• Title/Summary/Keyword: Coupling Agent

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Dynamic Mechanical and Morphological Properties of Natural Rubber Vulcanizates Containing Fillers

  • Lee, Hae Gil;Park, Chan Young
    • Elastomers and Composites
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    • v.51 no.3
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    • pp.218-225
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    • 2016
  • In order to examine correlation between silane coupling agent and activator which affects the physical properties of silica filled natural rubber compound, such as heat buildup, rebound property, dynamic mechanical and morphological properties were measured. With incorporation of silane coupling agent, $tan{\delta}$ at $0^{\circ}C$ was increased and at $60^{\circ}C$ was decreased, which resulted in improving of wet grip and rolling resistance. When silane coupling agent which is corresponding to 8~10% of silica was used, most favorable heat build up and $tan{\delta}$ was obtained. And also when activator was used, dispersibility of silica was improved as a result of reduction of reaggregation of silica.

Effect on the Physical Performance of Functionalized Silane Coupling Agent on Epoxy-Based Concrete Surface Finishing Material for Parking Floor (기능성 실란 커플링제가 에폭시계 콘크리트 주차장 바닥용 마감재의 물리적 성능에 미치는 영향)

  • Chae, Woo-Byung;Seong, Dong-Yun;Seo, Sang-Kyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.05a
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    • pp.279-282
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    • 2012
  • This study attempted to the effect on the physical performance of silane coupling agent on solventless epoxy-based concrete surface finishing material for parking floor. Tests were carried out in accordance with KS F 4041 and KS F 4937. The results of compressive strength, flexural compressive are 95.6N/㎟, 25.4N/㎟ and after wheel moving load testing, average abrasive depth is 0.96mm, these results satisfied the quality standard of KS F 4041, KS F 4937. As conclusion, this study confirmed that the silane coupling agent greatly effected on the physical performance of solventless epoxy resin.

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Influence of Silane Coupling Agent on Properties of Filled Styrene-Butadiene Rubber Compounds

  • Park, Sung-Seen
    • Macromolecular Research
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    • v.8 no.6
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    • pp.285-291
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    • 2000
  • Influence of silane coupling agent, bis-(3-(triethoxisilyl)-propyl)-tetrassulfide, on cure characteristics and bound rubber content of filled styrene-butadiene rubber (SBR) compounds and on physical properties of the vulcanizates was studied. Carbon black-filled and silica-filled compounds were compared. Content of the bound rubber increased with increased content of the silane coupling agent and this trend was shown more clearly in the silica-filled compounds. Optimum cure time of the carbon black-filled compound increased with increase of the silane content, while that of the silica-filled one decreased. Cure rate of the carbon black-filled compound became slower as the silane content increased while that of the silica-filled one became faster. By increasing the silane content, the minimum torque decreased and the delta torque increased. Physical properties of the silica-filled vulcanizate were found to be improved by adding the silane coupling agent. However, for the carbon black-filled vulcanizates, the tensile strength and tear resistance decreased with increase of the silane content. The differences between the carbon black-filled and silica-filled compounds were explained by difference in the reactivities of the fillers with the silane.

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A Study on the Dielectric Properties of Mica-reinforced Silicone Composites (마이카 강화 실리콘 복합재료의 제작과 그 유전적 특성에 관한 연구)

  • 조정수;곽영순;김순태;박차수;박정후
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.6
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    • pp.640-651
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    • 1992
  • This paper describes the electric properties of mica reinforced silicone composites with the parameter of curing condition of silicone resin, application amount of silane coupling agent to the mica paper and the mica wt% to the composite. Heat-resistant silicone resin and mica paper made of mica flakes are used to prepared the mica/silicone composite as matrix and filler, respectively. To improve the dielectric properties and interfacial adhesion between matrix and filler, silane coupling agent is applied on the mica paper. As for matrix, tan$\delta$ value of 30$0^{\circ}C$ heat-treated silicone resin is the lowest under 1%. The optimal wt% of coupling agent is 0.3% to the weight of mica paper. 80 wt% of mica as filler to the mica/silicone composite shows the best electric properties. And the mica reinforced silicone composite shows good high-frequency and mechanical tensile stress properties.

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A Study on Electrical Properties and Structure Analysis of Epoxy-Ceramic Composite Materials (에폭시-세라믹 복합재료의 전기적 특성 및 구조분석)

  • 정지원;홍경진;김태성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.9-12
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    • 1994
  • Epoxy-Ceramic Composite have good insulating, therma1 and mechanical properties, so it is studied actively on this material. In this thesis, we made a composite material b)\ulcorner filling Epoxy Resin with ceramics treated with Sillane Coupling Agent and studied dielectric and insulating characteristics according to treatment density of Sillane Coupling Agent and weight percent of filler. As a result, loss tangent increase and electrical breakdown voltage decrease according to increasing treatment density of sillane coupling agent because Interface matching between matrix and filler is not good. The best treatment density of sillane coupling agent is 0.5% water solution, in this density the best interface matching is achieved so good dielectric and insulation characteristics are shown. Dielectric and insulation characteristics according to weight percent of filler are best at 25wt.

