• Corrosion Science and Technology
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• v.21 no.2
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• pp.147-157
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• 2022

Electrochemical characteristics and damage behavior of 6061-T6 aluminum alloy used as a battery housing material for electric vehicles were investigated in solution simulating the acid rain environment with chloride concentrations. Potentiodynamic polarization test was performed to analyze electrochemical characteristics. Damage behavior was analyzed through Tafel analysis, measurement of damage area, weight loss, and surface observation. Results described that corrosion current density was increased rapidly when chloride concentration excceded 600 PPM, and it was increased about 7.7 times in the case of 1000 PPM compared with 0 PPM. Potentiodynamic polarization experiment revealed that corrosion damage area and mass loss of specimen increased with chloride concentrations. When chloride concentration was further increased, the corrosion damage area extended to the entire surface. To determine damage tendency of pitting corrosion according to chloride concentration, the ratio of damage depth to width was calculated. It was found that the damage tendency decreased with chloride concentrations. Thus, 6061-T6 aluminum alloy damage becomes larger in the width direction than in the depth direction when a small amount of chloride is contained in an acid rain environment.

• Journal of Korea Foundry Society
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• v.40 no.5
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• pp.129-133
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• 2020

The outcomes of solution annealing and stress corrosion cracking in cold-worked 316L austenitic stainless steel have been studied using x-ray diffraction (XRD) and the slow strain rate test (SSRT) technique. The good compatibility with a high-temperature water environment allows 316L austenitic stainless steel to be widely adopted as an internal structural material in light water reactors. However, stress corrosion cracking (SCC) has recently been highlighted in the stainless steels used in commercial pressurized water reactor (PWR) plants. In this paper, SCC and inter granular cracking (IGC) are discussed on the basis of solution annealing in a chloride environment. It was found that the martensitic contents of cold-worked 316L stainless steel decreased as the solution annealing time was increased at a high temperature. Moreover, mode of SCC was closely related to use of a chloride environment. The results here provide evidence of the vital role of a chloride environment during the SCC of cold-worked 316L.

• Journal of the Korea Concrete Institute
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• v.11 no.6
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• pp.89-100
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• 1999

Service life of concrete structures that are exposed to the environmental attack is largely influenced by the corrosion of reinforcing bare due to the chloride contamination. Chloride ions penetrate continuously into concrete from the environment, and chloride diffusion velocity is governed by a mechanical steady stage. In this study, a method is developed to predict corrosion initiation of reinforcing bars in the sea-shore structures, based on governing equations that take into account the diffusing of chloride ions and a mechanical steady state. As a result of this study, Corrosion Prediction System (CPS) is developed, and it can be used to determine an optimal time for repair and rehabilitation actions need to be taken. Futhermore, CPS assists the concrete mixing structures by predicting of chloride concentrations in concrete mixture, exposed to salt concentrations and service environment.

• Journal of the Korea institute for structural maintenance and inspection
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• v.27 no.4
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• pp.45-53
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• 2023

In this study, to analyze the correlation of surface chloride and corrosion amount level according to the installation location of steel members exposed to the marine environment, the surface chloride and mean corrosion depth were evaluated by member units for box girder members of the offshore steel bridge and box specimens. The surface chloride was measured monthly using the Bresle method for one year. The corrosion amount was evaluated by converting the weight loss due to corrosion products generated in the monitoring steel plate into mean corrosion depth. As a measurement result of the surface chloride and corrosion amount, relative differences in surface chloride and mean corrosion depth were appeared depending on the shape or installation location of the steel members. Moreover, even if members of the same shape were installed in the same bridge, it was confirmed that the corrosion amount was increased locally and rapidly. The tendency of corrosion amount depending on the surface chloride was evaluated to analyze the correlation between surface chloride and corrosion amount, and the relation equations that can asseses the corrosion amount depending on the surface chloride were analyzed. From the results of the correlation between surface chloride and corrosion amount, it was found that the corrosion amount of the steel member affected by the surface chloride was varied up to about 1.15 times depending on the structural detail.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.218-219
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• 2017

In order to examine the possibility of practical at low-temperature environment curable cement mortar with chloride and nitrite as cold resistance admixture for rebar corrosion prevention. As a result, chloride was used using nitrite complex in low temperature environment and corrosion performance of rebar was improved and mortar strength was promoted. The ratio of nitrite than chloride applied more than twice, corrosion of the reinforcing bars will not occur even in low temperature environment, cement hydration reaction will be promoted and mortar will prevent freezing damage.

