• Journal of Korean Society for Atmospheric Environment
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• v.26 no.4
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• pp.412-419
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• 2010

Concurrent Multi Path-Differential Optical Absorption Spectroscopy (CMP-DOAS) is a novel active optical system to measure simultaneously ambient trace gases (such as $NO_2$, $SO_2$, $O_3$, and HCHO) present on several light paths. The CMP-DOAS system consists of a 2D CCD camera, spectrometer, receiving telescopes, and artificial light sources. The system receives spectra, which have been transported through several paths. It also covers wavelength ranges of which trace gases of interest share at the same time. This study presents the instrumental setup of a CMP-DOAS in detail. A field campaign for a comparative measurement was carried out at an urban site in Gwangju for a month on January 2009. $NO_2$ mixing ratios measured by the CMP-DOAS system and in-situ $NO_2$ analyzers were in good agreement by 83%. It demonstrates the high capacities of the CMP-DOAS technique to cover atmospheric trace gases dispersed across wide light paths.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.2
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• pp.150-157
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• 2006

Spatially resolved remote identification and quantification of trace gases in the atmosphere is desirable in various fields of scientific research as well as in public security and industrial contexts. Environmental observations investigating causes, extent md consequences of air pollution are of fundamental interest. We present an Imaging-DOAS system, a ground based remote sensing instrument that allows spatially resolved mapping of atmospheric trace gases by a differential optical absorption spectroscopy(DOAS) with sun scattered light as the light source. A passive DOAS technique permits the identification and quantification of various gases, e.g., $NO_2,\;SO_2,\;and\;CH_2O$, from their differential absorption structures with high sensitivity. The Imaging-DOAS system consists of a scanning mirror, a focusing lens, a spectrometer, a 2-D CCD, ad the integral control software. An imaging spectrometer simultaneously acquires spectral information on the incident light in one spatial dimension(column) and sequentially scans the next spatial dimension with a motorized scanning mirror. The structure of the signal acquisition system is described in detail and the evaluation method is also briefly discussed. Applications of imaging of the $NO_2$ contents in the exhaust plumes from a power plant are presented.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.1
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• pp.1-14
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• 2005

In this study, a Long Path Differential Optical Absorption Spectroscopy system (K-JIST LP-DOAS) has been used to simultaneously measure atmospheric monoaromatic hydrocarbons and other trace compounds. The validity of the K-JIST LP-DOAS for measuring atmospheric monoaromatic hydrocarbons was tested during a field campaign between 12 February and 14 March 2003 at an urban site in Seoul, Korea through inter-comparative measurements against a collocated on-line Gas Chromatography (GC) system. The concentrations of benzene, toluene, p-xylene, and m-xylene were measured with the K-JIST LP-DOAS system in the UV region (239～302 nm) over a 740 m beam path. For the other trace compounds, a longer spectral range (299～362 nm) was used. In order to remove the interference of atmospheric abundant species (such as oxygen, sulfur dioxide and ozone), two oxygen optical density spectra obtained at two pathlengths, 697 and 1133m, and reference spectra of sulfur dioxide and ozone were incorporated in the fitting procedure. The mean concentrations measured by our LP-DOAS during the measurement period were 0.77 ($\pm$0.38) ppbv for benzene, 3.68 ($\pm$1.90) ppbv for toluene, 0.41 ($\pm$0.19) ppbv for p-xylene, 0.54 ($\pm$0.24) ppbv for m-xylene. The concentration data of benzene, toluene, p-xylene and m-xylene obtained by our LP-DOAS were found to be in relatively good correlations with those of the online GC system. Pearson's coefficients in the observed concentrations between LP-DOAS and on-line GC were 0.84 for benzene, 0.83 for toluene and 0.65 for m,p-xylene. This study suggests that the LP-DOAS system can be used to provide reliable information on both the mixing ratios and temporal distribution characteristics of monoaromatic hydrocarbons in the urban air.

