• Title/Summary/Keyword: Cycle ratio

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Radionuclides Transport from the Hypothetical Disposal Facility in the KURT Field Condition on the Time Domain (KURT 부지 환경에 위치한 가상의 처분 시설에서 누출되는 방사성 핵종의 이동을 Time Domain에서 해석하는 방법에 관한 연구)

  • Hwang, Youngtaek;Ko, Nak-Youl;Choi, Jong Won;Jo, Seong-Seock
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.4
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    • pp.295-303
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    • 2012
  • Based on the data observed and analyzed on a groundwater flow system in the KURT (KAERI Underground Research Tunnel) site, the transport of radionuclides, which were assumed to be released at the supposed position, was calculated on the time-domain. A groundwater pathway from the release position to the surface was identified by simulating the groundwater flow model with the hydrogeological characteristics measured from the field tests in the KURT site. The elapsed time when the radionuclides moved through the pathway is evaluated using TDRW (Time Domain Random Walk) method for simulating the transport on the time-domain. Some retention mechanisms, such as radioactive decay, equilibrium sorption, and matrix diffusion, as well as the advection-dispersion were selected as the factors to influence on the elapsed time. From the simulation results, the effects of the sorption and matrix diffusion, determined by the properties of the radionuclides and underground media, on the transport of the radionuclides were analyzed and a decay chain of the radionuclides was also examined. The radionuclide ratio of the mass discharge into the surface environment to the mass released from the supposed repository did not exceed $10^{-3}$, and it decreased when the matrix diffusion were considered. The method used in this study could be used in preparing the data on radionuclide transport for a safety assessment of a geological disposal facility because the method could evaluate the travel time of the radionuclides considering the transport retention mechanism.

Process Analysis on the Decontamination of Internal Surface of $UF_6$ Cylinder ($UF_6$ 실린더 내부표면 제염에 관한 공정분석)

  • Chun, Kwan-Sik;Yoo, Sung-Hyun;Cho, Young-June;Hong, Jang-Pyo;Han, Wook-Jin;Choi, Beong-Soon;Kang, Pil-Sang;Cho, Suk-Ju
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.3
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    • pp.161-165
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    • 2009
  • To evaluate the efficiency of the decontamination plant for the removal of uranium compounds deposited on the internal surface of $UF_6$ cylinder for its reuse, two demonstration tests of the plant with different ratio of ${Na_2}{CO_3}$ and ${H_2}{O_2}$ were carried out, and each test had 5 steps. The main chemical form removed by the tests was to be identified as ${Na_4}{UO_2}(CO_3)_3$. More than 50% of uranium was removed by water of the first step, and at the following steps the removal amounts were exponentially decreased. On the other hand, the result shows that the injected amount of ${Na_2}{CO_3}$, compared with that of the removed uranium, was stoichiometrically excessed. This suggests that the injected amounts of ${Na_2}{CO_3}$, the generation rate of decontaminated waste, and the decontamination steps could be reduced by a process optimization of the plant.

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Geochemical characteristics of a LILW repository I. Groundwater (중.저준위 방사성 폐기물 처분부지의 지구화학 특성 I. 지하수)

  • Choi, Byoung-Young;Kim, Geon-Young;Koh, Yong-Kwon;Shin, Seon-Ho;Yoo, Si-Won;Kim, Doo-Haeng
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.4
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    • pp.297-306
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    • 2008
  • This study was carried out to identify the characteristics of hydrochemistry controlling groundwater chemical condition in a repository site of Gyeongju. For this study, 12 bore holes of all monitoring bore holes in the study area were selected and total 46 groundwater samples were collected with depth. In addition, 3 surfacewater samples and 1 seawater sample were collected. For water samples, cations and anions were analyzed. The environmental isotopes(${\delta}^{18}O-{\delta}D$, Tritium, ${\delta}^{13}C,\;{\cdot}{\delta}^{34}S$) were also analyzed to trace the origin of water and solutes. The result of ${\delta}^{18}O\;and\;{\delta}D$ analysis showed that surface water and groundwater were originated from precipitation. Tritium concentrations of groundwater decreased with depth but high concentrations of tritium indicated that groundwater was recharged recently. The results of ion and correlation analysis showed that groundwater types of the study area were represented by Ca-Na-$HCO_3$ and Na-Cl-$SO_4$, which was caused by sea spray and water-rock interaction. Especially, high ratio of Na content in groundwater resulted from ion exchange. For redox condition of groundwater, the values of DO and Eh decreased with depth, which indicated that reducing condition was formed in deeper groundwater. In addtion, high concentration of Fe and Mn showed that redox condition of groundwater was controlled by the reduction of Fe and Mn oxides.

