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Types and Yields of Carbon Nanotubes Synthesized Depending on Catalyst Pretreatment

  • Go, Jae-Seong;Lee, Nae-Seong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.17.2-17.2
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    • 2011
  • Double-walled carbon nanotubes (DWCNTs) were grown with vertical alignment on a Si wafer by using catalytic thermal chemical vapor deposition. This study investigated the effect of pre-annealing time of catalyst on the types of CNTs grown on the substrate. The catalyst layer is usually evolved into discretely distributed nanoparticles during the annealing and initial growth of CNTs. The 0.5-nm-thick Fe served as a catalyst, underneath which Al was coated as a catalyst support as well as a diffusion barrier on the Si substrate. Both the catalyst and support layers were coated by using thermal evaporation. CNTs were synthesized for 10 min by flowing 60 sccm of Ar and 60 sccm of H2 as a carrier gas and 20 sccm of C2H2 as a feedstock at 95 torr and $750^{\circ}C$. In this study, the catalyst and support layers were subject to annealing for 0~420 sec. As-grown CNTs were characterized by using field emission scanning electron microscopy, high resolution transmission electron microscopy, Raman spectroscopy, and atomic force microscopy. The annealing for 90~300 sec caused the growth of DWCNTs as high as ~670 ${\mu}m$ for 10 min while below 90 sec and over 420 sec 300~830 ${\mu}m$-thick triple and multiwalled CNTs occurred, respectively. Several radial breathing mode (RBM) peaks in the Raman spectra were observed at the Raman shifts of 112~191 cm-1, implying the presence of DWCNTs, TWCNTs, MWCNTs with the tube diameters 3.4, 4.0, 6.5 nm, respectively. The maximum ratio of DWCNTs was observed to be ~85% at the annealing time of 180 sec. The Raman spectra of the as-grown DWCNTs showed low G/D peak intensity ratios, indicating their low defect concentrations. As increasing the annealing time, the catalyst layer seemed to be granulated, and then grown to particles with larger sizes but fewer numbers by Ostwald ripening.

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Bale Location Effects on Nutritive Value and Fermentation Characteristics of Annual Ryegrass Bale Stored in In-line Wrapping Silage

  • Han, K.J.;McCormick, M.E.;Derouen, S.M.;Blouin, D.C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.9
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    • pp.1276-1284
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    • 2014
  • In southeastern regions of the US, herbage systems are primarily based on grazing or hay feeding with low nutritive value warm-season perennial grasses. Nutritious herbage such as annual ryegrass (Lolium multiflorum Lam.) may be more suitable for preserving as baleage for winter feeding even with more intensive production inputs. Emerging in-line wrapped baleage storage systems featuring rapid wrapping and low polyethylene film requirements need to be tested for consistency of storing nutritive value of a range of annual ryegrass herbage. A ryegrass storage trial was conducted with 24-h wilted 'Marshall' annual ryegrass harvested at booting, heading and anthesis stages using three replicated in-line wrapped tubes containing ten round bales per tube. After a six-month storage period, nutritive value changes and fermentation end products differed significantly by harvest stage but not by bale location. Although wilted annual ryegrass exhibited a restricted fermentation across harvest stages characterized by high pH and low fermentation end product concentrations, butyric acid concentrations were less than 1 g/kg dry matter, and lactic acid was the major organic acid in the bales. Mold coverage and bale aroma did not differ substantially with harvest stage or bale location. Booting and heading stage-harvested ryegrass baleage were superior in nutritive value to anthesis stage-harvested herbage. Based on the investigated nutritive value and fermentation characteristics, individual bale location within in-line tubes did not significantly affect preservation quality of ryegrass round bale silages.

Feasibility Analysis for Introduction of Scaffolding with Advanced Guardrail System to Prevent Falls (비계작업의 추락재해예방을 위한 선행 안전난간 공법의 도입 타당성 분석)

  • Park, J.D.;Moon, S.O.;Lee, H.S.;Jeong, S.C.;Kwon, Y.J.;Jung, K.
    • Journal of the Korean Society of Safety
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    • v.35 no.4
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    • pp.23-31
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    • 2020
  • In the construction sector, there were 99 fatalities from falls associated with steel tube and system scaffolds for three years from 2016 to 2018 and out of which 27.3 percent (27 workers) were found to have occurred during installing and dismantling procedure. To erect scaffolding which is installed for the work at height, the work platforms are generally installed first and the safety guardrails are installed and vice versa to dismantle. As a result, workers are exposed to the risk of falling because they erect and dismantle scaffolding without guardrails. To minimize the risk of falling, it is necessary to study a new construction method that can erect or dismantle scaffolding while guardrails are installed (called advanced guardrail system). This study analyzed advanced guardrail system in terms of safety regulation, workability and economic efficiency by investigating the domestic situation on the use of scaffolding, reviewing domestic and foreign standards for guardrails and conducting economic feasibility study. The results of this study is expected to greatly contribute to preventing falls in scaffolding installation and dismantlement procedure. As a follow-up study, empirical research is required including physical test of scaffolding with advanced guardrail system and effectiveness analysis after trial applications.