• Journal of Ocean Engineering and Technology
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• v.12 no.3 s.29
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• pp.68-74
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• 1998

An increase of concrete construction in marine environments as well as an increasing use of marine aggregate at the mixing stage of concrete has provoked an important problem. A high concentration of chloride ion in the vicinity of steel bars in concrete is the principal cause of premature reinforcement corrosion in concrete structures. In this study, the behavior of chloride ions introduced into concrete from concrete surface by marine evironment was analysed. A mathematical model including the diffusion of chloride ion in aqueous phase of pores, the adsorption and desorption of chloride ions to and from the surface of solid phase of concrete and the chemical reactions of chloride ions with solid phase was presented. Finite element method was employed to carry out numerical analysis. The results of this study may be used to predict the onset of reinforcement corrosion and to identify the maximum limit of chloride ions contained in concrete admixtures.

• Journal of Welding and Joining
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• v.15 no.5
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• pp.124-133
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• 1997

Corrosion behavior of welded SWS400 steel used for bridges was studied in a range of the acid-rain environment using immersion, potentiodynamic polartization, polarization resistance, and galvanic corrosion tests. The SWS400 steel exhibited active corrosion behavior in the range of acid-rain environment, i.e. no passivation. As the results of immersion corrosion test, Tafel extrapolation method, and polarization resistance measurement, the average corrosion rats of the steels were 0.31-0.72 mm/year in the pH of 4-5, and 0.17 mm/yera in the pH 6, respectively. The steel showed a resistance to corrosion in the pH 6. The observed active behavior of SWS400 steel in chloride-containing environment indicated that the chloride ions exerts a detrimental influence on the formation of passive films. Galvanic corrosion was observed between the weld and the base metals because the weld is anodic to the base metal.

• Corrosion Science and Technology
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• v.4 no.5
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• pp.171-177
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• 2005

A comprehensive framework for numerical simulation of time-dependent performance change of reinforced concrete (RC) structures subjected to chloride attack is presented in this paper. The system is composed of simplified computational models for transport of moisture and chloride ions in concrete pore structure and crack, corrosion of reinforcement in concrete and mechanical behavior of RC member with reinforcement corrosion. Service-life of RC structures under various conditions is calculated.

• Corrosion Science and Technology
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• v.21 no.5
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• pp.348-359
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• 2022

Interest in electric vehicle is on the rise due to global eco-friendly policies. To improve the efficiency of electric vehicles, it is essential to reduce weights of components. Since electric vehicles have various electronic equipment, the research on stray current corrosion is required. In this research, a galvanostatic corrosion experiment was performed on 6061-T6 Al alloy for electric vehicle battery housing using chloride concentration and applied current density as variables in a solution simulating an acid rain environment. As a result of the experiment, when chloride concentration and applied current density were increased, corrosion damage became larger. In particular, pitting damage was dominant at an applied current density of 0.1 mA/cm². Pitting damage over the entire surface was found at a current density of 1.0 mA/cm². In conclusion, chloride concentration had a relatively large effect on localized corrosion. The applied current density had a great effect on uniform corrosion. However, in the case of applied current density, localized corrosion was also greatly affected by interaction with chloride.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.1045-1050
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• 2001

This study was performed to evaluate reinforced concrete durability in chloride attack environment under sustained load by the corrosion of reinforcing bars and the permeation of chloride ion. Generally, it is regarded that permeability of chloride ion is determined by the properties of concrete, but the effects of load which make alternation of concrete inner structure such as crack and so on should not neglected. In this study, it is shown that the relation between bending load on RC beam, deflection and crack of specimen, permeation of chloride ion, rating of re-bar corrosion, and the relation between compression load and permeation of chloride ion. Therefore the effects of load on permeation of chloride ion and re-bar corrosion are evaluated.