• Title/Summary/Keyword: Corrosion defect

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Effects of Thickness and Defects of DLC Coating Layer on Corrosion Resistance of Metallic Bipolar Plates of PEMFCs (PEMFC 금속분리판의 내식성에 미치는 DLC 코팅층의 두께 및 결함의 영향)

  • Dong-Ho Shin;Seong-Jong Kim
    • Corrosion Science and Technology
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    • v.23 no.3
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    • pp.235-245
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    • 2024
  • DLC coatings have been widely applied in industrial fields that require high corrosion resistance due to their excellent mechanical characteristics and chemical stability. In this research, effects of DLC coating thickness and defects on corrosion resistance were investigated for application of metallic bipolar plates in polymer membrane electrolyte fuel cells (PEMFCs). Results revealed that a DLC coating thickness of 0.7 ㎛ could lead to a defect size reduction of about 75.9% compared to that of 0.3 ㎛.As a result of potentiodynamic polarization experiments, the current density under a potential of 0.6 V was measured to be less than 1 ㎂/cm2,which was an excellent value. Inparticular, the delamination ratio and the decrease rate of maximum pitting depth were up to 84.8% and 63.3%, respectively, with an increase in the DLC coating thickness. These results demonstrate that DLC coating thickness and defects are factors that can affect corrosion resistance of DLC coating and its substrate.

Estimation of Failure Probability Using Boundary Conditions of Failure Pressure Model for Buried Pipelines (파손압력모델의 경계조건을 이용한 매설배관의 파손확률 평가)

  • Lee, Ouk-Sub;Kim, Eui-Sang;Kim, Dong-Hyeok
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.310-315
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    • 2003
  • This paper presents the effect of boundary condition of failure pressure model for buried pipelines on failure prediction by using a failure probability model. The first order Taylor series expansion of the limit state function is used in order to estimate the probability of failure associated with various corrosion defects for long exposure periods in years. A failure pressure model based on a failure function composed of failure pressure and operation pressure is adopted for the assessment of pipeline failure. The effects of random variables such as defect depth, pipe diameter, defect length, fluid pressure, corrosion rate, material yield stress, material ultimate tensile strength and pipe thickness on the failure probability of the buried pipelines are systematically studied by using a failure probability model for the corrosion pipeline.

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Burst capacity of pipe under corrosion defects and repaired with thermosetting liner

  • Akram, Ali;Mustaffa, Zahiraniza;Albarody, Thar M. Badri
    • Steel and Composite Structures
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    • v.35 no.2
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    • pp.171-186
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    • 2020
  • This paper aims at providing insights on the use of thermosetting liner for the repair of offshore pipelines exposed to corrosion and leakage. The work which covers both experimental and numerical approaches were aspired due to the high cost of repair for pipelines, limitations of thermoplastic material and limited study of reinforced thermosetting liner. The experiment involves a destruction test called the burst test, carried out on an API 5L X42 carbon steel pipe under four case studies, namely (i) intact pipe, (ii) pipe with corrosion defect, (iii) pipe with corrosion defect and repaired with thermosetting liner and (iv) pipe with leakage and repaired with thermosetting liner. The numerical simulation was developed to first validate the experimental results and later to optimize the design of the thermosetting liner in terms of the number of layers required to restore the original strength of the pipe. The burst test shows an improvement in 23% of the burst capacity for the pipe with corrosion defects, after being repaired with a three-layer thermosetting liner. The parametric studies conducted showed that with an addition of thermosetting layers, the burst capacity improves by an average of 1.85 MPa. In conclusions, the improvement in strength can be further increased with increasing thickness of the thermosetting liner. The thermosetting liner was also determined to fail first inside the host pipe.

