• Title/Summary/Keyword: Cu content

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The Evaluation of Thermal Properties for W-Cu Composite Sintered from Mechanically Alloyed Powders (기계적 합금화한 W-Cu 복합분말 소결체의 열물성 평가)

  • 오낭렴;김대건;석명진;김영환;김영도;문인형
    • Journal of Powder Materials
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    • v.7 no.3
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    • pp.154-160
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    • 2000
  • In order to enhance sinterability of W-Cu composites used for heat sink materials, mechanical alloying process where both homogeneous mixing of component powders and fine dispersion of minor phase can be easily attained was employed. Nanostructured W-Cu powders prepared by mechanical alloying showed W grain size ranged of 20-50 nm and were able to be efficiently sintered owing to the fine particle size as well as uniform distribution of Cu phase. The thermal properties such as electrical resistivity, coefficient of thermal expansion and thermal conductivity were evaluated as functions of temperature and Cu content. It was found that the coefficient of thermal expansion could be controlled by changing Cu content. The measured electrical resistivities and thermal diffusivities were also varied with Cu content. The thermal conductivities calculated from the values of resistivities and diffusivities showed similar tendency as a function of temperatures. However, this is in contradiction with thermal conductivities of pure W and Cu which decrease with increasing temperature.

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Pretreatment for Cu electroplating and Etching Property of Cu-Cr Film (Cu-Cr합금 박막의 구리 전기도금을 위한 전처리 및 에칭 특성에 관한 연구)

  • Kim, N. S.;Kang, T.;Yun, I. P.;Park, Y. S.
    • Journal of the Korean institute of surface engineering
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    • v.26 no.3
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    • pp.149-157
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    • 1993
  • In the study of TAB(Tape Automated Bonding)technologies, Cu-Cr sputtered seed layer has been used to improve the adhesion between Polyimide and Cu film and electrical properties. But the Cu electrodeposit on Cu-Cr film had poor adhesion or powder-like form due to the surface Cr oxides on the Cu-Cr film. By means of activating the Cu-Cr film with the oxalic acid and phosphoric acid, the Cu film with the improved adhesion could be coated on the Cu-Cr sputtered film in CuSO4 solution. The etching rate was compared with increasing the Cr content of the sputtered Cu-Cr film, and anodic polarization curve in FeCl3 solution was investigated. With increasing the Cr content, the etching rate was reduced. The clean etching cross section could be obtained with increasing the concentration of FeCl3 solution. But above the 13 w/o Cr content, Cu-Cr sputtered film could not bed etched cleanly only with FeCl3 solution and additives were needed.

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Effect of Cu Content on Microstructural and Magnetic Properties of a Nd-Fe-B Strip Cast (Cu 첨가에 따른 Nd-Fe-B strip cast의 미세조직과 자기적 특성의 상관관계)

  • Park, Song-E;Kim, Tae-Hoon;Lee, Seong-Rae;Kim, Dong-Hwan;NamKung, Seok;Jang, Tae-Suk
    • Journal of Powder Materials
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    • v.18 no.1
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    • pp.24-28
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    • 2011
  • Effect of Cu content on microstructural and magnetic properties of a $(Nd_{26.06},Dy_{6.51})Fe_{bal.}$ $Cu_xB_{0.97}$(wt.%), (x = 0.2, 0.3, 0.4, 0.5) strip-cast was studied. The average inter-lamellar spacing in the free surface and wheel side of the strip cast increased as the Cu content increases. The grain uniformity, the grain alignment, and (00L) texture of the strip cast increased with Cu contents up to 0.4 wt.%. These microstructural changes were attributed to the decrease of the effective cooling rate of the melted alloy caused by the decrease of the melting temperature of resulting from Cu addition. Coercivity and remanence were increased because of the grain alignment and (00L) texture improvement with Cu contents up to 0.4 wt.%.

