• Journal of Electrochemical Science and Technology
• /
• v.11 no.3
• /
• pp.282-290
• /
• 2020

In this article, we report the effect of blended cathode materials on the performance of all-solid-state lithium-ion batteries (ASLBs) with oxide-based organic/inorganic hybrid electrolytes. LiFePO₄ material is good candidates as cathode material in PEO-based solid electrolytes because of their low operating potential of 3.4 V; however, LiFePO₄ suffers from low electric conductivity and low Li ion diffusion rate across the LiFePO₄/FePO₄ interface. Particularly, monoclinic Li₃V₂(PO₄)₃ (LVP) is a well-known high-power-density cathode material due to its rapid ionic diffusion properties. Therefore, the structure, cycling stability, and rate performance of the blended LiFePO₄/Li₃V₂(PO₄)₃ cathode material in ASLBs with oxidebased inorganic/organic-hybrid electrolytes are investigated by using powder X-ray diffraction analysis, field-emission scanning electron microscopy, Brunauer-Emmett-Teller sorption experiments, electrochemical impedance spectroscopy, and galvanostatic measurements.

• Journal of Hydrogen and New Energy
• /
• v.10 no.4
• /
• pp.197-210
• /
• 1999

The hydrogen storage performance and electrochemical properties of $Zr_{1-X}Ti_X(Mn_{0.2}V_{0.2}Ni_{0.6})_{1.8}$(X=0.0, 0.2, 0.4, 0.6) alloys are investigated. The relationship between discharge performance and alloy characteristics such as P-C-T characteristics and crystallographic parameters is also discussed. All of these alloys are found to have mainly a C14-type Laves phase structure by X-ray diffraction analysis. As the mole fraction of Ti in the alloy increases, the reversible hydrogen storage capacity decreases while the equilibrium hydrogen pressure of alloy increases. Furthermore, the discharge capacity shows a maxima behavior and the rate-capability is increased, but the cycling durability is rapidly degraded with increasing Ti content in the alloy. In order to analyze the above phenomena, the phase distribution, surface composition, and dissolution amount of alloy constituting elements are examined by S.E.M., A.E.S. and I.C.P. respectively. The decrease of secondary phase amount with increasing Ti content in the alloy explains that the micro-galvanic corrosion by multiphase formation is little related with the degradation of the alloys. The analysis of surface composition shows that the rapid degradation of Ti-substituted Zr base alloy electrode is due to the growth of oxygen penetration layer. After comparing the radii of atoms and ions in the electrolyte, it is clear that the electrode surface becomes more porous, and that is the source of growth of oxygen penetration layer while accelerating the dissolution of alloy constituting elements with increasing Ti content. Consequently, the rapid degradation (fast growth of the oxygen-penetrated layer) with increasing Ti substitution in Zr-based alloy is ascribed to the formation of porous surface oxide through which the oxygen atom and hydroxyl ion with relatively large radius can easily transport into the electrode surface.

• Transactions on Electrical and Electronic Materials
• /
• v.8 no.1
• /
• pp.41-45
• /
• 2007

Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. Carbon black was added to enhance the electrical conductivity of $LiFePO_4$. The structural and morphological performance of $LiFePO_4$ and $LiFePO_4$-C powders were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). $LiFePO_4$/Li and $LiFePO_4$-C/Li cells were characterized electrochemically by cyclic voltammogram (CV), charge/discharge experiments and ac impedance spectroscopy. The results showed that the discharge capacity of $LiFePO_4$/Li cell was 147 mAh/g at the first cycle and 118 mAh/g after 30 cycles, respectively. The discharge capacity of $LiFePO_4$-C/Li cell with 5 wt% carbon black was the largest among $LiFePO_4$-C/Li cells, 133 mAh/g at the first cycle and 128 mAh/g after 30 cycles, respectively. It was demonstrated that cycling performance of $LiFePO_4$-C/Li cell with 5 wt% carbon black was better than that of $LiFePO_4$/Li cell.