Burst Behavior for Mechanically Machined Axial Flaws of Steam Generator Tubings

  • Hwang, Seong Sik;Kim, Hong Pyo;Kim, Joung Soo
    • Corrosion Science and Technology
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    • v.3 no.1
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    • pp.30-33
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    • 2004
  • It has been reported that some events of a rupture of seam generator tube have occurred in nuclear power plants around the world. Main causes of the leakage are from various types of corrosion in the steam generator(SG) tubings. Primary water stress corrosion cracking(PWSCC) of steam generator tubings have occurred in many tubes in Korean plant, and they were repaired using sleeves or plugs, In order to develop proper repair criteria, it is necessary to ascertain the leak behavior of the tubings. A high pressure leak and burst testing system was manufactured. Various types of Electro Discharged Machined (EDM) notches were developed on the SG tubes. Leak rate and burst pressure were measured on the tubes at room temperature. Burst pressure of the part through wall defected tubes depends on the defect depth, Water flow rates after the burst were independent of the t1aw types; tubes having 20 to 60 mm long EDM notches showed similar flow rates regardless of the defect depth. A fast pressurization rate gave the tube a lower burst pressure than the case of a slow pressurization.

Electrochemical Corrosion Damage Characteristics of Aluminum Alloy Materials for Marine Environment (해양환경용 알루미늄 합금 재료의 전기화학적 부식 손상 특성)

  • Kim, Sung Jin;Hwang, Eun Hye;Park, Il-Cho;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.51 no.6
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    • pp.421-429
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    • 2018
  • In this study, various electrochemical experiments were carried out to compare the corrosion characteristics of AA5052-O, AA5083-H321 and AA6061-T6 in seawater. The electrochemical impedance and potentiostatic polarization measurements showed that the corrosion resistance is decreased in the order of AA5052-O, AA5083-H321 and AA6061-T6, with AA5052-O being the highest resistant. This is closely associated with the property of passive film formed on three tested Al alloys. Based on the slope of Mott-Schottky plots of an n-type semiconductor, the density of oxygen vacancies in the passive film formed on the alloys was determined. This revealed that the defect density is increased in the order of AA5052-O, AA5083-H321 and AA6061-T6. Considering these facts, it is implied that the addition of Mg, Si, and Cu to the Al alloys can degrade the passivity, which is characterized by a passive film structure containing more defect sites, contributing to the decrease in corrosion resistance in seawater.

Technology for the Detection of Corrosion Defects in Buried Pipes of Nuclear Power Plants with 3D FEM (3D 유한요소법을 이용한 원전 매설배관 부식결함 탐상기술 개발)

  • Kim, Jae-Won;Lim, Bu-Taek;Park, Heung-Bae;Chang, Hyun-Young
    • Corrosion Science and Technology
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    • v.17 no.6
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    • pp.292-300
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    • 2018
  • The modeling of 3D finite elements based on CAD data has been used to detect sites of corrosion defects in buried pipes. The results generated sophisticated profiles of electrolytic potential and vectors of current distributions on the earth surface. To identify the location of defects in buried pipes, the current distribution on the earth surface was projected to a plane of incidence that was identical to the pipe locations. The locations of minimum electrolytic potential value were found. The results show adequate match between the locations of real and expected defects based on modeling. In addition, the defect size can be calculated by integrating the current density curve. The results show that the defect sizes were $0.74m^2$ and $0.69m^2$, respectively. This technology may represent a breakthrough in the detection of indirect damage in various cases involving multiple defects in size and shape, complex/cross pipe systems, multiple anodes and stray current.

