• Title/Summary/Keyword: Corrosion Degradation

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Development and Application of Anti-Corrosive Steel Using Electro-Deposition of Sea Water (2)- Evaluation of Application Rebar with Electro-Deposition Using Sea Water (해수전착 코팅을 이용한 내부식성 철근의 개발 및 적용성에 대한 연구 (2) -해수전착된 구조용 철근의 적용성 평가)

  • Kwon, Seung Jun;Lee, Sang Min;Park, Sang Soon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.155-162
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    • 2012
  • When RC (Reinforced Concrete) structures are exposed to sea water, steel corrosion can occur and this leads a degradation of structural performance. Referring the electro-deposition system with sea water from the 1st step research, durability and structural performance are evaluated in coated steel and RC members containing it in the 2nd research. In the durability performance test, Half Cell Potential test is performed and the coated steel is evaluated to have the high resistance to corrosion, which shows only 35% of corrosion velocity in normal (bare) steel. In the structural performance test, tensile strength, adhesive strength, and flexural/shear in RC member are performed. For the electro-deposit coated steel, increasing ratios of 3.2% and 8.8% are evaluated in the test of tensile strength and adhesive strength, respectively. For the structural test in RC member, there is no big difference between RC members with coated and non-coated steel in ultimate load and failure pattern It is evaluated that the chemical compound with $CaCO_3$ and $Mg(OH)_2$ from electro-deposition causes slightly increased structural performance. The electro-deposit coated steel can be more widely applied after performance verification from several tests like fatigue, resistance to impact, and long term-submerging test.

Chloride penetration in anchorage concrete of suspension bridge during construction stage

  • Yang, In-Hwan;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Advances in concrete construction
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    • v.10 no.1
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    • pp.13-20
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    • 2020
  • Steel corrosion in embedded steel causes a significant durability problems and this usually propagates to structural degradation. Large-scaled concrete structures, PSC (Pre-stressed Concrete) or RC (Reinforced Concrete) structures, are usually constructed with mass concrete and require quite a long construction period. When they are located near to sea shore, chloride ion penetrates into concrete through direct or indirect exposure to marine environment, and this leads durability problems. Even if the structures are sheltered from chloride ingress outside after construction, the chloride contents which have been penetrated into concrete during the long construction period are differently evaluated from the initially mixed chloride content. In the study, chloride profiles in cores extracted from anchorage concrete block in two large-scaled suspension bridge (K and P structure) are evaluated considering the exposure periods and conditions. Total 21 cores in tendon room and chamber room were obtained, and the acid-soluble chlorides and compressive strength were evaluated for the structures containing construction period around 3 years. The test results like diffusion coefficient and surface chloride content from the construction joint and cracked area were also discussed with the considerations for maintenance.

The Evaluation of Mechanical Property of X20CrMoV12.1 Boiler Tube Steels (X20CrMoV12.1강의 열화에 따른 기계적특성 평가)

  • Kim, B.S.;Lee, S.H.;Kim, D.S.;Jung, N.G.
    • Journal of Power System Engineering
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    • v.8 no.3
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    • pp.18-22
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    • 2004
  • Boiler is one of the most important utilities providing steam to turbine in order to supply mechanical energy in thermal power plant. It is composed of thousands of tubes for high efficient heat transfer. The material for boiler tubes is used in such high temperature and pressure condition as $540^{\circ}C$, 22MPa. The boiler tube material is required to resist creep damage, fatigue cracking, and corrosion damages. 2.25%Cr-1Mo steel is used for conventional boiler tubes, and austenitenite stainless steel is used for higher temperature boiler tubes. But the temperature and pressure of steam in power plant became higher for high plant efficiency. So, the property of boiler tube material must be upgaded to fit the plant property. Several boiler tube material was developed to fit such conditions. X20CrMoV12.1 steel is also developed in 1980's and used for superheater and reheater tubes in supercritical boilers. The material has martensite microstructures which is difficult to evaluate the degradation. In this thesis, degrade the X20CrMoV12.1 steel at high temperatures in electric furnace, and evaluate hardness with Vickers hardness tester and strengths with Indentation tester.

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A Study on the Rail Vehicle Applications and Increase the Capacity of Lithium Polymer Batteries (리튬폴리머 축전지의 철도차량 적용 및 용량증대에 관한 연구)

  • Cho, Kyu-Hwa;Kang, Seung-Wook
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.65 no.4
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    • pp.340-345
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    • 2016
  • Railway vehicle battery is supplying the power required for the initial start-up of the train, in the event of a fault in the vehicle, or catenary for supplying emergency power is one of the components are very important. Currently, the railway vehicles such as nickel-cadmium batteries are being used [1,2]. Ni-Cd batteries as a battery installed in the railway vehicles have a strong corrosion resistance is included, The charge-discharge performance is significantly degraded in cold weather, there is a danger of deterioration or explosion. Train accidents have been caused a lot of damage due to rapid deterioration and cracking of the battery and memory due to the effect of Ni-Cd batteries. In order to solve the problems, There is no risk of degradation, deterioration and leakage, cracking and exploding. maintenance is simple and applied measures proposed to apply Lithium Polymer battery of high performance. In addition, the lack of capacity problems identified by testing the different special systems is replaced by a 70Ah lithium-polymer battery is possible without changing the batteries of 50Ah caused by installing additional equipment in existing older trains were applied to the vehicle.

