• 제목/요약/키워드: Cross diffusion

검색결과 331건 처리시간 0.024초

고분자전해질 연료전지의 동작압력에 대한 가스 확산층의 위치 별 전류밀도 및 수분거동에 대한 수치해석 (Numerical Modeling of Current Density and Water Behavior at a Designated Cross Section of the Gas Diffusion Layer in a Proton Exchange Membrane Fuel Cell)

  • 강신조;김영배
    • 대한기계학회논문집B
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    • 제36권2호
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    • pp.161-170
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    • 2012
  • 고분자 전해질 연료전지에서 물 관리는 연료 전지성능에 영향을 미치는 중요한 요인이다. 공급되는 수분의 양이 적을 경우 수소이온의 이동을 담당하는 전해질의 건조현상으로, 수분의 양이 과다할 경우 반응이 일어나는 촉매층과 전해질 삼상 계면에서의 홍수현상으로 성능을 감소시키거나 동작을 멈추게 하므로 이 부분에 대한 많은 연구가 진행되고 있다. 본 논문에서는 연료전지 수분에 영향을 주는 요소 중, 연료극과 공기극에 공급되는 상대습도를 100%로, 동작온도를 $80^{\circ}C$로 설정한 후, 입구 측에 압력을 변화하면서, 다중물리응용 수치해석을 포함하고 유한요소를 통하여 비선형 편미분 방정식이 결부된 상용코드를 이용하여 전체적인 전기화학반응 및 성능에 대한 해석을 수행하고 공기극 측의 가스 확산층에 각 위치별 전류밀도 분포와 수분포화의 분포, 압력차에 의한 동작물질의 속도 등을 분석하여 보았다. 본 연구를 통하여 얻어진 결과는 연료전지의 성능은 압력의 세기에 따라 달라지며 압력이 높을수록 성능과 위치별 최대 전류밀도가 높게 나타났으며, 공기극의 가스 확산층에서의 수분함량은 높은 압력에서보다 낮은 압력에서 수분함량이 많은 것으로 나타났으며 특히 전극의 바로 아래 부분에서의 수분이 더 많이 응축되어 나타났으며 공기극 가스 확산층에서의 동작물질의 속도는 동작물질의 입구방향에서 출구측으로 진행할수록 그 변동 폭이 크게 나타났다.

감초 플라보노이드 Liquiritin 및 Liquiritigenin을 담지한 피부전달체인 셀룰로오스 다공성 하이드로젤 제형 개발 (Development of Porous Cellulose Hydrogel for Enhanced Transdermal Delivery of Liquiritin and Liquiritigenin as Licorice Flavonoids)

  • 김수지;권순식;유은령;박수남
    • 폴리머
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    • 제38권5호
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    • pp.676-681
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    • 2014
  • 한약재로 널리 사용되는 감초는 항산화/항염증 등의 작용을 나타내는 배당체 liquiritin 및 그 아글리콘인 liquiritigenin과 같은 플라보노이드를 함유하고 있다. 본 연구에서는 피부 전달체로 이들 플라보노이드를 함유하는 하이드로젤을 제조하고 그 특성과 피부 투과능을 조사하였다. 셀룰로오스와 NaOH/urea(1~10%) 용액 및 가교제로서 에피클로로하이드린을 사용하여 셀룰로오스 다공성 하이드로젤을 제조하였다. Liquiritin 및 liquiritigenin 담지를 위한 최적의 하이드로젤은 셀룰로오스 용해를 위해 사용된 1~10%의 우레아 농도 중 6% 우레아 용액에서 제조된 하이드로젤이 동적 점탄성 및 수분 흡수능이 가장 우수한 것으로 나타났다. SEM으로 관찰한 결과, 제조된 하이드로젤의 단면은 다공성을 나타내었다. Franz diffusion cell을 이용한 in vitro 피부투과 실험 결과, 감초 플라보노이드 함유하이드로젤은 대조군보다 더 높은 피부 투과능을 나타내었다. 이상의 결과들은 셀룰로오스 다공성 하이드로젤이 감초 플라보노이드의 경피 전달에 있어 효율적인 피부 전달체로 이용 가능성이 있음을 시사한다.

