• Corrosion Science and Technology
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• 제21권2호
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• pp.147-157
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• 2022

Electrochemical characteristics and damage behavior of 6061-T6 aluminum alloy used as a battery housing material for electric vehicles were investigated in solution simulating the acid rain environment with chloride concentrations. Potentiodynamic polarization test was performed to analyze electrochemical characteristics. Damage behavior was analyzed through Tafel analysis, measurement of damage area, weight loss, and surface observation. Results described that corrosion current density was increased rapidly when chloride concentration excceded 600 PPM, and it was increased about 7.7 times in the case of 1000 PPM compared with 0 PPM. Potentiodynamic polarization experiment revealed that corrosion damage area and mass loss of specimen increased with chloride concentrations. When chloride concentration was further increased, the corrosion damage area extended to the entire surface. To determine damage tendency of pitting corrosion according to chloride concentration, the ratio of damage depth to width was calculated. It was found that the damage tendency decreased with chloride concentrations. Thus, 6061-T6 aluminum alloy damage becomes larger in the width direction than in the depth direction when a small amount of chloride is contained in an acid rain environment.

• 한국주조공학회지
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• 제40권5호
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• pp.129-133
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• 2020

The outcomes of solution annealing and stress corrosion cracking in cold-worked 316L austenitic stainless steel have been studied using x-ray diffraction (XRD) and the slow strain rate test (SSRT) technique. The good compatibility with a high-temperature water environment allows 316L austenitic stainless steel to be widely adopted as an internal structural material in light water reactors. However, stress corrosion cracking (SCC) has recently been highlighted in the stainless steels used in commercial pressurized water reactor (PWR) plants. In this paper, SCC and inter granular cracking (IGC) are discussed on the basis of solution annealing in a chloride environment. It was found that the martensitic contents of cold-worked 316L stainless steel decreased as the solution annealing time was increased at a high temperature. Moreover, mode of SCC was closely related to use of a chloride environment. The results here provide evidence of the vital role of a chloride environment during the SCC of cold-worked 316L.

• 콘크리트학회논문집
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• 제11권6호
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• pp.89-100
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• 1999

Service life of concrete structures that are exposed to the environmental attack is largely influenced by the corrosion of reinforcing bare due to the chloride contamination. Chloride ions penetrate continuously into concrete from the environment, and chloride diffusion velocity is governed by a mechanical steady stage. In this study, a method is developed to predict corrosion initiation of reinforcing bars in the sea-shore structures, based on governing equations that take into account the diffusing of chloride ions and a mechanical steady state. As a result of this study, Corrosion Prediction System (CPS) is developed, and it can be used to determine an optimal time for repair and rehabilitation actions need to be taken. Futhermore, CPS assists the concrete mixing structures by predicting of chloride concentrations in concrete mixture, exposed to salt concentrations and service environment.

• 한국구조물진단유지관리공학회 논문집
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• 제27권4호
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• pp.45-53
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• 2023

본 연구에서는 해양환경에 노출된 강부재의 표면염분과 부식량의 상관관계를 분석하기 위하여 해상강교량의 보강형 거더 부재와 강박스 실험체를 대상으로 표면염분량과 평균부식두께를 부재단위로 평가하였다. 표면염분은 월단위로 1년간 Bresle method를 활용하여 계측하였고, 부식량은 실험용 모니터링 강판에 발생한 부식생성물로 인한 중량감소량을 평균부식두께으로 환산하여 분석하였다. 표면염분과 부식량을 계측한 결과, 강부재의 형상이나 설치위치에 따라 상대적인 표면염분량과 평균부식두께의 차이가 나타났으며, 동일한 교량 내에 설치된 동일한 형상의 부재라도 부식량이 국부적으로 급격히 증가하는 것을 확인하였다. 표면염분과 부식량의 상관관계를 분석하기 위하여 표면염분에 따른 부식량 발생 경향을 평가하였으며, 부식량을 평가할 수 있는 평가식을 부재의 형상별로 분석하였다. 표면염분과 부식량의 상관관계 분석 결과, 표면염분의 영향으로 강부재에서 발생하는 부식량은 부재의 형상에 따라 약 1.15배까지 변화하는 것으로 나타났다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2017년도 춘계 학술논문 발표대회
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• pp.218-219
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• 2017

In order to examine the possibility of practical at low-temperature environment curable cement mortar with chloride and nitrite as cold resistance admixture for rebar corrosion prevention. As a result, chloride was used using nitrite complex in low temperature environment and corrosion performance of rebar was improved and mortar strength was promoted. The ratio of nitrite than chloride applied more than twice, corrosion of the reinforcing bars will not occur even in low temperature environment, cement hydration reaction will be promoted and mortar will prevent freezing damage.

