• Title/Summary/Keyword: Corrosion in chloride environment

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Investigation of Salt Attack of Concrete Structures Exposed to Reclaimed Marine Land (해안매립지에 위치한 콘크리트구조물의 염해조사)

  • Kim, Seong-Soo;Cheong, Ran;Kim, Young-Ung;Kim, Young-Chul;Park, Kwang-Pil
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.835-840
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    • 2002
  • Chloride ions have a tendency to penetrate into concrete and proceed the corrosion by depassivating rebar surface. Thus tire deteriorated concrete is subject to experience severe degrading of durability under marine environment. In this study, concrete structures exposed to reclaimed marine land wet-e investigate to find out the salt attack along with analysis and review of it's cause. Under the reclaimed marine land, the main causes of deterioration of concrete structures is the steel corrosion due to the Penetration of chlorides and the deterioration of outer concrete itself by chemical attack.

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A Study on the Application of FRP Hybrid Bar to Prevent Corrosion of Reinforcing Bar in Concrete Structure (콘크리트구조물 중의 철근 부식 저감을 위한 FRP Hybrid Bar의 적용성 연구)

  • Lee, Seung-Tae;Park, Kwang-Pil;Park, Ki-Tae;You, Young-Jun;Seo, Dong-Woo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.5
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    • pp.559-568
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    • 2019
  • Recently, the infrastructure of the marine environment has been increasing. Therefore, there has been increasing interest in increasing the durability of structures. The FRP Hybrid Bar with improved durability against corrosion was developed in recent years. On the other hand, studies that evaluate the corrosion resistance are insufficient. In this study, the corrosion resistance according to the type of rebar in concrete was assessed and analyzed. The experiment used steel bars and FRP Hybrid Bar. The corrosion test method was a galvanic current and half-cell potential method. The accelerated corrosion test was carried out by four levels (0%, 1.5%, 3%, and 6%) of chloride added to the concrete. The galvanic current measurements revealed no corrosion current in the FRP Hybrid Bar. The half-cell measurement also showed the corrosion resistance of the FRP Hybrid Bar. Therefore. FHB can be used as an alternative steel for structures where a marine environment and steel corrosion are predicted.

Progressive Evaluation of Concrete Deterioration Caused by Chloride-Induced Steel Corrosion Using Impact-Echo Testing (충격 반향 신호 모니터링을 통한 철근 부식 진전에 따른 콘크리트 상태 평가)

  • Rizky Pitajeng;Julfikhsan Ahmad Mukhti;Seong-Hoon Kee
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.28 no.3
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    • pp.37-46
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    • 2024
  • This study investigates the evolution of concrete damage due to chloride-induced steel corrosion through Impact-echo (IE) testing. Three reinforced concrete specimens, each measuring 1500 mm in length, 400 mm in width, and 200 mm in thickness, were fabricated using three concrete mixture proportions of blended cement types: ordinary Portland cement, ground granulated blast-furnace slag and fly ash. Steel corrosion in the concrete was accelerated by impressing a 0.5 A current following a 35-day cycle of wet-and-dry saturation in a 3% NaCl solution. Initial IE data collected during the saturation phase showed no significant changes, indicating that moisture had a minimal impact on IE signals and highlighting the slow progress of corrosion under natural conditions. Post-application of current, however, there was a noticeable decline in both IE peak frequency and the P-wave velocity in the concrete as the duration of the impressed current increased. Remarkably, progressive monitoring of IE proves highly effective in capturing the critical features of steel-corrosion induced concrete deterioration, such as the onset of internal damages and the rate of damage propagation. These results demonstrate the potential of progressive IE data monitoring to enhance the reliability of diagnosing and prognosticating the evolution of concrete damage in marine environment.

Durability Analysis of Underground Structure based on Limit State Function Considering Carbonation (탄산화 기반의 한계상태함수를 활용한 지하구조물의 내구성 평가)

  • Choo, Jin-Ho;Lee, Tae-Jong;Yoon, Tae-Gook;Lee, Sang-Chul
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.3
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    • pp.69-75
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    • 2014
  • The priority of repair areas are chosen with the probability distribution of 0.3mm wide crack and carbonation induced corrosion. Data is analyzed and evaluated based on the 28 section of Precise Inspection for Safety and Diagnosis (PISD) in seoul. As the crack is distributed in log-normal, the carbonation and cover are in normal distribution. To have rational in repair sections among 503 sheets of underground structure, it is adopted the reliability index as well as the environment factors: strength, sonic speed, $CO_2$ concentration, corrosion, and content of chloride.

