• Title/Summary/Keyword: Corrosion in chloride environment

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An Experimental Study on Development of Physical Properties and Durability of Concrete Spread with Inorganic Antibiotics (무기질 항균제 도포에 의한 콘크리트의 경화성상 및 내구성상 향상에 관한 실험적 연구)

  • Kim, Moo-Han;Khil, Bae-Su;Kim, Jae-Hwan;Cho, Bong-Suk;Lee, Eui-Bae
    • Journal of the Korea Institute of Building Construction
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    • v.5 no.3 s.17
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    • pp.75-82
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    • 2005
  • Sewage facilities are positively necessary for environment improvement such as rainwater removal, sewage disposal, preservation of the quality of water and health of the citizens in present-day. Meanwhile, a deterioration of the concrete sewer pipe is increasing rapidly due to the chemical and physical attack and especially biochemical attack that is to say biodeterioration. So, in advanced countries, prediction techniques and corrosion inhibition system for sewer concrete are developed and are being applied. Also, antibiotics were developed already but application of that is low because it is not economical and has no practical use. But, in domestic, countermeasures for the corrosion of sewage concrete are not sufficient and biochemical attack is not reflected in those essentially. In this study, to prevent biochemical corrosion of the sewer concrete, surface of the concrete was spread with liquefied inorganic antibiotics and then its engineering properties were experimentally investigated. As a result, compressive strength of the specimen spread with antibiotics were similar to those of non spread, Both bond strength and abrasion amount of the specimen spread with antibiotics were inferior to non spread. Properties of absorption and air permeability of the specimen spread with antibiotics were superior to non spread. Finally, carbonation depth, chloride ion penetration depth and weight change ration of the specimen spread with antibiotics were smaller than non spread.

Cavitation-Erosion Characteristics of the Stainless Steel with Adding Ti Stabilizer Element in Sea Water (안정화 원소 Ti 첨가에 따른 스테인리스강의 해수 내 캐비테이션-침식 특성)

  • Choi, Yong-Won;Yang, Ye-Jin;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.49 no.4
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    • pp.344-348
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    • 2016
  • Stainless steel is widely applied in many industrial fields due to its excellent anti-corrosion and durability characteristics. However, stainless steel is very vulnerable to cavitation attack caused by high speed flow of fluid in the chloride environments such as marine environment. These conditions promote intergranular corrosion and cavitation-erosion, leading to degradation of the structural integrity and service life. In order to prevent these problems, the stabilized stainless steel is applied to the offshore and shipbuilding industries. In this study, Ti was added to 19%Cr-9%Ni as the stabilizer element with different concentrations (0.26%, 0.71%), and their durabilities were evaluated with cavitation-erosion experiment by a modified ASTM G32 method. The microstructural change was observed with the stabilizer element contents. The result of the observation indicated that the amount of carbide precipitation was decreased and its size became finer with increasing Ti content. In the cavitation-erosion experiment, both weight loss and surface damage depth represented an inverse proportional relationship with the amount of Ti element. Consequently, the stainless steel containing 0.71% of Ti had excellent durability characteristics.

Evaluation of Chloride Diffusion Characteristics in Concrete with Fly Ash Cured for 2 Years (2년 양생된 Fly Ash 콘크리트의 염화물 확산 특성 평가)

  • Yoon, Yong-Sik;Hwang, Sang-Hyeon;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.8-15
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    • 2019
  • When RC(Reinforced Concrete) structures are exposed to harsh environment, deterioration phenomenon occurs, and the corrosion in rebar due to chloride intrusion is known as representative deterioration, so called chloride attack. In this paper, chloride resistance performance of 2 years aged concrete is evaluated considering 3 levels of water to binder ratio(0.37, 0.42, and 0.47) and 2 levels of substitution ratio of fly ash(0% and 30%). Accelerated chloride diffusion coefficient tests referred to Tang's method, total passed charge tests referred to ASTM C 1202, and compressive strength tests referred to KS F 2405 are performed. With adaptation of the previous test results and the results from this study, time-dependent chloride diffusion characteristics are analyzed for each concrete. The FA(Fly Ash) concrete has higher chloride resistance performance than OPC(Ordinary Portland Cement) concrete. According to the evaluation standard of ASTM C 1202, the FA concrete has "Moderate" grade after 49 days while OPC concrete does "Moderate" grade after 365 days. As the results of time-parameter for chloride diffusion, OPC concrete and FA concrete show the decreasing behavior of time-parameters with increasing water to binder ratio. Also, FA concrete has 1.57~2.74 times of time-parameter than OPC concrete. That's cause is thought that the time-parameter indicates the gradient of decreasing of diffusion coefficient. FA concrete has higher time-parameters than OPC concrete by pozzolanic reaction of FA.

