• Title/Summary/Keyword: Corrosion Model

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Revisiting exponential stress corrosion model

  • Elishakoff, Isaac;Miglis, Yohann
    • Ocean Systems Engineering
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    • v.1 no.2
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    • pp.121-130
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    • 2011
  • One of the prevailing models that describe the stress corrosion is represented by an exponential dependence between rate of corrosion and stress, suggested by Gutman, Zainullin and Zuripov. This study revisits the exponential model and derives analytical expressions for the structures' durability which is postulated as the time for stress level to reach its yield value. Comparison is conducted with other possible models, namely with linear, quadratic or cubic cases.

Comprehensive Empirical Equation for Assessing Atmospheric Corrosion Progression of Steel Considering Environmental Parameters

  • Sil, Arjun;Kumar, Vanapalli Naveen
    • Corrosion Science and Technology
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    • v.19 no.4
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    • pp.174-188
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    • 2020
  • Atmospheric corrosion is a natural surface degradation process of metal due to changes in environmental parameters in the surrounding atmosphere. It is very sensitive to environmental parameters such as temperature, relative humidity, sulphur dioxide, and chloride, making it a major global economic challenge. Existing forecasting empirical corrosion models including the ISO standard are based on statistical analysis of experimental studies without considering the behavior of atmospheric parameters. The present study proposes a reliable global empirical model for estimating short and long-term atmospheric corrosion rates based on environmental parameters and corrosion mechanisms obtained from a parametric study. Repercussion of atmospheric corrosion rate due to individual and combined influences of environmental parameters specifies their importance in the estimation. New global empirical coefficients obtained for environmental parameters are statistically established (R2 =0.998) with 95% confidence limit. They are validated using experimental datasets of existing studies observed at 88 different continental locations. The current proposed model can predict atmospheric corrosion by means of corrosion formation mechanisms influenced by combined effects of environmental parameters, further abating applicability limitations of location and time.

Evaluation of carbonation service life of slag blended concrete considering climate changes

  • Wang, Xiao-Yong;Luan, Yao
    • Computers and Concrete
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    • v.21 no.4
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    • pp.419-429
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    • 2018
  • Climate changes, such as increasing of $CO_2$ concentration and global warming, will impact on the carbonation service life of concrete structures. Moreover, slag blended concrete has a lower carbonation resistance than control concrete. This study presents a probabilistic numerical procedure for evaluating the impact of climate change on carbonation service life of slag blended concrete. This numerical procedure considers both corrosion initiation period and corrosion propagation period. First, in corrosion initiation period, by using an integrated hydration-carbonation model, the amount of carbonatable substances, porosity, and carbonation depth are calculated. The probability of corrosion initiation is determined through Monte Carlo method. Second, in corrosion propagation period, a probabilistic model is proposed to calculate the critical corrosion degree at surface cracking, the probability of surface cracking, and service life. Third, based on the service life in corrosion initiation period and corrosion propagation period, the whole service life is calculated. The analysis shows that for concrete structures with 50 years service life, after considering climate changes, the service life reduces about 7%.

An advanced technique to predict time-dependent corrosion damage of onshore, offshore, nearshore and ship structures: Part I = generalisation

  • Kim, Do Kyun;Wong, Eileen Wee Chin;Cho, Nak-Kyun
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.12 no.1
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    • pp.657-666
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    • 2020
  • A reliable and cost-effective technique for the development of corrosion damage model is introduced to predict nonlinear time-dependent corrosion wastage of steel structures. A detailed explanation on how to propose a generalised mathematical formulation of the corrosion model is investigated in this paper (Part I), and verification and application of the developed method are covered in the following paper (Part II) by adopting corrosion data of a ship's ballast tank structure. In this study, probabilistic approaches including statistical analysis were applied to select the best fit probability density function (PDF) for the measured corrosion data. The sub-parameters of selected PDF, e.g., the largest extreme value distribution consisting of scale, and shape parameters, can be formulated as a function of time using curve fitting method. The proposed technique to formulate the refined time-dependent corrosion wastage model (TDCWM) will be useful for engineers as it provides an easy and accurate prediction of the 1) starting time of corrosion, 2) remaining life of the structure, and 3) nonlinear corrosion damage amount over time. In addition, the obtained outcome can be utilised for the development of simplified engineering software shown in Appendix B.

Model Cut-edge Formed on Zinc Coated Steels by Laser Machining and Its Corrosion Behavior

  • Sakairi, Masatoshi;Kageyama, Akihiro;Kikuhchi, Tatsuya
    • Corrosion Science and Technology
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    • v.9 no.1
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    • pp.29-33
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    • 2010
  • Laser machining technique, which is used focusing pulse YAG laser beam irradiation was applied to form area ratio controlled model cut-edge on pre painted Zn coated steels. A corrosion behavior of formed model cut-edge was investigated by rest potential measurement in 1 mol $m^{-3}$ NaCl with and without 0.5 kmol $m^{-3}$ $H_3BO_4$/0.05kmol$m^{-3}$ $Na_2B_4O_7$. The rest potential showed almost constant value with fluctuations. The amplitude of fluctuations increased with exposed area of steel surface. White corrosion products of zinc oxide and simonkollite was formed after the experiments at the formed model cut-edge.