Effects of the Combination Herbal Extract on Working Memory and White Matter Integrity in Healthy Individuals with Subjective Memory Complaints : A Randomized, Double-Blind, Placebo-Controlled Clinical Trial

  • Kwon, Oran;Lee, Sunho;Ban, Soonhyun;Im, Jooyeon J.;Lee, Doo Suk;Lee, Eun Hee;Kim, Joohee;Lim, Soo Mee;Lee, Sang Gon;Kang, Ilhyang;Kim, Kyung-Hee;Yoon, Sujung;Lee, Sun Hea
    • 생물정신의학
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    • 제22권2호
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    • pp.63-77
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    • 2015
  • Objectives The combination extract of four kinds of herbs, Gastrodia elata, Liriope platyphylla, Dimocarpus longan, and Salvia miltiorrhiza, has shown to have memory improving effects in mice. The aim of this study was to investigate the efficacy and safety of the herbal mixture for improving working memory as well as microstructural changes in white matter integrity in individuals with subjective memory complaints. Methods Seventy-five individuals with subjective memory complaints were assigned to receive either placebo (n = 15) or herbal mixture (low-dose group, n = 30 and high-dose group, n = 30) supplementation in an 8-week, randomized, double-blind, placebo-controlled clinical trial. Changes in working memory performance and fractional anisotropy (FA) values reflecting white matter integrity from baseline to 8-week endpoint were assessed. Results The herbal mixture group showed an increase in working memory performance compared to the placebo group (p for interaction = 0.001). In addition, the herbal mixture group showed an increase in FA values in the temporo-parietal regions (corrected p < 0.05), which are crucially involved in working memory function and are among the most affected regions in patients with cognitive impairments. Conclusions Findings from this study indicate that the herbal mixture may be a promising therapeutic option for individuals with subjective memory complaints.

강판 보강 집성재 보의 휨성능 평가 연구 (Evaluation on Flexural Performance of Steel Plate Reinforced GLT Beams)

  • 박금성;이상섭;곽명근
    • 한국공간구조학회논문집
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    • 제20권2호
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    • pp.39-49
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    • 2020
  • In this study, we will develop a hybrid cross-sectional shape of steel inserted type glued-laminated timber that can improve the strength of structural glued-laminated timber and maximize the ductility by using steel plate with excellent tensile and deformation ability. A total of three specimens were fabricated and the flexural performance test was carried out to evaluate the structural performance of the steel inserted type glued-laminated timber. In order to compare the effect of steel inserted glued-laminated timber, one structural glued-laminated timber test specimen composed of pure wood was manufactured. In addition, in order to evaluate the adhesion performance of the steel inserted, one each of a screw joint test specimen and a polyurethane joint test specimen was prepared. As a result, all the specimens showed the initial crack in the finger joint near the force point. This has been shown to be a cause of crack diffusion and strength degradation. The use of finger joints in the maximum moment section is considered to affect the strength and ductility of the glued-laminated timber beam. Polyurethane-adhesive steel inserted glued-laminated timber showed fully-composite behavior with little horizontal separation between the steel plate and glued-laminated timber until the maximum load was reached. This method has been shown to exhibit sufficient retention bending performance.

소오스/드레인 영역의 도펀트 양의 증가에 따른 코발트실리사이드의 물성변화 (Influence of Dose on the Property of Cobalt Silicides in Source/Drain Area)

  • 정성희;송오성;김민성
    • 한국재료학회지
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    • 제13권1호
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    • pp.43-47
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    • 2003
  • As and BF$_2$dopants are implanted for the formation of source/drain with dose of 1${\times}$10$^{15}$ ions/$\textrm{cm}^2$∼5${\times}$10$^{15}$ ions/$\textrm{cm}^2$ then formed cobalt disilicide with Co/Ti deposition and doubly rapid thermal annealing. Appropriate ion implantation and cobalt salicide process are employed to meet the sub-0.13 $\mu\textrm{m}$ CMOS devices. We investigated the process results of sheet resistance, dopant redistribution, and surface-interface microstructure with a four-point probe, a secondary ion mass spectroscope(SIMS), a scanning probe microscope (SPM), and a cross sectional transmission electron microscope(TEM), respectively. Sheet resistance increased to 8%∼12% as dose increased in $CoSi_2$$n^{+}$ and $CoSi_2$$p^{V}$ , while sheet resistance uniformity showed very little variation. SIMS depth profiling revealed that the diffusion of As and B was enhanced as dose increased in $CoSi_2$$n^{+}$ and $CoSi_2$$p^{+}$ . The surface roughness of root mean square(RMS) values measured by a SPM decreased as dose increased in $CoSi_2$$n^{+}$ , while little variation was observed in $CoSi_2$$p^{+}$ . Cross sectional TEM images showed that the spikes of 30 nm∼50 nm-depth were formed at the interfaces of $CoSi_2$$n^{+}$ / and $CoSi_2$/$p^{+}$, which indicate the possible leakage current source. Our result implied that Co/Ti cobalt salicide was compatible with high dose sub-0.13$\mu\textrm{m}$ process.

