• 제목/요약/키워드: Crystal-field parameters

검색결과 66건 처리시간 0.024초

Spectroscopic effects of negative and positive stresses on the transition metal-ion activated sapphire fibers

  • Lim, Ki-Soo
    • 한국광학회:학술대회논문집
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    • 한국광학회 1990년도 제5회 파동 및 레이저 학술발표회 5th Conference on Waves and lasers 논문집 - 한국광학회
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    • pp.115-120
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    • 1990
  • The spectroscopic properties of Cr3+-doped sapphire and Ti3+-doped sapphire fibers are reported. Tensile stress produces blue shifts of the R lines and changes in their radiative lifetimes and integrated intensities which can be correlated to stress-induced changes of the crystal-field parameters in a Cr3+-doped sapphire fiber. A net red shift of the zero phonon fluorescence line of 2Eg state and a decrease of the splittings of 2T2g state with uniaxial stress are observed in a Ti3+-doped sapphire. In excitation spectra the two peaks from the 2Eg state are shifted to the blue with different rates. The changes are attributed to the stress-induced changes of crystal field and Jahn-Teller effect.

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Effects of Surface Termination on Directional Emission from Photonic Crystal Waveguides

  • Chung, K.B.
    • Journal of the Optical Society of Korea
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    • 제12권1호
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    • pp.13-18
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    • 2008
  • We numerically investigate by the finite-difference time-domain method the effects of surface termination on directional emission exiting a photonic crystal waveguide. The directed power and far-field beam profile for the original proposal [E. Moreno et al., Phys. Rev. B 69, 121402 (2004)] and its enhancement [S. K. Morrison et al., Appl. Phys. Lett. 86, 081110 (2005)] are computed for different values of some important parameters. We find another surface termination condition with a positive surface displacement in the structure of the original proposal which has a negative surface displacement. Our surface termination is more effective than the original structure, and nearly as effective as the termination for the enhancement, for directional emission. Besides, our termination is simpler than that for the enhancement. We confirm the effectiveness of directional emission from our termination in its far-field beam profile, radiation intensity distribution, and additionally the wave-vector space representation by the Fourier analysis.

A Study on the Surface Finishing Technique using Electrorheological Fluid

  • Park, Sung-Jun;Kim, Wook-Bae;Lee, Sang-Jo
    • International Journal of Precision Engineering and Manufacturing
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    • 제5권2호
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    • pp.32-38
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    • 2004
  • The electrorheological(ER) fluid has been used to the ultraprecision polishing of single crystal silicon as new polishing slurry whose properties such as yield stress and particle structure changed with the application of an electric field. In this work, it is aimed to find the effective parameters in the ER fluid on material removal in the polishing system whose structure is similar to that of the simple hydrodynamic bearing. The generated pressure in the gap between a moving wall and a workpiece, as well as the electric field-induced stress of the mixture of ER fluid-abrasives, is evaluated experimentally, and their influence on the polishing of single crystal silicon is analyzed. Moreover, the behavior of abrasive and ER particles is described.

Fringe-Field Switching Transflective Displays

  • Lim, Y.J.;Choi, M.O.;Lee, S.H.;Song, J.H.;Jeong, Y.H.;Kim, H.Y.;Kim, S.Y.;Lim, Y.J.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.419-422
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    • 2005
  • We have studied transflective liquid crystal displays (LCDs) associated with fringe-field switching (FFS) mode to achieve high image quality. In the past, several cell structures were used to fabricate transflective FFS liquid crystal display s. Their structures and characteristics are carefully examined to find their merits and cons. Further, optimization of cell parameters to achieve a single driving circuit is performed.