Assessment of external corrosion deterioration of large diameter metallic water pipes buried in reclaimed land (간척지대에 매설된 대구경 금속관의 외면 부식손상 평가)

  • Lee, Ho-Min;Choi, Tae-Ho;Kim, Jung-Hyun;Bae, Cheol-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.5
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    • pp.373-383
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    • 2020
  • The purpose of this study was to evaluate the corrosion damage of large diameter metallic pipes buried in reclaimed land due to the corrosion effect by soil, and to propose a method of installing metal pipes in the reclaimed land. The results are as follow. First, the soil of the reclaimed land was gray clay, the soil specific resistance indicating soil corrosiveness was at least 120 Ω-cm, the pH was weakly acidic(5.04 to 5.60), the redox potential was at least 62 mV, the moisture content was at most 48.8%, and chlorine ions and sulfate ions were up to 4,706.1 mg/kg and 420 mg/kg. Therefore, the overall soil corrosivity score was up to 19, and the external corrosion effect seems to be very large. Second, the condition of straight part of pipes was in good condition, but most of KP joints were affected by corrosion at a severe level. The reason for this seems to be that KP joints accelerated corrosion due to stress and crevice corrosion in addition to galvanic corrosion in the same environment. Third, as a result of evaluating correlations of each item that affects the corrosion on the external part, the lower the soil resistivity and redox potential, the greater the effect on the KP joints corrosion, and the moisture content, chloride ion, and sulfate ion, the higher the value, the greater the effect on the corrosion of KP joints. In addition, among soil corrosion items, the coefficient of determination of soil resistivity with corrosion of KP joints was the highest with 0.6439~0.7672. Fourth, when installing metal pipes or other accessories because the soil of the reclaimed land is highly corrosive, it is necessary to apply a corrosion preventive method to extend the life of pipes and prevent leakage accidents caused by corrosion damage to the joint.

An Experimental Study on the Salt Resistance Properties with Concrete Materials under Marine Environment (Exposure period : 5 years) (해양환경에 폭로한 콘크리트의 내염특성에 대한 실험적 연구 (폭로기간 : 5년))

  • Kim, Yong-Chul;Suk, Jun-Yeoll;Shin, Do-Chul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.169-172
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    • 2006
  • The IIA structures exposed to marine environment is subject to many different types of potential attack. The physical attack due to drying and wetting would increase the internal stress of concrete. The chemical attack resulting from the diffusion of ions$(Cl^-,SO_4^{2-},Mg^+)$ from seawater through the pores in concrete. Therefore the sea water resistance of concrete must be considered when it is used for structure in the ocean. The objective of this study is to evaluate chloride diffusion and corrosion characteristics of concrete when using the various concrete materials under marine environment. After 5 years of exposure, concrete incorporating 40% blast-furnace slag as replacement for type I cement with low w/c ratio of 0.42 and using the inhibitor shows excellent performance.

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Effect of Period of Immersion on Corrosion Potential, Anodic Polarization, and Impedance Characteristics of Reinforced Steel in Mortar (W/C: 0.6) (모르타르(W/C:0.6)의 철근의 부식전위와 양극분극 및 임피던스 특성에 미치는 재령 년수)

  • Jeong, Jae-Hyun;Moon, Kyung-Man;Lee, Sung-Yul;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Journal of Ocean Engineering and Technology
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    • v.30 no.4
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    • pp.327-333
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    • 2016
  • Reinforced concrete structures have found wide usage in land and maritime applications. However, the corrosion of reinforced concrete has been recognized as a serious problem from economic and safety standpoints. In previous studies, the corrosion behavior of the inner steel bar embedded in mortar (W/C: 0.4, 0.5) was investigated using electrochemical methods. In this study, multiple mortar test specimens (W/C: 0.6) with six different cover thicknesses were prepared and immersed in flowing seawater for five years. Subsequently, equations related to the cover thickness, period of immersion, and corrosion characteristics of the embedded steel bar were evaluated using electrochemical methods. Prior to immersion, the corrosion potentials indicated an increase with increasing cover thickness, and after five years, all corrosion potentials demonstrated a trend in the positive direction irrespective of the cover thickness. However, the relationships between the corrosion potential and cover thickness were not in complete agreement. Furthermore, after five years, all of the corrosion potentials indicated values that were nobler compared to those obtained prior to immersion, and their corrosion current densities also decreased compared to their values obtained prior to immersion. It was considered that the embedded steel bar was easily corroded because of the aggression of water, dissolved oxygen, and chloride ions; a higher W/C ratio also assisted the corrosion process. The corrosive products deposited on the surface of the steel bar for five years cast a resistance polarizing effect shifting the corrosion potential in the nobler direction. Consequently, it was considered that the W/C ratio of 0.6 showed nearly same results as those of W/C of 0.4 and 0.5. Therefore, the corrosion potential as well as various parameters such as the cover thickness, period of immersion, and W/C ratio must be considered at once for a more accurate evaluation of the corrosion property of reinforced steel exposed to marine environment for a long period.