Thermal behavior of Cu-Cr Alloy Films sputter-deposited onto polyimide (폴리이미드에 스퍼터 증착된 Cu-Cr 합금박막의 열처리 거동)

  • 임준홍;이태곤;김영호;한승희
    • Journal of the Korean institute of surface engineering
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    • v.27 no.5
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    • pp.273-284
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    • 1994
  • Thermal behavior of Cu-Cr thin alloy films has been investigated by SEM, AES, and TEM. Cu-Cr alloy films containing 3wt% Cr, 8wt% Cr have been sputter-deposited onto polyimide substrates and heat treated at $400^{\circ}C$ for 2hrs in the various atmosphere. Before heat treatment, Cu and Cr content in the film are uniform through the thickness and oxygen content in the film is negligible. Redistribution of Cr, Cu, and O in the film due to heat treatment depends on the Cr content and heat treatment atmoshpere. There kinds of thermal behavior are ascribed to the formation of surface and interface oxides as well as internal oxidation. Hillocks are observed on the surface of Cu-Cr alloy films which have been heat treated in N2. The hillocks are composed of large grainss of Cu.

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Composition and magnetic ProPerties of CoFecu alloys according to electrolysis conditions (전해조건에 따른 CoFeCu 함금박막의 조성, 우선방위 및 자기적 특성)

  • 예길촌
    • Journal of the Korean institute of surface engineering
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    • v.30 no.1
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    • pp.3-12
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    • 1997
  • The composition, the preferred orientation and the magnetic properties of the CoFeCu alloys electrodepositen under various electrolysis conditions in sulfate baths ware investigated. As the D.C. current density increased, the Co content in alloy electrodeposits increased, while the Cu content decreased and Fe content remained content. The effect of magnetic field up to 300 Oe on the composition of alloys was negligible. The Cu content of the alloys deposited in pulse current increased noticeably with increasing off-time, while the Co and Fe content decreased. The coercivity of the alloys with 3.5 to 7.0wt.% Cu was 1.0 to 2.0 Oe, but increased noticeably above and below that composition. The application of magnetic field during deposition decreased the coercivity of alloys. The saturation flux density of the alloys with 3.5 to 5.0wt.% Cu was relatively high in the range from 16 to 20.7Gauss. The anisotropy field(HK) of the alloys deposited under the magnetic field(50∼300 Oe) ranged from 18 to 22 Oe. The alloys had fcc structure with (111) preferred orientation, whose distribution increased a little with increasing magnetic field.

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Thermal Properties according to Content and Alignment of Carbon Fiber in Cu Matrix Composite Reinforced with Chopped Carbon Fiber (탄소 단섬유가 첨가된 Cu기지 복합재료의 섬유 분율 및 배열에 따른 열적 특성)

  • Kim, Minkyoung;Han, Jun Hyun
    • Korean Journal of Materials Research
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    • v.31 no.11
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    • pp.626-634
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    • 2021
  • Cu matrix composites reinforced with chopped carbon fiber (CF), which is cost effective and can be well dispersed, are fabricated using electroless plating and hot pressing, and the effects of content and alignment of CF on the thermal properties of CF/Cu composites are studied. Thermal conductivity of CF/Cu composite increases with CF content in the in-plane direction, but it decreases above 10% CF; this is due to reduction of thermal diffusivity related with phonon scattering by agglomeration of CF. The coefficient of thermal expansion decreases in the in-plane direction and increases in the through-plane direction as the CF content increases. This is because the coefficient of thermal expansion of the long axis of CF is smaller than that of the Cu matrix, and the coefficient of thermal expansion of its short axis is larger than that of the Cu matrix. The thermal conductivity is greatly influenced by the agglomeration of CF in the CF/Cu composite, whereas the coefficient of thermal expansion is more influenced by the alignment of CF than the aggregation of CF.

A Study on the Content of Trace Constituents in Dried Milk Powder (粉乳의 微量 營養成分에 관한 연구)

  • Kim, Dae-Seon;Ha, Man-Kwang;Lee, Won-Chang
    • Journal of Environmental Health Sciences
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    • v.13 no.1
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    • pp.67-71
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    • 1987
  • This study was intended to investigate the content of Cu, Mn, Zn in the dried milk powders except infant formula milkpowder from January to March, 1986. The content of the trace metals was determined by Atomic Absorption Spectrophotometry. The results were as follows: 1. Averages of Cu, Mn, Zn in the total samples were Cu, 0.3043 ppm Mn, 0.5101 ppm Zn, 26.006 ppm. 2. Averages and ranges of Cu, Mn, Zu in the whole milk powder were Cu, 0.2483, 0.216 - 0.48 Mn, 0.552 ppm, 0.336 - 0.732 ppm Zn, 28.961 ppm, 7.5 - 51.9 ppm. 3. Averages and ranges of Cu, Mn, Zn in the skim milk powder were Cu, 0.4095 ppm, 0.3 - 0.54 ppm Mn, 0.6907 ppm, 0.348 - 0.84 ppm Zn, 38.381 ppm, 30.6 - 55.2 ppm. 4. Averages and ranges of Cu, Mn, Zn in the modified milk powder were Cu, 0.3459 ppm, 0.12 0.948 ppm Mn, 0.2414 ppm, 0.096 - 0.348 ppm Zn, 7.752 ppm, 1.2 - 17.002 ppm. 5. It showed the highest amount of Cu, Mn, Zu in the skim milk powder group than in the other group and the lowest amount of Cu in the whole milk powder group and Mn, Zn in the modified milk group.