Effect of Tripolyphosphate (TPP) on the Controlled Release of Cyclosporin A from Chitosan-coated Lipid Microparticles

  • Cheon, Ji-Woong;Shim, Chang-Koo;Chung, Suk-Jae;Kim, Dae-Duk
    • Journal of Pharmaceutical Investigation
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    • 제39권1호
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    • pp.59-63
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    • 2009
  • Soybean phosphatidylcholine microparticles loaded with cyclosporin A (CsA) were prepared by the modified emulsion solvent diffusion and ionic gelation method, in which chitosan on the surface of the microparticles was crosslinked with various concentrations of tripolyphosphate (TPP). The morphology of the particles was characterized by scanning electron microscopy (SEM). The change of particle size and zeta-potential by chitosan on the surface of the lipid microparticles were systematically observed. The encapsulation efficiency and loading capacity of CsA in the particles were determined by high performance liquid chromatography (HPLC). In vitro release kinetics was studied using the dialysis method. In the results, the mean particle size and the zeta-potential of lipid microparticles increased when the attached chitosan was cross-linked (from 2.5 to 6.2 ${\mu}m$ and from -37.0 to +93.0 mV, respectively). The cyclosporin A-loaded lipid microparticles appeared discrete and spherical particles with smooth surfaces. The encapsulation efficiency of CsA was between 79% and 90% while the loading capacity was between 41% and 56%. In vitro release study showed that the crosslinkage of chitosan by TPP significantly delayed the release of CsA from the particles in a concentration-dependent manner. Thus, the release of CsA from the lipid microparticles could be controlled by tripolyphosphate used as a cross-linking agent.

$UO_2-PuO_2$ 노심에서의 유효증배계수계산 (An Effective Multiplication Factor Calculation of Uniform Lattices of $UO_2-PuO_2$ Fueled System)

  • Sang Keun Lee;Ji Bok Lee;Chang Saeng Rim;Chang Kun Lee;Chang Hyun Chung
    • Nuclear Engineering and Technology
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    • 제14권3호
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    • pp.138-147
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    • 1982
  • 열중성자로에 플루토늄의 재순환이 실현될 것에 대비하여 이의 해석을 위한 이론적인 기초를 수립하였다. 특히 상업적인 목적으로 플루토늄 재순환이 이루어질 때를 위하여 $UO_2$-PuO$_2$를 핵연료로 하는 균일격자 임계실험로에 대한 분석을 수행하였다. 이 목적을 위하여 GAM과 THERMOS에 이론적인 기초를 두고 $UO_2$-PuO$_2$계통의 해석에 적합한 이론을 가미하여 KARATE라는 이름의 단일세포격자코드를 개발하였다. KARATE에서 산출한 소수군 중성자 단면적과 확산이론 계산코드인 KIDD를 이용하여 임계실험로에 대한 유효증배계수를 계산하였다. 우리가 선정한 41개의 임계실험로에 대하여 유효증배계수의 평균치는 0.9997, 그 표준편차는 0.43%이었다. 이러한 결과는 KARATE/KIDD 전산체제가 $UO_2$-PuO$_2$를 핵연료로 하는 계통의 핵적 특성분석에 아주 유효하게 사용될 수 있다는 사실을 밝혀 준다.