Resistance to Chloride Attack of FRP Hybrid Bar After Freezing and Thawing Action (동결융해 이후의 FRP Hybrid Bar의 부식 저항성)

  • Ryu, Hwa-Sung;Park, Ki-Tae;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.59-65
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    • 2018
  • RC(Reinforced Concrete) structures are exposed to various exterior conditions, and the performances of both chloride resistance and freezing/thawing action are evaluated for those exposed to corrosive environment-sea shore. Recently developed FRP Hybrid Bars which is coated with glass fiber and epoxy with core steel has an engineering advantage of higher Elasticity than FRP rod. In this work, corrosion resistance, weight loss, and bond strength are evaluated for the FRP Hybrid Bar tested through freezing/thawing action for 300cycles. The double coated FRP Hybrid Bar shows the least weight loss without defection due to freezing/thawing action. Bond strength in FRP Hybrid Bar increases to 120% of normal steel through torturity effect with Si-coating. Bond strength in normal steel shows 0.86~0.89times in 3-day corrosion acceleration and 0.35~0.38times in 5-day corrosion acceleration, however, that in FRP Hybrid Bar shows little changes in bond strength before and after freezing/thawing action.

An Experimental Study on the Early Compressive Strength Improvement of Cement Mortar Mixed with Blast Furnace Slag using Powdered Stimulants (분말형 자극제를 이용한 고로슬래그미분말 혼입 시멘트 모르타르의 조기 압축강도 향상에 관한 실험적 연구)

  • Lee, Kang Jin;Kim, Jin Hyoung;Park, Ki Bong;Lee, Han Seung
    • KIEAE Journal
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    • v.12 no.3
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    • pp.115-122
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    • 2012
  • Based on previous research and existing literature, this study examines the development of admixture, which increases the early concrete strength (1 and 3 day) by mixing blast furnace slag cement and concrete stimulant. The research on early strength development of concrete is necessary in dealing with the drawbacks of slow early strength concrete on site and to shorten the construction time. The study confirmed that when a high alkaline mortar mixture is mixed with blast furnace slag, the early strength of admixture exceeds that of ordinary portland cement (OPC). The use of calcium chloride ($CaCl_2$) promotes hydration of cement at low temperature and show similar strength as the blast furnace slag admixture. Although calcium chloride seems economically advantageous, it causes steel corrosion and its use in concrete should be further studied in-depth.

Performance Evaluation of Repair Methods for RC structures by Accelerating Test in Combined Deterioration Chamber and Long-Term Field Exposure Test (복합열화촉진실험 및 장기현장폭로실험에 의한 RC구조물 보수공법의 보수성능평가)

  • Kwon Young-Jin;Kim Jae-Hwan;Han Byung-Chan;Jang Seung-Yup
    • Journal of the Korean Society for Railway
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    • v.9 no.4 s.35
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    • pp.349-356
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    • 2006
  • At present, the selecting system and analytic estimation criterion on repair materials and methods of the deteriorated RC structures have not yet been set up in domestic. Under these circumstances, deterioration such as shrinkage crack, corrosion of rebar has been often occurred after repair, and this finally results in too frequent repairs. In this study, three types of repair methods were experimentally investigated by the accelerating test in a combined deterioration chamber and long-term field exposure test. Three types of repair methods applied in this study belong to a group of polymer cement mortar, which is commonly used in repair works. According to the results of this study, durability of repair mortar layers and corrosion properties of recovered rebar could be investigated in short period by the accelerating test in a combined deterioration chamber, which can simulate the condition of repeated high-and-low temperature and repeated dry-and-wet environment, spraying chloride solution and emitting $CO_2$ gas. After 36 month long-term filed exposure test in the coastal area, harmful macro-cracks are observed in the polymer cement mortar layer of some repair methods. These crack are considered to result from drying shrinkage of polymer cement mortar. Also, after 36 month exposure, amount of corrosion area and weight loss of rebar are found to be different according to the types of repair methods.

