. (1990). The Origin of Kriging, Mathematical Geology, 22(3), 239-252.   DOI
12 Han Gang Watershed Management Committee. (2015). Aquatic Ecosystem Monitoring in Weirs of the Han River (III), 11- 1480347-000079-10, Han River Environment Research Center. [Korean Literature]
13 Cumberland, S. A. and Baker, A. (2007). The Freshwater Dissolved Organic Matter Fluorescence-Total Organic Carbon Relationship, Hydrological Processes, 21(16), 2093-2099.   DOI
14 Fellman, J. B., Hood, E., and Spencer, R. G. M. (2010). Fluorescence Spectroscopy Opens New Windows into Dissolved Organic Matter Dynamics in Freshwater Ecosystems: A Review, Limnology and Oceanography, 55(6), 2452-2462.   DOI
15 Han River Basin Environmental Office. (2014). Namhan River Mid-watershed Water Environment Management Plan (2013-2015), Han River Basin Environmental Office, 82-83. [Korean Literature]
16 Hur, J., Kim, M. K., Park, S. W. (2007). Analyses of Synchronous Fluorescence Spectra of Dissolved Organic Matter for Tracing Upstream Pollution Sources in Rivers, Journal of Korean Society of Environmental Engineers, 29(3), 317-324. [Korean Literature]
17 Holbrook R. D., Yen, J. H., and Grizzard, T. J. (2006). Characterization Natural Organic Material from the Occoquan Watershed (Northern Virginia, US) using Fluorescence Spectroscopy and PARAFAC, The Science of the Total Environment, 361(1-3), 249-266.   DOI
18 Hudson, N., Baker A., and Reynoles, D. (2007). Fluorescence Analysis of Dissolved Organic Matter in Natural, Waste and Polluted Waters - A Review, River Research and Applications, 23(6), 631-649.   DOI
19 Huguet, A., Nacher, L., Relexans, S., Saubusse, S., Froidefond, J. M., and Parlanti, E. P. (2009). Properties of Fluorescent Dissolved Organic Matter in the Gironde Estuary, Organic Geochemistry, 40(6), 706-719.   DOI
20 Hur, J., Shin, J. K., and Park, S. W. (2006). Characterizing Fluo- rescence Properties of Dissolved Organic Matter for Water Quality Management of Rivers and Lakes, Journal of Korean Society of Environmental Engineers, 28(9), 940-948. [Korean Literature]
21 Jung, S. H. (2015). Experimental and Numerical Study of Twodimensional Mixing Based on the Conductivity Tracing in Natural Streams, Master's Thesis, Seoul National University, Seoul, 1-40. [Korean Literature]
22 Kang, H. S. (2017). A study on the Establishment of a Survey System for Water Ecological Continuity [Final Report], The Ministry of Environment. [Korean literature]
23 Lee., B. G., Kim, H. J. , Hyeon, Y. J. , Jeong, S. H., and Kim, E. Y. (2012). A Study for Integrated Management of Water Quantity and Quality to Improve the Water Environment of 4 Rivers Restoration Project, Research Paper 2012-04, Korea Environment Institute, 1-22. [Korean Literature]
24 Kim, J. S., Rim, H. W., Um, M. J., Kim, W. I., Ahn, W. S. (2008). Spatial Adjustment of Rainfall using Kriging Method and Application of Distributed Model, Proceedings of the Korea Water Resources Association Conference, Korea Water Resources Association, 130-134. [Korean Literature]
25 Kis, I. M. (2016). Comparison of Ordinary and Universal Kriging Interpolation Techniques on a Depth Variable (a Case of Linear Spatial Trend), Case Study of the Sandrovac Field, The Mining-Geology-Petroleum Engineering Bulletin, 31(2), 41-58.