Simulation of corroded RC structures using a three-dimensional irregular lattice model

  • Kim, Kunhwi;Bolander, John E.;Lim, Yun Mook
    • Structural Engineering and Mechanics
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    • v.41 no.5
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    • pp.645-662
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    • 2012
  • Deteriorative effects of steel corrosion on the structural response of reinforced concrete are simulated for varying degrees of corrosion. The simulation approach is based on a three-dimensional irregular lattice model of the bulk concrete, in which fracture is modeled using a crack band approach that conserves fracture energy. Frame elements and bond link elements represent the reinforcing steel and its interface with the concrete, respectively. Polylinear stress-slip properties of the link elements are determined, for several degrees of corrosion, through comparisons with direct pullout tests reported in the literature. The link properties are then used for the lattice modeling of reinforced concrete beams with similar degrees of corrosion of the main reinforcing steel. The model is successful in simulating several important effects of steel corrosion, including increased deflections, changes in flexural cracking behavior, and reduced yield load of the beam specimens.

On the Implementation of Fuzzy Arithmetic for Prediction Model Equation of Corrosion Initiation

  • Do Jeong-Yun;Song Hun;Soh Yang-Seob
    • Journal of the Korea Concrete Institute
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    • v.17 no.6 s.90
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    • pp.1045-1051
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    • 2005
  • For critical structures and application, where a given reliability must be met, it is necessary to account for uncertainties and variability in material properties, structural parameters affecting the corrosion process, in addition to the statistical and decision uncertainties. This paper presents an approach to the fuzzy arithmetic based modeling of the chloride-induced corrosion of reinforcement in concrete structures that takes into account the uncertainties in the physical models of chloride penetration into concrete and corrosion of steel reinforcement, as well as the uncertainties in the governing parameters, including concrete diffusivity, concrete cover depth, surface chloride concentration and critical chloride level for corrosion initiation. The parameters of the models are regarded as fuzzy numbers with proper membership function adapted to statistical data of the governing parameters and the fuzziness of the corrosion time is determined by the fuzzy arithmetic of interval arithmetic and extension principle

An advanced technique to predict time-dependent corrosion damage of onshore, offshore, nearshore and ship structures: Part II = Application to the ship's ballast tank

  • Kim, Do Kyun;Lim, Hui Ling;Cho, Nak-Kyun
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.12 no.1
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    • pp.645-656
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    • 2020
  • In this study (Part II), the empirical formulation of corrosion model of a ship's ballast tank was developed to predict nonlinear time-dependent corrosion wastage based on the advanced data processing technique proposed by Part I. The detail on how to propose generalised mathematical formulation of corrosion model was precisely documented in the previous paper (Part I). The statistical scatter of corrosion data at any exposure time was investigated by the refined method and formulated based on a 2-parameter Weibull distribution which selected the best fit PDF. Throughout the nine (9) steps, empirical formulation of the ship's seawater ballast tank was successfully proposed and four (4) key step results were also obtained. The proposed method in Part I was verified and confirmed by this application of seawater ballast tank, thus making it possible to predict accurate behaviours of nonlinear timedependent corrosion. Developed procedures and obtained corrosion damage model for ship's seawater ballast tank can be used for development of engineering software.

A Comparison of Four Atmospheric Corrosivity Modeling Results for Aircraft (4개 모델에 따른 항공기의 대기 부식성 모의 결과 비교)

  • Mu-sung Woo;Jae-won Lee;Ji-hye Lee;Kyong-jin Woo;Jongchul Park
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.31 no.3
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    • pp.79-92
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    • 2023
  • Aluminum alloys are important materials in modern aircraft. Aircraft failures due to corrosion are fatal and costly. Thus, information about the atmospheric corrosion of aluminum is helpful for aviation safety. This study employed four corrosion models and 12 environmental variables to improve knowledge of aluminum atmospheric corrosivity: PACER LIME, ICP, ISO CORRAG, and a modified model of CORRAG. This study applied each model on 47 aircraft operating bases in Korea and compared the results. In the results, The risk of corrosion was different for each model. The cause was the difference in environmental variables according to the model. Especially, the effect of ozone, which has recently been increasing, was shown in the results of PACER LIME. These findings suggest that caution is needed when assessing atmospheric corrosion risk as a single model. Furthermore, it means that the application and integration of various models are needed to improve atmospheric corrosion risk assessment.

Service Life Prediction of Concrete Structures Exposed to a Sulfuric Acid Environment

  • Jeon, Joong-Kyu;Moon, Han-Young;Jeon, Chan-Ki;Song, Jong-Hwa
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.385-389
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    • 2007
  • In this study, it was investigated the resistance of OPC, 60% GGBS, 20% PFA and 10% SF mortar specimens against sulfuric acid corrosion. As an index for degree of acid corrosion, the corrosion depth was evaluated. Then, it was found that an increase in the duration of immersion and a decrease in the pH, as expected, resulted in a more severe corrosion irrespective of binders; 60% GGBS mortar specimen was the most resistant to sulfuric acid corrosion. From the laboratory testing of sulfuric acid corrosion, an empirical prediction model was suggested as a power function of time and the pH of sulfuric acid, and was applied to an assessment of concrete structures exposed to an acidic environment. It was found that the empirical model gave a more precise prediction of sulfuric acid deterioration of concrete rather than a conventional model, mostly used for predicting carbonation of concrete.