Effect of Coating Materials for Steel on the Threshold of Corrosive Amount of Airborne Chlorides and the Evaluation of Their Corrosion Speeds (강재마감별 부식개시 임계 비래염분량 및 부식속도 평가)

  • Cho, Gyu-Hwan;Lim, Myung-Hyun;Park, Dong-Cheon
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.2
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    • pp.143-151
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    • 2015
  • Many studies have investigated the airborne chlorides that can weaken the overall durability of the concrete structures due to the corrosion of steel materials, but most of the studies have aimed to examine weathering by exposing various construction materials to the actual oceanic environment. However, with the exposure test, it was difficult to find the threshold of precise corrosive amount of airborne chlorides due to diverse deteriorating environmental factors such as ultraviolet ray, acid rain, floating material from industrial pollution as well as airborne chlorides. Therefore, in this study, an airborne chloride simulator was set up, in oder to conduct a corrosion accelerating test for steels coated by five different finishing materials. As results, it was found that the corrosion began to be observed at $0.58{\sim}0.73mg/dm^2$ for no-coated steel, at $7.89{\sim}8.46mg/dm^2$for urethane-coated steel, at $57.95{\sim}69.48mg/dm^2$ for red lead-coated steel, and at $80.73{\sim}89.35mg/dm^2$ for stainless-coated steel, respectively. Hence, these specific data can be considered as the threshold ranges of corrosion for each coating material for steel.

Evaluation on Damage Behavior of Al-4.5%Mg-0.6%Mn Al Alloy with Potentiostatic Experiment Time (Al-4.5%Mg-0.6%Mn 알루미늄 합금의 정전위 시간 변수에 따른 손상거동 평가)

  • Kim, Seong-Jong;Woo, Yong-Bin;Han, Min-Su;Jang, Seok-Ki
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.6
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    • pp.569-576
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    • 2012
  • In general, aluminum alloys forms the passive film($Al_2O_3$, $Al_2O_3{\cdot}3H_2O$) in neutral solution. However, the passive film created on the surface will be destroyed by chloride ions contained in sea water so the corrosion will occur. In this study, in order to solve the problem of corrosion under a seawater environment, potentiostatic protection techniques were applied to Al-4.5%Mg-0.6%Mn aluminum alloy in seawater. At polarization experiments, active state were observed at anodic polarization and concentration polarization by reduction of dissolves oxygen and activation polarization were found at anodic polarization. As a results of potentiostatic experiment, calcareous deposit were created much more as applying time increase from the turning point of the concentration polarization and activation polarization and crevice corrosion was partially observed between calcareous deposit and surface of base metal. Overall potentiostatic anodic polarization experiment was difficult to apply potentiostatic corrosion protection technology by occurrence of active state, whereas potentiostatic cathodic polarization experiment examined optimum corrosion protection condition of -1.1 V~-0.75 V within the range of concentration polarization considered various applying time.

A Study on Repair Method of Concrete Structures using the Solution of Removing Chloride (염분제거용 약액을 이용한 콘크리트 구조물의 보수공법에 관한 연구)

  • Kim, Woonhak;Hwang, Sungwoon;Kang, Seokwon
    • Journal of the Society of Disaster Information
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    • v.13 no.4
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    • pp.562-569
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    • 2017
  • Reinforced concrete is used for bridges and large structures that are constructed with social overhead capital because they are economically and semi-permanently integrated with reinforcing bar and concrete. However, when the chloride ion in the concrete destroys the passive film of the reinforcing bar by the marine exposure environment and the snow remover used in the winter season, and the reinforcing bar is corroded by various chemical and physical actions, the durability is deteriorated in a short period, and the life span is shortened. In this study, a repair method to recover the durability of the initial structure by effectively removing chloride ion from the damage caused by salting of the above mentioned reinforced concrete was conducted.