A Study on Conductivity Characteristics of X-ray Irradiated Insulating Oil (X선조사(線照射)에 의한 절연유(絶緣油)의 도전특성(導電特性)에 관한 연구(硏究))

  • Kim, Young-Il;Lee, Duck-Chool;Chung, Yon-Tack
    • Journal of radiological science and technology
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    • v.10 no.1
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    • pp.75-83
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    • 1987
  • The insulating oil used for X-ray tube housing were degraded by X-ray irrdiation, high temperature and high anode voltage for normal operation. This study was measured the conduction current-X-ray dose, heating degradation, time, temperature and electric field characteristics and the dependense of electrode materials and gap length in the X-ray irradiatied insulating oil under of D.C voltage. The obtained results can be summarized as following. 1. The conduction current of X-ray irradiated insulating oil is more about $2.5{\sim}3$ times as large as than that of non x-ray irradiated, and is become saturation phenomena after some degree. 2. The conduction current of many times heating x-ray irradiated insulating oil is more than that of a few times heating. 3. The higher temperature x-ray irradiated insulating oil is increased, the more conduction current, and that is increased about ten times as large as when it's temperatures is increased to $80^{\circ}C\;at\;30^{\circ}C$, twenty five times at $100^{\circ}C$. 4. The dependence of electrode materials is appeared at the low electric field, and the small gap length with Fe > Cu > Al. 5. The low electric field than 3000 v/cm is appeared Ohm's law region, and the high is become saturation region at the I-E characteristics. 6. The larger gap length is become, the more conduction current is increased at the same electric field.

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Comparison of microstructures in T1-1223/Ag tapes with different chemical compositions and J$_c$'s

  • Jeong, D.Y.;Kim, H.K.;Lee, H.Y.;Cha, M.K.;Ha, H.S.;Oh, S.S.;Tsuruta, T.;Horiuchi, S.
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.280-290
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    • 1999
  • The microstructures of a Tl$_{0.8}Pb_{0.2}Bi_{0.2}Sr_{1.6}Ca_2Cu_3O_{9+{\delta}}$/Ag tape (tape I ) with J$_c$ of 17,600 A/cm$^2$ at 77 K and 0 T and three Tl$_{0.8}Pb_{0.2}Bi_{0.2}Sr_{1.8}Ba_{0.2}Ca_{2.2}Cu_3O_{9+{\delta}}$/Ag tapes with J$_c$'s of 9,300 (tape II), 16,700 (tape III) and 25,200 A/cm$^2$ (tape IV)prepared using the powder-in-tube method and an in-situ reaction method, were investigated using scanning electron microscopy and high-resolution transmission electron microscopy, and compared each other. ln the tape preparation, an intermediate rolling process was incorporated during final heat-treatment for the last tape, but not for the rest of the tapes. The microstructural analysis revealed clear differences in grain-texturing, crystallographic defects and impurity phases, depending on the chemical composition of the tape. Tendency of directional grain-alignment increased in an order of tapes I, II III and IV. In tape IV, T1-1223 grains are textured, at least in local regions. In crystallographic defects, while stacking faults were prevalent in the former composition, dislocations and voids were frequently observed in the latter. Also impurity phases were appeared to be more abundant in the former than in the latter. The relationship between 1,and the microstructure in the tapes was attempted to explain in a term of grain-linking.

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Point-diffraction interferometer for 3-D profile measurement of light scattering rough surfaces (광산란 거친표면의 고정밀 삼차원 형상 측정을 위한 점회절 간섭계)

  • 김병창;이호재;김승우
    • Korean Journal of Optics and Photonics
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    • v.14 no.5
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    • pp.504-508
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    • 2003
  • We present a new point-diffraction interferometer, which has been devised for the three-dimensional profile measurement of light scattering rough surfaces. The interferometer system has multiple sources of two-point-diffraction and a CCD camera composed of an array of two-dimensional photodetectors. Each diffraction source is an independent two-point-diffraction interferometer made of a pair of single-mode optical fibers, which are housed in a ceramic ferrule to emit two spherical wave fronts by means of diffraction at their free ends. The two spherical wave fronts then interfere with each other and subsequently generate a unique fringe pattern on the test surface. A He-Ne source provides coherent light to the two fibers through a 2${\times}$l optical coupler, and one of the fibers is elongated by use of a piezoelectric tube to produce phase shifting. The xyz coordinates of the target surface are determined by fitting the measured phase data into a global model of multilateration. Measurement has been performed for the warpage inspection of chip scale packages (CSPs) that are tape-mounted on ball grid arrays (BGAs) and backside profile of a silicon wafer in the middle of integrated-circuit fabrication process. When a diagonal profile is measured across the wafer, the maximum discrepancy turns out to be 5.6 ${\mu}{\textrm}{m}$ with a standard deviation of 1.5 ${\mu}{\textrm}{m}$.