• Journal of Electrochemical Science and Technology
• /
• v.9 no.3
• /
• pp.220-228
• /
• 2018

This study introduced a carbon-free electrode for $Li-O_2$ cells with the aim of suppressing the side reactions activated by carbon material. Micro-particles of poly(3,4-ethylenedioxythiophene) (PEDOT), a conducting polymer, were used as the base material for the air electrode of $Li-O_2$cells. The PEDOT micro-particles were treated with $H_2SO_4$ to improve their electronic conductivity, and LiBr and CsBr were used as the redox mediators to facilitate the dissociation of there action products in the electrode and reduce the over-potential of the $Li-O_2$ cells. The capacity of the electrode employing PEDOT micro-particles was significantly enhanced via $H_2SO_4$ treatment, which is attributed to the increased electronic conductivity. The considerable capacity enhancement and relatively low over-potential of the electrode employing $H_2SO_4$-treated PEDOT micro-particles indicate that the treated PEDOT micro-particles can act as reaction sites and provide storage space for the reaction products. The cyclic performance of the electrode employing $H_2SO_4$-treated PEDOT micro-particles was superior to that of a carbon electrode. The results of the Fourier-transform infrared spectroscopic analysis showed that the accumulation of residual reaction products during cycling was significantly reduced by introducing the carbon-free electrode based on $H_2SO_4$-treated PEDOT micro-particles, compared with that of the carbon electrode. The cycle life was improved owing to the effect of the redox mediators. The refore, the use of the carbon -free electrode combined with redox mediators could realize excellent cyclic performance and low over-potential simultaneously.

• Journal of Electrochemical Science and Technology
• /
• v.11 no.1
• /
• pp.50-59
• /
• 2020

Birnessite-type manganese dioxide (δ-MnO₂) with hierarchical micro-/mesoporosity was synthesized via sacrificial graphene template approach under mild hydrothermal conditions for the first time. Graphene template was obtained by a surfactant (cetyltrimethylammonium bromide, CTAB) assisted liquid phase exfoliation (LPE) in water. A thin PEDOT:PSS (poly (3,4-ethylene dioxythiophene): poly (styrene sulfonate)) layer was applied to improve electrical conductivity and rate capability of MnO₂. The MnO₂ (535 F g^-1 at 1 A g^-1 and 45 F g^-1 at 10 A g^-1) and MnO₂/PEDOT:PSS nanocomposite (550 F g^-1 at 1 A g^-1 and 141 F g^-1 at 10 A g^-1) delivered electrochemical performances superior to their previously reported counterparts. An asymmetric supercapacitor, composed of MnO₂/PEDOT:PSS (positive) and Fe₃O₄/Carbon (negative) electrodes, provided a maximum specific energy of 18 Wh kg^-1 and a maximum specific power of 4.5 kW kg^-1 (ΔV= 2 V, 1M Na₂SO₄) with 85% capacitance retention after 1000 cycles. The graphene-templated MnO₂/PEDOT:PSS nanocomposite obtained by a simple and green approach promises for future energy storage applications with its remarkable capacitance, rate performance and cycling stability

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.37 no.9
• /
• pp.1077-1082
• /
• 2013

To improve cycling performance, the power output of the rider and the sources of resistance (e.g., air resistance, frame stiffness, and cycle mass) must be considered. From a mechanical viewpoint, we consider how the bike frame performance can be increased while decreasing the resistance. First, to improve the competitive ability of a racing track cycle, we should consider the stiffness of the bike frame including the pedal loading and aerodynamic effects when riding. Therefore, we obtained the cross-sectional area of each part of the bike frame and then aimed to minimize the drag force through an aerodynamic parametric study. In addition, the frame should remain safe under the loading applied by the rider. Under the guidelines of the UCI (union Cycliste Internationale) regulations, the bike frame has been evaluated under the proposed loading condition, and we developed a racing track cycle for elite cyclists.

• The Journal of Advanced Prosthodontics
• /
• v.6 no.3
• /
• pp.165-170
• /
• 2014