• 한국태양에너지학회:학술대회논문집
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• 2009.11a
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• pp.285-290
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• 2009

The main thrust of this paper is to investigate acceptable supply air conditions of a dedicated outdoor air system (DOAS) for highrise apartment buildings. As for a typical $132-m^2$ apartment unit, it was assumed that centralized DOAS-Ceiling Radiant Cooling Panel was installed. Transient behavior and control characteristics of each system were modeled numerically using a commercial equation solver program. The optimized dew point temperature of the DOAS was discussed on the basis of the ASHRAE standard 62.1-2007 and the current Korean ventilation standard for apartments. It was found that the optimized dew point temperature of the DOAS supply air accommodating total latent load of a space is $11-12^{\circ}C$ and the appropriate supply air temperature of the DOAS is $11-12^{\circ}C$ in cooling period and neutral temperature of $18-20^{\circ}C$ in intermediate period.

• International Journal of High-Rise Buildings
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• v.8 no.1
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• pp.71-82
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• 2019

The purpose of this study is to evaluate the indoor air quality (IAQ) and energy benefits of a dedicated outdoor air system (DOAS) and compare them with a conventional variable air volume (VAV) system. The DOAS is a decoupled system that supplies only outdoor air, while reducing its consumption using an enthalpy wheel. The VAV system supplies air that is mixed outdoor and transferred indoor. The VAV has the issue of unbalanced ventilation in each room in multiple zones because it supplies mixing air. The DOAS does not have this problem because it supplies only outdoor air. That is, the DOAS is a 100% outdoor air system and the VAV is an air conditioning system. The transient simulations of carbon dioxide concentration and energy consumption were performed using a MATLAB program based on the thermal loads from the model predicted by the TRNSYS 18 program. The results indicated that when the air volume is large, such as in summer, the distribution of air is not appropriate in the VAV system. The DOAS however, supplies the outdoor air stably. Moreover, in terms of annual primary energy consumption, the DOAS consumed approximately 40% less energy than the VAV system.

• Journal of Korean Society for Atmospheric Environment
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• v.17 no.5
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• pp.395-405
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• 2001

To make an assessment of the compatibility between DOAS and conventional point monitoring system (MCSAM-2: MS2), we investigated the concentrations of three criteria pollutants which include S $O_2$, N $O_2$, and $O_3$from a national monitoring station in Seoul during the periods of June 1999~August 2000. The average concentration values for the whole study period derived from hourly concentration data sets of those three species indicated that the mean differences between the two methods can be approximated as 18%. When the bias structure of two systems was evaluated through the computation of percent difference(PD) between the two such as ( $C_{DOAS}$- $C_{conventional}$ $C_{DOAS}$*100, differences between the two systems appeared to be quite systematic among different compounds. While the mode of bias peaked at 0~20% or 20~40% in terms of PD values, the cause of such positive bias mainly arised from generally enhanced concentration values of DOAS system. The structure of bias among different species was further assessed through linear regression analysis. Results of the analysis indicated that the dominant portions of differences observed from two monitoring systems can be accounted for by the systematic differences in their spanning and zeroing systems. S $O_2$(MS2)=0.6385 S $O_2$(DOAS)+2.0985($r^2$=0.7894) N $O_2$(MS2)=0.6548 N $O_2$(DOAS)+7.437($r^2$=0.7687) $O_3$(MS2)=1.0359 $O_3$(DOAS)-7.7885($r^2$=0.7944) The findings of slope values at around 0.64~0.65 from two species suggest that DOAS should respond more sensitively in upper bound concentration range. The offset values apart from zero indicate that more deliberate comparison needs to be made between these monitoring systems. However, based on the existence of strong correlations from at least 8,000 data points for each species of comparison, we were able to conclude that the compatibility of two monitoring systems is highly significant. With the improvement of calibration techniques for the DOAS system. its applicability for routine monitoring of airborne pollutant species is expected to be quite extendable.