An Experimental Study on the Improvement of Early Strength and Chloride Attack Resistance for Marine Concrete (해양용콘크리트의 초기강도 및 내염해 저항성 향상에 관한 실험적 연구)

  • Lee, Keon-Ho;Kim, Jong-Back;Bae, Jun-Young;Seo, Shin-Seok;Jo, Sung-Hyun;Roh, Hyeon-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.661-664
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    • 2008
  • The structure which is located in special surroundings like ocean-environment is physically and chemically eroded by seawater or salt damage, and then concrete-structure becomes deteriorated by iron corrosion and swelling pressure which leads to remarkably decline durability due to cracks and exploitation. As a measure against salt damage, it is actively being examined to use the blended cement that controls salt damage and fix chloride in the process of hydration. In this study, therefore, to examine the property of marine concrete added admixture, marine concrete is manufactured by adding high-strength admixture(omega2000) by 0, 5, 10, and 15% to low heat-blended cement. Then it shows that the compressive strength of manufactured marine cement tends to increase and chloride penetration resistance improves.

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An Experimental Study on the Fundamental Properties and Durability of Sewer Type Restorative Mortar Spread with Antibiotics (항균제를 도포한 하수시설용 단면복구 모르타르의 기초물성 및 내구특성에 관한 실험적 연구)

  • Kim, Moo-Han;Kim, Gyu-Yong;Kim, Jae-Hwan;Cho, Bong-Suk;Lee, Dong-Heck
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.3
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    • pp.195-202
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    • 2006
  • Deterioration of sewer concrete is representative that biochemical corrosion according to the $H_2S$ has growth by inhabit sulfur-oxidzing bacteria because of special environment in sewer. But in case of domestic, fundamentally, sulfur-oxidzing bacteria could moderate development of repair material method is need because of corrosion prevent method is inconsideration with carry out to improve project. In this paper, after development of spread type antibiotic with antibio-metal, antibacterial performance about sulfur-oxidzing bacteria of antibiotic and tested to estimate fundamental properties of bonding strength, abrasion contents, contents of water absorption, contents of air permeability, carbonation depth, chloride ion penetration depth and chemical resistance of spread with antibiotic restorative mortar.

Evaluation on Durability of Structures continuously Exposed to the Coastal Environment (장기간 해안환경에 노출된 구조물의 내구성 평가)

  • Son, Chang-Du;Lee, In-Ju;Hong, Sung-Nam;Park, Jun-Myung;Kim, Tae-Wan;Park, Sun-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.279-280
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    • 2009
  • This study is to aim an evaluation of concrete durability exposed to coastal circumstance. Therefore, six cores of the seawater pump were obtained by drilling, and their total chloride content were tested to predict initial time of steel corrosion..

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Effects of alloying elements(Cr, Mn) on corrosion properties of high manganese steel in 3.5% chloride environments and sour gas environment (염수 및 Sour gas환경에서 고 망간강의 내식성에 미치는 합금원소 Mn, Cr의 영향)

  • Kim, Hui-San;Hyeon, Yeong-Min;Lee, Sun-Gi
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.39-42
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    • 2013
  • 자동차 및 에너지 산업의 적용을 목표로 고망간강의 기계적 성질 향상 연구가 활발히 진행된 반면 내식성 연구는 미비하다. 본 연구에서는 염수 환경 및 H2S 환경에서 4종의 고망간강의 내식성에 미치는 크롬 및 망간의 영향을 조사하였다. 비교재로 사용된 탄소강 대비 실험재의 부식 속도는 침지 실험을 통해 얻어졌다. 또한 내식성 기구 고찰을 위하여 상평형 프로그램을 통하여 녹 층을 예측하고, 침지실험으로부터 얻어진 녹 층을 XRD, SEM-EDS 및 TEM-EDS로 분석하였다. 3.5% NaCl 용액에서 크롬 및 망간이 모두 내식성을 향상시킨 반면, synthetic seawater에서는 크롬만이 내식성을 향상시켰다. 또한 이들 염수 환경과 달리 H2S 환경에서 크롬과 망간 모두 내식성을 향상시키지 못했다. 환경에 따라 강의 내식성에 미치는 합금 원소의 영향이 상이한 원인은 각각의 환경에서 형성된 녹층의 구성 물질의 차이에 의한 것으로 이에 대하여는 본문의 된 녹 층 분석 결과에서 자세히 설명되었다.

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