26 Lee, M. K., Choi, K. S., Kim, S. W., and Kim, D. S. (2009). characterization of Dissolved Organic Matter in Stream and Industrial Waste Waters of Lake Sihwa Watershed by Fluorescence 3D-EEMs Analysis, Journal of Korean Society of Environmental Engineers, 31(9), 803-810. [Korean Literature]
27 Leenheer, J. A. and Croue, J. P. (2003). Peer Reviewed: Characterizing Aquatic Dissolved Organic Matter, Environmental Science & Technology, 37(1), 18-26.   DOI
28 Ministry of Environment (ME). (2010). Environmental Geographic Information Service, https://egis.me.go.kr/main.do (accessed by Feb. 2018)
29 Li, J., Dong, S., Liu, S., Yang. Z., Peng, M., and Zhao, C. (2013). Effects of Cascading Hydropower Dams on the Composition, Biomass and Biological Integrity of Phytoplankton Assemblages in the Middle Lancang-Mekong River, Ecological Engineering, 60, 316-324.   DOI
30 Matilainen, A., Gjessing, E. T., Lahtinen, T., Hed, L., Mhatnager, A., and Sillanpaa, M. (2011). An Overview of the Methods used in the characterization of natural organic matter (NOM) in relation to Drinking Water Treatment, Chemosphere, 83(11), 1431-1442.   DOI
31 Monteiro, M. T. F., Oliveira, S. M., Luizao, F. J., Candido, L. A., Ishida, F. Y., and Tomasella, J. (2014). Dissolved Organic Carbon Concentration and its Relationship to Electrical Conductivity in the Waters of a Stream in a Forested Amazonian Blackwater Catchment, Plant Ecology & Diversity, 7(1-2), 205-213.   DOI
32 Murphy, K. R., Stedmon, C. A., Graeber, D., and Bro, R. (2013). Fluorescence Spectroscopy and Multi-way Techniques. PARAFAC, Analytical Methods, 23, 6557-6566.
33 Ogawa, H. and Tanoue, E. (2003). Dissolved Organic Matter in Oceanic Waters, Journal of Oceanography, 59(2), 129-147   DOI
34 Park, M. H. and Hur, J. (2008). Changes in Spectroscopic Characteristics and Pyrene Binding Reactivities of Dissolved Organic Matters by Biodegradation, Journal of Korean Society of Environmental Engineers, 30(9), 893-899. [Korean Literature]
35 Santin, C., Yanashita, Y., Otero, X. L., Alvarez, M. A., and Jaffe R. (2009). Characterizing Humic Substances from Estuarine Soils and Sediments by Excitation-Emission Matrix Spectroscopy and Parallel Factor Analysis, Biogeochemistry, 96(1-3), 131-147.   DOI
36 Stedmon, C. A. and Bro, R. (2008). Characterizing Dissolved Organic Matter Fluorescence with Parallel Factor Analysis: a Tutorial, Limnology and Oceanography, 6(11), 572-579.
37 Stedmon, C. A. and Markager, S. (2005). Resolving the Variability in Dissolved Organic Matter Fluorescence in a Temperate Estuary and its Catchment Using PARAFAC analysis, Limnology and Oceanography, 50(2), 686-697.   DOI
38 United States Environmental Protection Agency (EPA) (2012). United States Environmental Protection Agency (EPA), https://archive.epa.gov/water/archive/web/html/vms59.html (accessed Feb. 2018)
39 Stedmon, C. A., Markager, S., and Bro, R. (2003). Tracing Dissolved Organic Matter in Aquatic Environments New Approach to Fluorescence Spectroscopy, Marine Chemistry, 82(3), 239- 254.   DOI
40 Stewart, A. J. and Wetzel R. G. (1980). Fluorescence: Absorbance Ratios-a molecular-Weight Tracer of Dissolved Organic Matter1, Limnology and Oceanography, 25(3), 559-564.   DOI
41 Vogt, T., Hoehn, E., Schneider, P., Freund, A., Schirmer, M., and Cirpka, O. A. (2010). Fluctuations of Electrical Conductivity as a Natural Tracer for Bank Filtration in a Losing Stream, Advances in Water Resources, 33(11), 1296-1308.   DOI
42 Korea Water Resources Corporation (K-water). (2017). Water Resources Management Information System (WAMIS), http://www.wamis.go.kr/ (accessed Feb. 2018)
43 Woo, K. S., Jo, J. H., and Lee, D. J. (2006). Stress Recovery Technique by Ordinary Kriging Interpolation in P-Adaptive Finite Element Method, Journal of the Korean Society of Civil Engineers, 26(4), 677-687.
44 Yang, L., Hur, J., and Zhuang, W. (2015). Occurrence and Behaviors of Fluorescence EEM-PARAFAC Components in Drinking Water and Wastewater Treatement Systems and Their Applications: A Review, Environmental Science and Pollution Research, 22(9), 6500-6510.   DOI
45 Yeoju City. (2015). Yeoju City, http://www.yeoju.go.kr/cms/content/view/1684 (accessed Feb. 2018).
46 You, K. A. (2013). Initial Effects of Large Artificial Structure Construction on River Ecosystem, Ph. D. Dissertation, Graduate School of Konkuk University, Seoul, 40-42. [Korean Literature]
47 Zsolnay, A., Baihar, E., Jimenez, M., Steinweg, B., and Saccomandi, F. (1999). Differentiating with Fluorescence Spectroscopy the Sources of Dissolved Organic Matter in Soils Subjected to Drying, Chemosphere, 38(1), 45-50.   DOI