• Korean Journal of Remote Sensing
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• v.34 no.2_1
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• pp.191-201
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• 2018

In this present study, we, for the first time, retrieved total column of ozone ($O_3$) and tropospheric ozone vertical profile using the Optimal Estimation (OE) method based on the MAX-DOAS measurement at the Yonsei University in Seoul, Korea. The optical density fitting is carried out using the OE method to calculate ozone columns. The optical density between the MAX-DOAS data obtained by dividing the measured intensities for each viewing elevated angle by those at the zenith angle. The retrieved total columns of the ozone are 375.4 and 412.6 DU in the morning (08:13) and afternoon (17:55) on 23 May, 2017, respectively. In addition, under 10 km altitude, the $O_3$ vertical profile was retrieved with about 5% of retrieval uncertainty. However, above 10 km altitude, the $O_3$ vertical profile retrieval uncertainty was increased (>10%). The spectral fitting errors are 16.8% and 19.1% in the morning and afternoon, respectively. The method suggested in this present study can be useful to measure the total ozone column using the ground-based hyper-spectral UV sensors.

• Korean Journal of Remote Sensing
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• v.22 no.2
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• pp.141-151
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• 2006

UV-visible absorption measurement techniques using several horizone viewing directions in addition to the traditional zenith-sky pointing have been recently developed in ground-based remote sensing of atmospheric constituents. The spatial distribution of various trace gases close to the instrument can be derived by combing several viewing directions. Multi-axis differential optical absorption spectroscopy (MAX-DOAS) technique, one of the remote sensing techniques for air quality measurements, uses the scattered sunlight as a light source and measures it at various elevation angles (corresponding to the viewing directions) by sequential scanning with a stepper motor. A MAX-DOAS system developed by GIST/ADEMRC has been applied to measuring trace gases in urban air and plumes of the volcano and fossil fuel power plant in January, May, and October 2004, respectively. MAX-DOAS spectra were analyzed to identify and quantify $SO_2,\;NO_2,\;BrO,\;and\;O_4$ (based on Slant Column Densities, SCD) in the urban air, volcanic plume, and fossil fuel power plant utilizing theirs specific structured absorption features in the UV-visible region. Vertical scan through the multiple elevation angles was performed at different directions perpendicular to the plume dispersion to retrieve cross-sectional distribution of $SO_2\;or\;NO_2$ in the plumes of the volcano and fossil fuel power plant. Based on the estimated cross sections of the plumes the mixing ratios were estimated to 580 $SO_2$ ppbv in the volcanic Plume, and 337 $NO_2\;and\;227\;SO_2$ ppbv in the plume of the fossil fuel power plant, respectively.

• 한국태양에너지학회:학술대회논문집
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• 2009.11a
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• pp.291-296
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• 2009

This paper investigates the energy saving potentials of a dedicated outdoor air system (DOAS) applied to a highrise apartment building. As for a typical $132-m^2$ apartment unit, two different HVAC systems; centralized DOAS-Ceiling Radiant Cooling Panel and decentralized Energy Recovery Ventilator-Packaged Air Conditioner were installed. Transient behavior and control characteristics of each system were modeled numerically using a commercial equation solver program, and annual cooling coil load and heating load reduction potentials were compared. The research shows that DOAS-Ceiling Radiant Cooling Panel system can reduce the cooling coil load over 21% annually compared with the current Energy Recovery Ventilator-Packaged Air Conditioner pair. In addition, over 40% of annual ventilation heating load can be reduced by use of DOAS.

• Journal of the Architectural Institute of Korea Planning & Design
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• v.34 no.11
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• pp.45-55
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• 2018

To reduce the energy consumption of HVAC system in buildings, thermally activated building system(TABS) has been applied to low energy building because of energy efficient performance and reduction of peak load. DOAS coupled with a parallel sensible cooling could be promising because TABS handles sensible heat load only. The purpose of this study was to evaluate the indoor thermal environment and cooling operation characteristic of TABS with dedicated outdoor air system(DOAS) in Korea climate. Indoor thermal environment and operation characteristic of TABS integrated with DOAS are investigated at different TABS operation schedules and climate conditions by simulation tests. The result shows that the DOAS is more suitable for hot and humid climates. And also it show that the potential of intermittent operation of TABS.