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Effect of Cu on Hot Ductility Behavior of Low Carbon Steel (저탄소강의 열간 연성 거동에 미치는 Cu의 영향)

  • Son, Kwang Suk;Park, Tae Eun;Park, Byung-Ho;Kim, Donggyu
    • Korean Journal of Metals and Materials
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    • v.47 no.4
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    • pp.217-222
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    • 2009
  • Cu as a tramp element has been reported to encourage transverse cracking upon straightening operation during continuous casting or mini-mill processing. Therefore, the hot workability of steels containing Cu should be investigated. The purpose of the present study was to examine the effect of Cu contents on the hot ductility of low carbon steels by using hot compression test. Hot compression test was carried out using a Gleeble. The specimens were heated to $1300^{\circ}C$ for solution treatment and then held for 300s before cooling at a rate of $1^{\circ}C/s$ to test temperatures in the range of $650{\sim}1150^{\circ}C$ ($50^{\circ}C$ intervals) with strain rate of $5{\times}10^{-3}/s$. In Cu containing steels, the hot ductility was decreased with increasing Cu content at high temperature region which is to be attributed to copper enriched phase formed at scale/steel interface, and low hot ductility with increasing Cu content at low temperature region is attributable to the strengthening of matrix by the formation of ${\varepsilon}-Cu$. The width of ductility trough region was decreased with increasing Cu content.

The Effect of Composition on the Properties of NiCuZn ferrites (NiCuZn ferrite의 특성에 미치는 조성의 영향)

  • 남중희;정현학;신재영;오재희
    • Journal of the Korean Magnetics Society
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    • v.5 no.3
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    • pp.191-196
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    • 1995
  • NiCuZn ferrites were prepared by a solid-state reaction and sintered at $900^{\circ}C$ for 5 hours. Its properties were investigated by controlling the ferrite composition and processing. NiCuZn ferrite with a composition of ${(Ni_{0.2}Cu_{0.2}Zn_{0.6}O)}_{1.02}{(Fe_{2}O_{3})}_{0.98}$ was found to have the maximum initial permeability as a result of the variation of Cu content and the (Ni+Cu)/Zn ratio. Curie temperature($T_{c}$) of NiCuZn ferrite was decreased with the larger Cu content and increased with the larger Ni content. NiCuZn ferrites of ${(Ni_{0.2}Cu_{0.2}Zn_{0.6}O)}_{1-w}{(Fe_{2}O_{3})}_{1+w}$ composition milled for 20~80 hours had the maximum initial permeability at w=-0.015 and Curie temperature ($T_{c}$) was decreased with the increasing of $Fe_{2}O_{3}$ deficiency(w).

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Influence of Cu and Zn Contents on the Properties of Al-Fe-Cu-Mg Based Casting Alloys (Cu 및 Mg 첨가량에 따른 Al-Fe-Cu-Mg계 주조합금의 특성변화)

  • Kim, Jeong-Min;Kim, Nam-Hoon;Shin, Je-Sik;Kim, Ki-Tae;Ko, Se-Hyun
    • Journal of Korea Foundry Society
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    • v.34 no.4
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    • pp.130-135
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    • 2014
  • Efforts have been made to develop new silicon-free aluminum casting alloys that possess high electrical and thermal conductivity. In this research Al-Fe-Cu-Mg alloys with various Cu and Mg contents were investigated for their various properties. As the Cu or Mg content was increased, the electrical conductivity gradually decreased, while the tensile strength of the Al-Fe-Cu-Mg alloy tended to be improved. It was found that fluidity was generally inversely proportional to the Cu content, but the alloys containing 1%Mg showed considerably low fluidity, regardless of the Cu content.