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The Synthesis and the Electrochemical Properties of Al Doped $V_2O_5$ (Al이 도핑된 오산화바나듐의 합성 및 전기화학적 특성)

  • Park, Heai-Ku;Joung, Ok-Young;Lee, Man-Ho
    • Applied Chemistry for Engineering
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    • v.16 no.4
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    • pp.491-495
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    • 2005
  • Vanadium pentoxide xerogels with a doping ratio of $Al/V_2O_5$ ranging from 0.01 to 0.05 were synthesized by doping Al into $V_2O_5$ xerogel via the sol-gel process. By using the synthesized $Al_xV_2O_5$, the $Li/Al_xV_2O_5$ cells were assembled to investigate the chemical and electrochemical properties. Surface morphology of the $Al_xV_2O_5$ xerogel showed an anisotropic corrugated sheet-like matrix, and the interlayer distance was about $11.5{\AA}$. The IR spectra of the $Al_xV_2O_5$ revealed that the doped Al was coordinated to the vanadyl group in $V_2O_5$. The $Al_xV_2O_5$ xerogels showed enhanced reversibility and energy density compared with the $V_2O_5$ xerogel. The specific capacity of the $Al_{0.05}V_2O_5$ xerogel was more than 200 mAh/g at 10 mA/g discharge rate, and cycle efficiency was about 90% after the 31st cycling test between 1.9 V and 3.9 V.

Analysis of Fundamental Properties and Durability of Concrete Using Coal Gasification Slag as a Combined Aggregate (석탄가스화 용융슬래그를 혼합잔골재로 사용한 콘크리트의 기초적 특성 및 내구성 분석)

  • Choi, Il-Kyung;Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.4
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    • pp.331-338
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    • 2020
  • The aim of the research is to evaluate the possibility of using coal gasification slag (CGS) as a combined aggregate for concrete mixture. To achieve this goal, the fundamental properties and the durability of concrete were analyzed depending on various combining ratio of CGS into both fine aggregate with favorable gradation and relatively coarse particles. According to the results of the experiment, slump and slump flow were increased with content of CGS regardless of crushed fine aggregate with good and poor gradations while the air content was decreased. For the compressive strength of the concrete, in the case of using the crushed aggregate with good gradation, increasing CGS content decreased compressive strength of the concrete, while when the concrete used crushed aggregate with poor gradation, the compressive strength was the maximum at 50% of CGS content. As a durability assessment, drying shrinkage was decreased and carbonation resistance was improved by increasing CGS content. On the other hand, for freeze-thawing resistance, CGS influenced adverse effect on freeze-thawing resistance. Therefore, it is known that an additional air entrainer is needed to increase the freeze-thawing resistance when CGS was used as a combined aggregate for concrete.

Characteristics of Solidified Cement of Electrokinetically Decontaminated Soil and Concrete Waste (동전기 제염 토양 및 콘크리트 폐기물의 시멘트 고화 특성)

  • Koo, Daeseo;Sung, Hyun-Hee;Hong, Sang Bum;Seo, Bum Kyoung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.1
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    • pp.83-91
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    • 2018
  • While using an electrokinetic method to analyze the characteristics of cement solidification of radioactive wastes from decontaminated uranium soil and concrete, the compressive strength, pH, electrical conductivity, irradiation effects, and volume expansion were measured for the solidified cement specimens. The workability of cement solidified from radioactive waste was about 170-190%. After the solidified cement was irradiated, the compressive strength decreased by about 15%, but met the criteria ($34kgf{\cdot}cm^{-2}$) of KORAD (Korea Radioactive Waste Agent). According to the results of SEM-EDS for solidified cement, the aluminum phase was well combined with cement, while the calcium phase was separated from cement. The volume of solidified cement in radioactive wastes was dependent on the waste-to-cement ratio and the amount of water, and increased by about 30% under the conditions used in this study. Therefore, it was concluded that permanent disposal of electrokinetically decontaminated radioactive wastes is appropriate.

An Experimental Study on the Properties of Concrete Using the Waste Gypsum (폐석고를 시멘트 대체재로 활용한 콘크리트의 특성에 관한 실험적 연구)

  • Kim, Nam Wook;Song, In;Park, Rae Seon;Bae, Ju Seong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.2
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    • pp.69-76
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    • 2007
  • As amount of waste matter rapidly increases with fast growth of cities and industry, how to dispose them has arisen as an important problem. Current policy of the government on disposal of waste is repressing generation of waste itself and in case of already generated waste, resource cycle waste management system that recycles waste after proper environmental process is getting established. Therefore recycling of waste and industrial by-products is rising hugely. One of largely wasted matters is waste gypsum, which was categorized as designated waste but changed to general since 1994. Due to disposal cost and lack of impurities removal technology, recycling of it was quite low. However, as impurities removal technology using semi-dried desulfurization process is developed lately, study on recycling of waste gypsum is going on lively. This study examines possibility of utilizing waste gypsum as alternative for concrete cement and analyzed attributes of waste gypsum before and after ball mill process to find out proper alternation ratio, and conducted strength and property tests on concrete subject whose percentage of cement use is substituted with 0, 5.0, 7.5, 10.0 and 12.5% of waste gypsum.