Study on the effect of corrosion defects on VIV behavior of marine pipe using a new defective pipe element

  • Zhang, He;Xu, Chengkan;Shen, Xinyi;Jiang, Jianqun
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.12 no.1
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    • pp.552-568
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    • 2020
  • After long-term service in deep ocean, pipelines are usually suffered from corrosions, which may greatly influence the Vortex-Induced Vibration (VIV) behavior of pipes. Thus, we investigate the VIV of defective pipelines. The geometric nonlinearity due to large deformation of pipes and nonlinearity in vortex-induced force are simulated. This nonlinear vibration system is simulated with finite element method and solved by direct integration method with incremental algorithm. Two kinds of defects, corrosion pits and volumetric flaws, and their effects of depth and range on VIV responses are investigated. A new finite element is developed to simulate corrosion pits. Defects are found to aggravate VIV displacement response only if environmental flow rate is less than resonance flow rate. As the defect depth grows, the stress responses increase, however, the increase of the defect range reduces the stress response at corroded part. The volumetric flaws affect VIV response stronger than the corrosion pits.

Investigation of Streaky Mark Defect on Hot Dip Galvannealed IF Steel

  • Xinyan, Jin;Li, Wang;Xin, Liu
    • Corrosion Science and Technology
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    • v.9 no.3
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    • pp.109-115
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    • 2010
  • Interstitial-free (IF) steels are widely used for car body material. However, a few types of streaky mark defect are commonly found on hot dip galvannealed (GA) IF steel sheets. In the present study, both the phase structure of a streaky mark defect and the microstructure of the substrate just below it were characterized by optical microscopy (OM) and scanning electron microscopy (SEM). It was found that the bright streaky mark area was composed of ${\delta}$ phase while the dark normal area was full of craters. More than half of the grains at the uppermost surface of the substrate just below the streaky mark defect are unrecrystallized grains which could result from lower finish rolling temperature during hot rolling and be kept stable during the annealing process, while almost all the grains in the normal area are equiaxed grains. In order to confirm the effect of the unrecrystallized grains on the coating morphology, hot dip galvannealing simulation experiments were carried out in IWATANI HDPS. It is proved that the unrecrystallized grains accelerate the Fe-Zn reaction rate during galvannealing and result in a flatter coating surface and an even coating thickness. Finally, a formation mechanism of the streaky mark defect on the hot dip galvannealed IF steel sheet was discussed.

Strain Distribution Measurement for Wall Thinning Defect in Pipe Bends by ESPI (ESPI 를 이용한 곡관 감육 결함부의 변형률 분포 측정)

  • Naseem, Akhter;Kim, Koung-Suk;Jung, Sung-Wook;Park, Jong-Hyun;Choi, Jung-Suk;Jung, Hyun-Chul
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.120-125
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    • 2007
  • Put Abstract text here The strain distribution measurement for wall thinned pipe bends by ESPI is presented. Defect types observed in the steel piping in the nuclear power plants (NPP) are the crack at the weld part and the wall thinning defect in the pipe bends. Especially, the wall thinning defects in the pipe bends due to the flow-accelerated corrosion (FAC) is a main type of defects observed in the carbon steel piping system. ESPI is one of the optical non-destructive testing methods and can measure the stress and the strain distribution of the object subjected by the tensile loading or the internal pressure. In this paper, the strain distribution of the wall thinned pipe bends due to the internal pressure will be measured by ESPI technique and the results are discussed. From the results, the size of the wall thinning defect can also be measured approximately.

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Fabrication and Use of Corrosion Defect Specimens for Enhancement of ECT Reliability for Nuclear Steam Generator Tubing (증기발생기 전열관 와전류 검사의 신뢰성 향상을 위한 부식결함 시편의 제작 및 활용)

  • Hur, Do-Haeng;Choi, Myung-Sik;Lee, Doek-Hyun;Park, Jung-Am;Han, Jung-Ho
    • Journal of the Korean Society for Nondestructive Testing
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    • v.20 no.5
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    • pp.451-456
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    • 2000
  • The development of an integrated technology including fabrication of corrosion defect specimens and their practical use is needed to enhance the reliability of eddy current test for nuclear steam generator tubing. In this paper, the necessity and importance are presented from the viewpoint of the structural integrity, simulation specimens for real defects, and experiences from the destructive examination of pulled tubes. The models for several corrosion defects we also briefly introduced, with the scheme for their practical use.

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