• 한국해양공학회지
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• 제12권3호통권29호
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• pp.68-74
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• 1998

An increase of concrete construction in marine environments as well as an increasing use of marine aggregate at the mixing stage of concrete has provoked an important problem. A high concentration of chloride ion in the vicinity of steel bars in concrete is the principal cause of premature reinforcement corrosion in concrete structures. In this study, the behavior of chloride ions introduced into concrete from concrete surface by marine evironment was analysed. A mathematical model including the diffusion of chloride ion in aqueous phase of pores, the adsorption and desorption of chloride ions to and from the surface of solid phase of concrete and the chemical reactions of chloride ions with solid phase was presented. Finite element method was employed to carry out numerical analysis. The results of this study may be used to predict the onset of reinforcement corrosion and to identify the maximum limit of chloride ions contained in concrete admixtures.

• Journal of Welding and Joining
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• 제15권5호
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• pp.124-133
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• 1997

Corrosion behavior of welded SWS400 steel used for bridges was studied in a range of the acid-rain environment using immersion, potentiodynamic polartization, polarization resistance, and galvanic corrosion tests. The SWS400 steel exhibited active corrosion behavior in the range of acid-rain environment, i.e. no passivation. As the results of immersion corrosion test, Tafel extrapolation method, and polarization resistance measurement, the average corrosion rats of the steels were 0.31-0.72 mm/year in the pH of 4-5, and 0.17 mm/yera in the pH 6, respectively. The steel showed a resistance to corrosion in the pH 6. The observed active behavior of SWS400 steel in chloride-containing environment indicated that the chloride ions exerts a detrimental influence on the formation of passive films. Galvanic corrosion was observed between the weld and the base metals because the weld is anodic to the base metal.

• Corrosion Science and Technology
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• 제4권5호
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• pp.171-177
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• 2005

A comprehensive framework for numerical simulation of time-dependent performance change of reinforced concrete (RC) structures subjected to chloride attack is presented in this paper. The system is composed of simplified computational models for transport of moisture and chloride ions in concrete pore structure and crack, corrosion of reinforcement in concrete and mechanical behavior of RC member with reinforcement corrosion. Service-life of RC structures under various conditions is calculated.

• Corrosion Science and Technology
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• 제21권5호
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• pp.348-359
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• 2022

Interest in electric vehicle is on the rise due to global eco-friendly policies. To improve the efficiency of electric vehicles, it is essential to reduce weights of components. Since electric vehicles have various electronic equipment, the research on stray current corrosion is required. In this research, a galvanostatic corrosion experiment was performed on 6061-T6 Al alloy for electric vehicle battery housing using chloride concentration and applied current density as variables in a solution simulating an acid rain environment. As a result of the experiment, when chloride concentration and applied current density were increased, corrosion damage became larger. In particular, pitting damage was dominant at an applied current density of 0.1 mA/cm². Pitting damage over the entire surface was found at a current density of 1.0 mA/cm². In conclusion, chloride concentration had a relatively large effect on localized corrosion. The applied current density had a great effect on uniform corrosion. However, in the case of applied current density, localized corrosion was also greatly affected by interaction with chloride.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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• pp.1045-1050
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• 2001

This study was performed to evaluate reinforced concrete durability in chloride attack environment under sustained load by the corrosion of reinforcing bars and the permeation of chloride ion. Generally, it is regarded that permeability of chloride ion is determined by the properties of concrete, but the effects of load which make alternation of concrete inner structure such as crack and so on should not neglected. In this study, it is shown that the relation between bending load on RC beam, deflection and crack of specimen, permeation of chloride ion, rating of re-bar corrosion, and the relation between compression load and permeation of chloride ion. Therefore the effects of load on permeation of chloride ion and re-bar corrosion are evaluated.