Precision and accuracy of CARS spectrometer for instantaneous temperature measurement (순간 온도 측정을 위한 CARS 분광기의 정밀 정확도 분석)

  • 박승남;박철융;한재원;길용석;정석호
    • Korean Journal of Optics and Photonics
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    • v.7 no.4
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    • pp.348-356
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    • 1996
  • A mobile CARS spectrometer is constructed to measure the instantaneous temperature of gases, of which software include the quick fit methods and a least square fitting method to obtain temperatures from the spectra. Two quick-fit-methods give smaller variance of temperatures than the least square fitting method even though they consume much shorter time to yield temperatures. The precision and accuracy of CARS temperature is measured in the graphite tube blackbody furnace in reference to a radiation pyrometer. The accuracy of the CARS temperature is $\pm$2% from 1000K to 2400K and the precision is $\pm$35K at 1600K with the most accurate quick-fit-method. As a demonstration of the instantaneous measurement, the spectrometer is applied for measurement of the turbulent combustion at a certain condition. eograms(HS) are made using a relatively small number of synthesized 2D images. The influence of aliasing artifacts caused by insufficient or improper sampling is presented, and a new sampling theory is proposed, which is used to making holographic stereograms. Also, the optical system for extension of viewing distance and viewing zone is proposed. Results of this analysis can be applied to design normal holographic stereograms and computer based holographic stereograms.

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Sinusoidal A Study on the gain Stability of the Feedback Linear Pulse Amplifiers for Fast Pulse Input (금속펄스 선형증폭기의 빠른 입력펄스에 대한 이득안정도에 관한 연구)

  • 이병선
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.11 no.3
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    • pp.1-14
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    • 1974
  • The gain stability of the nuclear pulse linear amplifiers with feedback for such a fast pulse input as the step voltage or the nuclear radiation detector pulse is analysed in detail. The expression is derived which describes the waveform at the anode circuit of the photomultiplier tube which is a part of the nuclear radiation detector. It is analysed and compared when the feedback amplifier has one and two time-constants. When these fast input pulse voltages are applied to the feedback amplifier, the effects of feedback in linearity and stability of the output voltage appear only after two or three rise-times of the amplifier, And it is proved that in order to reduce this limitation, the rise time of the feedback amplifier shou1d be less than the input pulse width. It is also shown that the above theory can be applied directly to the voltage-shunt feedback amplifier stages designed as the basic amplifier of the linear amplifier, and that the gain stability is more improved for the smaller input impedance of this amplifier stage.

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A Study on the Analysis of a Negative Pressure in the Seawater Line of a Main Centeral Cooler (MCC) for a Large LNG Ship (대형 LNG선 주냉각기 해수라인의 부압현상 해석에 관한 연구)

  • Jin, Chang-Fu;SaGong, Woon-Gon;Kim, Jong-Gyu;Kim, Chung-Sik;Song, Young-Ho;Choi, Soon-Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.6
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    • pp.893-900
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    • 2008
  • The heat exchangers in the ships have been changed from the conventional shell & tube type to the plate type due to some merits as a compactness, a high thermal efficiency and a light-weight. In recent. it is reported that the vacuum phenomena were occurred in the seawater outlet piping of a main central cooler (MCC) on the ships. From the viewpoints of a common sense, the vacuum pressure in the seawater piping is rare event and difficult to be convinced because the seawater is pumped into the piping by a seawater pump with a high discharge head. However, the occurrence of a vacuum pressure in the seawater line of an MCC is real situation and often gives a severe damage to a rubber gasket of an MCC with a plate type heat transfer area. In this study, we analyzed the vacuum pressure in the seawater line of an MCC by using the simpl Bernoulli's equation and found that the vacuum pressure in the seawater line of an MCC is inevitable untill the installation postion of an MCC is not lowered.

Studies on Root Bark of Mulberry Tree (II) -Pharmacognostical Studies on Mori Cortex Radicis- (상백피(桑白皮)에 관한 연구(硏究) (II) -상백피(桑白皮)의 생약학적(生藥學的) 연구(硏究)-)

  • Ryu, Kyung-Soo;Toh, Chung-Ae
    • Korean Journal of Pharmacognosy
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    • v.11 no.2
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    • pp.95-103
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    • 1980
  • In our country there are five species of Morus genus including Morus alba L.. Also their varieties and hybrids are distributed so much. In sucession of previous report we collected control and marketing specimens of Mori Cortex Radicis, comparative experiments were pharmacognostically carried out to identify the control specimen by the differences of external and internal morphology. It was difficult to identify marketing specimens by external morphology, because they are similar in spite of conparating with control specimen which the origin is definite. In internal morphology, medullary ray is developed near the cambium to primary bark in control specimen A(Morus alba series) and C(M. Lhou series), but less developed in B(M. bombycis series). The difference of these three series was observed. The thickness of cork layer is almost the same($7{\sim}12$ layers) in A and C series, but B is thin layer and sample E(that on the market) is generally more thick and has a stick cork cell. The kinds of starch, Ca-oxalate and latex, cell centents were same, but it was easy to identify them by the differences of their distribution. The bast fibre of D(wild specimen) and E were light lignified, latex tube of A and C series was richer distributed than others. These results show that the origin of Mori Cortex Radicis on the market can be appreciated in four groups of Korean Morus genus which are M. alba, M. bambycis, M. Lhou series and the others.

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