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$SF_6$+Ar 혼합기체의 전리 및 부착계수에 관한 연구 (The Study on the Electron ionization and Attachment Coefficients in $SF_6$+Ar Mixtures Gas)

  • 김상남;하성철
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.591-593
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    • 2000
  • In this paper, we describe the results of a combined experimental theoretical study designed to understand and predict the dielectric properties of SF$_{6}$ and SF$_{6}$+Ar mixtures. The electron transport, ionization, and attachment coefficients for pure SF$_{6}$ and gas mixtures containing SF$_{6}$ has been analysed over the E/N range 30~300[Td] by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] SF$_{6}$+Ar mixtures were measured by time- of- flight method, The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with the experimental and theoretical for a rang of E/N values. Electron energy distribution functions computed from numerical solutions of the electron transport and reaction coefficients as functions of E/N. We have calculated $\alpha$,η and $\alpha$-η the ionization, attachment coefficients, effective ionization coefficients, and (E/N), the limiting breakdown electric-field to gas density ratio, in SF$_{6}$ and SF$_{6}$+Ar mixtures by numerically solving the Boltzmann equation for the electron energy distribution. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of theections of the

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해안선 횡방향의 표사이동 예측모형 (Numerical Model for Cross-Shore Sediment Transport)

  • 이철응;김무현
    • 한국해안해양공학회지
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    • 제7권1호
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    • pp.57-69
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    • 1995
  • 폭풍해일에 의한 쇄파대내에서의 표사이동을 예측할 수 있는 유한차분 수치모형을 개발하였다. 이동 경계조건을 가지는 비제차 확산방정식을 사용하여 개발된 수치모형은 Kriebel과 Dean(1985)의 수치모형이 가지고 있는 많은 제약성을 해결할 수 있었다. 임의의 초기단면과, 시간에 따른 폭풍해일의 스펙트럼을 이용하여 계산된 수치모형의 결과는 표사량의 보존 및 해안선이 후퇴나 쇄파점의 이동을 잘 나타내 주며, 해석해 및 관측자료 그리고 실험자료와 매우 잘 일치한다. 수치모형과 관련된 제반 변수들의 민감도를 분석하여 수치모형 적용의 편의를 도모하였으며, 해안선 단면을 따른 표사의 입경변화 효과를 부여할 수 있음을 알았다.

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Modification of RFSP to Accommodate a True Two-Group Treatment

  • Bae, Chang-Joon;Kim, Bong-Ghi;Suk, Soo-Dong;D. Jenkins;B. Rouben
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1996년도 춘계학술발표회논문집(1)
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    • pp.185-190
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    • 1996
  • RFSP is a computer program to do fuel management calculations for CANDU reactors. Its main function is to calculate neutron flux and power distributions using two-energy-group, three dimensional neutron diffusion theory. However, up to now the treatment has not been true two-group but actually "one-and-half groups". In other words, the previous (1.5-group) version of RFSP lumps the fast fission term into the thermal fission term. This is based on the POWDERPUFS-V Westcott convention. Also, there is no up-scattering term or bundle power over cell flux (H1 factor) for the fast group. While POWDERPUFS-V provides only 1.5 group properties, true two-group cross sections for the design and analysis of CAUDU reactors can be obtained from WIMS-AECL. To treat the full two-group properties, the previous RFSP version was modified by adding the fast fission, up-scatter terms, and H1 factor. This two-group version of RFSP is a convenient tool to accept lattice properties from any advanced lattice code (e.g. WIMS-AECL DRAGON, HELIOS...) and to apply to advanced fuel cycles. In this study, the modification to implement the true two-group treatment was performed only in the subroutines of the *SIMULATE module of RFSP. This module is the appropriate one to modify first, since it is used for the tracking of reactor operating histories. The modified two-group RFSP was evaluated with true two-group cross sections from WIMS-AECL. Some tests were performed to verify the modified two-group RFSP and to evaluate the effects of fast fission and up-scatter for three core conditions and four cases corresponding to each condition. The comparisons show that the two-group results are quite reasonable and serve as a verification of the modifications made to RFSP. To assess the long-term impact of the full 2-group treatment, it is necessary to simulate a long period (several months) of reactor history. It will also be necessary to implement the full two-group treatment of reactivity devices and assess the reactivity-device worths.ce worths.

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