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Fringe-Field 구동형 반사형 Hybrid Aligned Nematic 액정 디스플레이의 전기-광학 특성 (Electro-Optic Characteristics of the Fringe-Field driven Reflective Hybrid Aligned Nematic Liquid Crystal Display)

  • 정태봉;박지혁;손정석;이종문;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.972-975
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    • 2003
  • We have performed computer simulation to obtain electro-optic characteristics of reflective hybrid aligned nematic liquid crystal displays driven by fringe field. The results show that the optimal retardation value of the cell is $0.289{\mu}m$, which allows for the cell to have a practical cell gap of larger than $3{\mu}m$ when manufacturing. A reflectance of the dark state is only 0.114% for an incident light 550nm. At this condition, the light efficiency of white state reaches 92.7%. Further, we have studied a new reflective display with polarizer, optical compensation with half plate, LC plus reflector. The display with optimized cell parameters shows low wavelength dispersion and the contrast ratio greater than 5 over exists about $120^{\circ}$ in vertical direction and $160^{\circ}$ in horizontal direction.

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SOI소자 제죠를 위한 ZMR공정의 모델링 (Modelling of ZMR process for fabrication of SOI)

  • 왕종회;김도현
    • 한국결정성장학회지
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    • 제5권2호
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    • pp.100-108
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    • 1995
  • SOI구조를 얻기 위한 방법의 한가지인 ZMR공정에 있어서 열전달은 계면의 위치와 모양을 결정하는 중요한 역할을 한다. 본 연구에서는 SOI구조를 얻기 위한 ZMR공정중의 열전달 공정을 모사할 수 있는 의사정상상태 2차원 ZMR모델을 수립하였다. 본 모델은 복사, 전도 그리고 대류 열전달을 포함하며, 고/액 계면의 위치를 결정한다. 모델로부터 구한 수치해는 실리콘 기판의 용융부에서의 유동장, 전체 SOR구조에서의 온도장 그리고 실리콘 박막과 기판에서의 고/액 계면의 위치를 포함한다. 여러 공정 변수들의 변화에 따른 온도장과 계면의 형상과 폭의 변화를 알아보았다.

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PbWO4 : Gd 단결정 내의 Gd3+ 상자성 이온에 대한 바닥 상태 에너지 (Ground State Energy of Gd3+ Paramagnetic Ion in PbWO4 : Gd Single Crystal)

  • 염태호
    • 한국자기학회지
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    • 제26권2호
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    • pp.45-49
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    • 2016
  • 분광학적 분리인자 $g_{ij}$와 영자기장 갈라지기 상수 값 $B_k^q$ 값을 유효 스핀 하밀토니안에 사용하여, $PbWO_4$ : Gd 단결정 내의 정방정계 대칭성 자리에 위치하고 있는 $Gd^{3+}$ 상자성 불순물 이온(유효전자 스핀 S = 7/2)의 바닥상태에서의 에너지 준위를 계산하였다. 외부 자기장이 영일 경우의 $Gd^{3+}$ 이온의 영자기장 갈라지기 값은 $PbWO_4$ : Gd 단결정의 방향에 관계없이 모두 같았고, 이때 ${\mid{\pm}7/2}$ > ${\leftrightarrow}{\mid{\pm}5/2}$ >, ${\mid{\pm}5/2}$ > ${\leftrightarrow}{\mid{\pm}3/2}$ >, ${\mid{\pm}3/2}$ > ${\leftrightarrow}{\mid{\pm}1/2}$ > 전이 사이에서 계산된 에너지 간격은 각각, 6.9574 GHz, 6.9219 GHz, 15.8704 GHz이다. 결정학적 축에 대하여 외부 자기장을 가하는 방향에 따라서 서로 다른 에너지 준위 값을 나타내었다. 이중 외부자기장이 결정학적 주축 a- 및 c-축에 나란할 경우에 에너지 준위를 계산하여 논의하였다.