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Influence of Cure Accelerator Content on Change of Crosslink Density by Thermal Aging in Natural Rubber Vulcanizates Filled with Silica (실리카로 보강된 천연고무 가황물의 가교 밀도 변화에 가황촉진제 함량이 미치는 영향)

  • Choi, Sung-Seen;Nah, Changwoon
    • Journal of Adhesion and Interface
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    • v.3 no.2
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    • pp.30-39
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    • 2002
  • The effect of cure accelerator content on the change in crosslink density by thermal aging was studied for silica-filled natural rubber (NR) vulcanizates. Influence of silane coupling agent was also investigated. N-tert-Butyl-2-benzothiazole sulfenamide (TBBS) and bis-(3-(triethoxysilyl)-propyl)-tetrasulfide (TESPT) were used as a cure accelerator and a silane coupling agent, respectively. The crosslink density increased by thermal aging and the increasing level became larger as the aging temperature increased. The degree of crosslink density change of the vulcanizates without the silane coupling agent was larger than that of the vulcanizates containing the silane coupling agent. For the vulcanizates silane coupling agent, the activation energy for the crosslink density change decreased with increase of the cure accelerator content in the vulvanizate.

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Electrical properties of XLPE/SXLPE blends as a function of silane coupling agent contents (실란 계면 결합제 함량에 따른 XLPE/SXLPE 블렌드의 전기적 성질)

  • Ko, Jung-Woo;Suh, Kwang-S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05a
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    • pp.33-36
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    • 2000
  • Electrical properties of Crosslinked polyethylene/silane crosslinked polyethylene (XLPE/SXLPE) blends were studied. Silane coupling agents of various contents were added to blends and their water tree and electrical breakdown characteristics were investigated. The water tree length of XLPE/SXLPE were increased by the addition of silane coupling agents except the case of SXLPE 10 % containing coupling agents of 0.5, 1.0 phr. AC breadown strength slightly increased by the addition of coupling agents to XLPE/SXLPE blends in cases of SXLPE 20 % containing coupling agents of 2.0 phr and SXLPE 50 %. The tendency of effects on water tree and breakdown characteristics was inverse.

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The Effect of Functionalized Organosilane Coupling Agent on the Adhesion Properties of 2 Layer Flexible Copper Clad Laminate (기능성 실란커플링제가 2-FCCL의 접착특성에 미치는 영향)

  • Park, Jin-Young;Lim, Jae-Phil;Kim, Yong-Seok;Jung, Hyun-Min;Lee, Jae-Heung;Ryu, Jong-Ho;Won, Jong-Chan
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.525-529
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    • 2009
  • In order to manufacture 2-layer flexible copper clad laminate (FCCL) s having the excellent performance high adhesion properties between copper foil and polyimide film are required. Silane coupling agents with specific functional groups as an adhesion promoter are generally used to enhance the adhesion. In our study, we synthesized a novel silane coupling agent for increasing the adhesive property between copper layer and polyimide layer. The surface morphology of rolled copper foil, as a function of the concentrations of the coated silane coupling agent, was fully characterized. As fabricated 2-layer FCCL, we observed that adhesive properties were changed by the surface morphology and we confirmed that the novel silane coupling agent affects adhesive properties in FCCL with two types of poly (amic acid)s.

STUDY ON THE INFLUENCE OF POLYOL ON MICROEMULSION GEL SYSTEM (Microemulsion gel system에 있어서 Polyol의 효과에 관한 연구)

  • Youn, J.;Jin, P.K.
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.18 no.1
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    • pp.132-149
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    • 1992
  • This study relates to a microemulsion gel which is applied in various cosmetic preparations because of good appearance, superior stability and a thin, uniform, non-greasy fi Am on the skin. Main object of this study is to elucidate the influence of polyol(clarifying agent and/or coupling agent in microemulsion) on microemulsion and to establish the optimum conditions for microemulsion gel formation in the view of superior consistency, stability, clarity and pick-up from a container. The constituents of the system are composed of water, polar ester oi1, nonionic surfactant and polyol. Using the three-component phase diagram and the tetrahedral-phase diagram, we have investigated the changes of transparence regions, consistency and resonance effect by an impact in microemulsion gel varying in polyol ratio. The results of this study showed that the variation in the content of water and couple ins agent has major influence on the microemulsion gel and the optimum formation region of microemulsion gel is the widest when the ratio of glycerine(coupling agent) to water is 63-75% It is believed that optimum use of polyol seems to be helpful to obtain the microemulsion gel containing maximum amount of oil phase with minimum amount of surfactant which is recently one of the major problems of cosmetic chemists.

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