Contents Analysis of the Elderly Housing in the Unit "Family Life & Housing" - Focused on the 9th Grade Textbooks of Technology & Home Economics - (주생활 단원에서의 노인주거 관련 교과내용 분석 - 중학교 3학년 기술.가정 교과서를 중심으로 -)

  • Jang, Sang-Ock
    • Journal of Korean Home Economics Education Association
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    • v.20 no.2
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    • pp.31-46
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    • 2008
  • The purpose of this study is to analyze the contents of elderly housing in the unit "Family Life & Housing" in Technology & Home Economics 9th grade textbooks. The results of this study are as follows: First, the contents, illustrations, pictures, floor-plans, graphs and tables in current unit "Family Life & Housing" varied widely among textbooks and some didn't even contain these informations. Illustrations and pictures which are suit to the content and which contain positive image of space and living should be chosen. Second, most of the contents about elderly housing were concentrated on the life cycle, three-generation housing and universal design, discussed in chapter 'utility of living space.' The unification of overlapped contents and description which don't have stereotype about elderly housing are needed. Not only the interior environment but also the exterior environment of the elders and life-support service for them should be included in the contents. Contents that reflect the change of future population composition and the ratio of three-generation household are required. The elderly housing floor plan needs to be diversified in quantity such as ones which reflect the Korean characteristics or ones which enable person an independent life.

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Electrochemical Properties of Activated Carbon Supecapacitor Containing Poly(acrylonitrile) Nonwoven Separator Coated by a Hydrogel Polymer Electrolyte (Poly(acrylonitrile) 부직포 분리막에 코팅된 하이드로겔 고분자 전해질을 포함하는 활성탄 수퍼커패시터 특성)

  • Latifatu, Mohammed;Ko, Jang Myoun;Lee, Young-Gi;Kim, Kwang Man;Jo, Jeongdai;Jang, Yunseok;Yoo, Jung Joon;Kim, Jong Huy
    • Korean Chemical Engineering Research
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    • v.51 no.5
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    • pp.550-555
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    • 2013
  • A hydrogel electrolyte consisting of potassium poly(acrylate) (PAAK) (3 wt%) in 6 M KOH aqueous solution is coated on poly(acrylonitrile) nonwoven separator to examine high-rate characteristics of activated carbon supercapacitor adopting the separator. The hydrogel is homogeneously coated on the surface pores of the nonwoven separator. The electrolyte uptake of the PAAK hydrogel maintains for 24 days higher than 230% and the coated separator shows slightly lower ionic conductivity ($2.9{\times}10^{-2}Scm^{-1}$) than that ($3.6{\times}10^{-2}Scm^{-1}$) of using 6 M KOH only. The activated carbon supercapacitor adopting the coated separator shows a specific capacitance higher than $27Fg^{-1}$ at $1000mVs^{-1}$ and a retention ratio higher than 97% after the 1000th cycle. This is due to strong interfacial contact of coated hydrogel electrolyte between the activated carbon electrode and the nonwoven separator.

Increased Serum Level of Inhibin in Oligo-amenorrheic Women with Polycystic Ovaries (배란장애를 동반한 다낭성 난소인 여성에서 혈중 Inhibin 농도의 증가)

  • Roh, Jae-Sook;Yoo, Jung-Bae;Moon, Hyung;Hwang, Yoon-Yeong
    • Clinical and Experimental Reproductive Medicine
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    • v.25 no.1
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    • pp.93-102
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    • 1998
  • Normal and abnormal follicular growth and steroidogenesis depend on gonadotropins as well as intraovarian peptides, which may mediate or potentiate gonadotropin action. Inhibin also affect follicular development and steroidogenesis and may play a role in dominant follicle selection and follicular atresia. Therefore, we studied the differences of serum inhibin, gonadotropin and androgen levels in the women with only the ultrasound findings and no disorder, and polycystic ovary (PCO) with ovulatory disturbance. We prospectively analysed forty-three women with PCO. The diagnosis of PCO was based on typical appearance of the ovaries on TVS. Twelve women with regular menstrual cycle and normal ovarian morphology were selected as control. Basal levels of inhibin, luteinizing hormone (LH), follicle stimulating hormone (FSH), estradiol $(E_2)$, testosterone (T), androstenedione (ADD), dehydroepiandrosterone-sulfate (DS), prolactin and TSH in serum were determined. There were significant differences in basal LH levels and LH/FSH ratio between the control and the women with PCO. The basal levels of inhibin and $E_2$ in the oligo-amenorrheic PCO (N=34) were significantly higher than those in the control. There was higher negative correlation between the inhibin and T levels in the oligo-amenorrheic PCO, but, not in the regular cycling PCO. Also, there was higher positive correlation between the LH and T levels in the oligo-amenorrheic PCO, but not in the regular cycling PCO. These data presume that the initial event of PCO is elevated pituitary LH secretion. Elevated levels of LH may down-regulate LH receptors on granulosa cells and also cause hypertrophy of the thecal layer. High level of androgen secreted by the hypertrophied thecal layer may stimulate inhibin secretion from granulosa cells and can be converted to estrogen by extraovarian tissues and could serve to augment pituitary sensitivity to GnRH with a resultant secretion of more LH than FSH. Inhibin may inhibit FSH action on granulosa cell in the PCO follicle, impairing follicular development and dominant follicle selection resulted in ovulatory disturbance.

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