Syndiotactic isoregic 폴리비닐플로라이드 결정의 Force Fields 및 Elastic Properties (Force Fields and Elastic Properties of Syndiotactic Isoregic Poly(viny1 fluoride) Crystal)

  • ;이정구;홍진후
    • 한국재료학회지
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    • 제4권7호
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    • pp.792-797
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    • 1994
  • 6-31G $\ast$ $\ast$ basis set을 이용한 ab initio 양자역학적 방법에 의하여 2,4,6- trifluoroheptane구조를 구함으로서 syndiotactic isoregic PVF결정의 force field를 유도하였다. 또 그 결과를 PVF의 structure parameter및 elastic constant를 계산하는데 응용하였다. 그 결과 cell parameter는 각각 a(5.205$\AA$: chain axis), b(8.457 $\AA$) 및 c(4.621 $\AA$)로 나타났으며 X-ray data(5.04$\AA$, 8.57$\AA$, 및 4.95$\AA$)결과와 비교적 잘 일치함을 알 수 있었다. Defect 비존재하에서의 syndiotactic PVF결정의 Young's 모듈러스 계산값은 267Gpa로 나타났으며, polyvinylideme fluoride(277-293 GPa)및 polyethylene(264-337 GPa)결정의 경우와 비슷한 수준으로 나타났다. 또한 optimum geometry에서 얻어진 bulk modulus값은 experimental geometry 에서 얻어진 값보다 두배의 차이를 보였으며, 이것은 geometry 에 따른 elastic compliance constant(특히 $S_{33}$인자)가 크게 달라지기 때문인 것으로 나타났다.

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Crystal Structure and Magnetic Properties of Sodium-Iron Phosphates NaFe0.9Mn0.1PO4 Cathode Material

  • Seo, Jae Yeon;Choi, Hyunkyung;Kim, Chul Sung;Lee, Young Bae
    • Journal of the Korean Physical Society
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    • 제73권12호
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    • pp.1863-1866
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    • 2018
  • The sodium-iron phosphate maricite-$NaFe_{0.9}Mn_{0.1}PO_4$ was synthesized using the ball mill method. The crystal structure and magnetic properties of the prepared materials were studied using X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and $M{\ddot{o}}ssbauer$ spectroscopy. Structural refinement of maricite-$NaFe_{0.9}Mn_{0.1}PO_4$ was analyzed using the FullProf program. From the XRD patterns, the crystal structure of maricite-$NaFe_{0.9}Mn_{0.1}PO_4$ was found to be orthorhombic with the space group Pmnb. The lattice parameters of maricite-$NaFe_{0.9}Mn_{0.1}PO_4$ are as follows: $a_0=6.866{\AA}$, $b_0=8.988{\AA}$, $c_0=5.047{\AA}$, and $V=311.544{\AA}^3$. Maricite-$NaFePO_4$ has an edge-sharing structure that consists of $FeO_6$ octahedral. Under an applied field of 100 Oe, the temperature dependences of zero-field-cooled (ZFC) and field-cooled (FC) curves were measured from 4.2 to 295 K. $M{\ddot{o}}ssbauer$ spectra were also recorded at various temperatures ranging from 4.2 to 295 K. We thus confirmed that the $N{\acute{e}}el$ temperature of $NaFe_{0.9}Mn_{0.1}PO_4$ ($T_N=14K$) was lower than that of maricite-$NaFePO_4$ ($T_N=15K$).

Influence of processing parameters for adhesion strength of TiN films prepared by AIP technique

  • ;주윤곤;조동율;윤재홍;송기오
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2007년도 추계학술대회 논문집
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    • pp.140-141
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    • 2007
  • The arc ion plating (AIP) technique has been used widely for thin coating in the area of surface engineering. The TiN coating is important in the field of dies, cutting tools and other mechanical parts. When forming the TiN films by AIP technique, the processing parameters such as arc power, bias voltage, working pressure, temperature of substrate and pre-treatment affected the adhesion respectively. The results of scratch test revealed that the adhesion strength was influenced by arc power most strongly. And a sequence of the importance of each parameters has been obtained. The crystal structure and cross-section of TiN films are also be investigated.

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