PURPOSE. This study was aimed to evaluate effect of the desensitizing pretreatments on the micro-tensile bond strengths (${\mu}TBS$) to eroded dentin and sound dentin. MATERIALS AND METHODS. Forty-two extracted molars were prepared to form a flat dentin surface, and then they were divided into two groups. Group I was stored in distilled water while group II was subjected to a pH cycling. Each group was then subdivided into three subgroups according to desensitizing pretreatment used: a) pretreatment with desensitizer (Gluma); b) pretreatment with $CO_2$ Laser (Ultra Dream Pluse); c) without any pretreatment. All prepared surfaces were bonded with Single Bond 2 and built up with resin composite (Filtek Z250). The micro-tensile bond test was performed. Fracture modes were evaluated by stereomicroscopy. Pretreated surfaces and bonded interfaces were characterized by scanning electron microscope (SEM). The data obtained was analyzed by two-way ANOVA (${\alpha}$=0.05). RESULTS. For both sound and eroded dentin, samples treated with desensitizer showed the greatest ${\mu}TBS$, followed by samples without any treatment. And samples treated with $CO_2$ laser showed the lowest ${\mu}TBS$. SEM study indicated that teeth with eroded dentin appeared prone to debonding, as demonstrated by existence of large gaps between adhesive layers and dentin. CONCLUSION. Pretreatment with Gluma increased the ${\mu}TBS$ of Single Bond 2 for eroded and sound teeth. $CO_2$ laser irradiation weakened bond performance for sound teeth but had no effect on eroded teeth.

• Proceedings of the Safety Management and Science Conference
• /
• 2009.11a
• /
• pp.15-24
• /
• 2009

Cycling that transform human energy into mechanical energy is one of the man-machine systems out of sports fields. Benchmarking means " improving ourselves by learning from others ", therefore benchmarking toward dominant cyclist is necessary on field. the goals of this study were to provide important factors on multi-disciplines (kinematics, physiology, power, psychology) for a tailored-training program that is suitable to individual characteristics. Two cyclist participated in this study and gave consent to the experimental procedure. one was dominant cyclist (years:21 yrs, height:177 cm, mass:70 kg), and the other was non-dominant cyclist(years:21, height:176, mass:70). Kinematic data were recorded using six infrared cameras (240Hz) and QTM (software). Physiological data (VO2max, AT) were acquired according to graded exercising test with cycle ergometer and power with Wingate test used by Bar-Or et. al ( 1977) and to evaluate muscle function with Cybex. Psychological data were collected with competitive state anxiety inventory (CSAI-2) that were devised by Martens et. al (1990) and with athletes' self-management questionnaire (ASMQ) of Huh (2003). It appears that the dominant's CV(coefficient of variability) was higher than non-dominant's CV in Sports Biomechanics domain, that the dominant's values for all factors ware higher than non-dominant's values in physical, and physiological domain, and their values between cognitive anxiety and somatic anxiety were contrary to each other in psychology. Further research on multi-disciplines may lead to the development of tailored-optimal training programs applicable with key factors to enhance athletic performance by means of research including athlete, coach and parents.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.04a
• /
• pp.161-164
• /
• 2008

In recent years, carbon fiber-reinforced polymer (CFRP) has been widely used for repairing and/or strengthening structural elements in concrete. Not enough test data, however, are available to predict the long-term performance of the repaired and improved structures exposed to weathering. The objective of this research is to study the effect of freeze-thaw cycling on the behavior of reinforced concrete (RC) beams strengthened in shear with carbon fiber sheet. Six small-scale RC beams (100mm${\times]$100mm${\times]$400mm) were strengthened with CFRP in shear, subjected to up to 400 cycles freeze-thawing from -17${\sim}4^{\circ}C$, and tested to failure in four-point bending. Test result, there was no significant damage to carbon fiber sheet strengthened concrete beams had been suffered 30 cycles of freeze-thawing, and more over 60 cycles of freezing-thawing brought about a reduction in resistance of only 25% of the initial level.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2006.12a
• /
• pp.48-52
• /
• 2006

Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. Carbon black was added to enhance the electrical conductivity' of $LiFePO_4$. The structural and morphological performance of $LiFePO_4$ and $LiFePO_4$-C powders were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). $LiFePO_4$/Li and $LiFePO_4-C$/Li cells were characterized electrochemically by cyclic voltammogram (CV), charge/discharge experiments and ac impedance spectroscopy. The results showed that the discharge capacity of $LiFePO_4$/Li cell was 147 mAh/g at the first cycle and 118 mAh/g after 30 cycles, respectively. The discharge capacity of $LiFePO_4-C$/Li cell with 5wt% carbon black was the largest among $LiFePO_4-C$/Li cells, 133 mAh/g at the first cycle and 128 mAh/g after 30 cycles, respectively. It was demonstrated that cycling performance of $LiFePO_4-C$/Li cell with 5wt% carbon black was better than that of $LiFePO_4$/Li cell.