Oxidation of organic contaminants in water by iron-induced oxygen activation: A short review

  • Lee, Changha
    • Environmental Engineering Research
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    • v.20 no.3
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    • pp.205-211
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    • 2015
  • Reduced forms of iron, such as zero-valent ion (ZVI) and ferrous ion (Fe[II]), can activate dissolved oxygen in water into reactive oxidants capable of oxidative water treatment. The corrosion of ZVI (or the oxidation of (Fe[II]) forms a hydrogen peroxide ($H_2O_2$) intermediate and the subsequent Fenton reaction generates reactive oxidants such as hydroxyl radical ($^{\bullet}OH$) and ferryl ion (Fe[IV]). However, the production of reactive oxidants is limited by multiple factors that restrict the electron transfer from iron to oxygen or that lead the reaction of $H_2O_2$ to undesired pathways. Several efforts have been made to enhance the production of reactive oxidants by iron-induced oxygen activation, such as the use of iron-chelating agents, electron-shuttles, and surface modification on ZVI. This article reviews the chemistry of oxygen activation by ZVI and Fe(II) and its application in oxidative degradation of organic contaminants. Also discussed are the issues which require further investigation to better understand the chemistry and develop practical environmental technologies.

Cavity and Interface effect of PI-Film on Charge Accumulation and PD Activity under Bipolar Pulse Voltage

  • Akram, Shakeel;Wu, Guangning;Gao, GuoQiang;Liu, Yang
    • Journal of Electrical Engineering and Technology
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    • v.10 no.5
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    • pp.2089-2098
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    • 2015
  • With the continuous development in insulation of electrical equipment design, the reliability of the system has been enhanced. However, in the manufacturing process and during operation under continues stresses introduce local defects, such as voids between interfaces that can responsible to occurrence of partial discharge (PD), electric field distortion and accumulation of charges. These defects may lead to localize corrosion and material degradation of insulation system, and a serious threat to the equipment. A model of three layers of PI film with air gap is presented to understand the influence of interface and voids on exploitation conditions such as strong electrical field, PD activity and charge movement. The analytical analysis, and experimental results are good agreement and show that the lose contact between interfaces accumulate more residual charges and in consequences increase the electric field intensity and accelerates internal discharges. These residual charges are trapped charges, injected by the electrodes has often same polarity, so the electric field in cavities increases significantly and thus partial discharge inception voltage (PDIV) decreases. Contrary, number of PD discharge quantity increases due to interface. Interfacial polarization effect has opposite impact on electric field and PDIV as compare to void.

A Study to Simulate Cell Voltage-Reversal Behavior Caused by Local Hydrogen Starvation in a Stack of Fuel Cell Vehicle (연료전지차 스택 내 국부적 수소 부족에 기인한 셀 역전압 거동 모사에 대한 연구)

  • Park, Ji Yeon;Im, Se Joon;Han, Kookil;Hong, Bo Ki
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.4
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    • pp.311-319
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    • 2013
  • A clear understanding on cell voltage-reversal behavior due to local hydrogen starvation in a stack is of paramount importance to operate the fuel cell vehicle (FCV) stably since it affects significantly the cell performance and durability. In the present study, a novel experimental method to simulate the local cell voltage-reversal behavior caused by local hydrogen starvation, which typically occurs only one or several cells out of several hundred cells in a stack of FCV, has been proposed. Contrary to the conventional method of overall fuel starvation, the present method of local hydrogen starvation caused the local cell voltage-reversal behavior in a stack very well. Degradation of both membrane electrode assembly (i.e., pin-hole formation) and gas diffusion layer due to an excessive exothermic heat under voltage-reversal condition was also observed clearly.

A Review of the Progress with Statistical Models of Passive Component Reliability

  • Lydell, Bengt O.Y.
    • Nuclear Engineering and Technology
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    • v.49 no.2
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    • pp.349-359
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    • 2017
  • During the past 25 years, in the context of probabilistic safety assessment, efforts have been directed towards establishment of comprehensive pipe failure event databases as a foundation for exploratory research to better understand how to effectively organize a piping reliability analysis task. The focused pipe failure database development efforts have progressed well with the development of piping reliability analysis frameworks that utilize the full body of service experience data, fracture mechanics analysis insights, expert elicitation results that are rolled into an integrated and risk-informed approach to the estimation of piping reliability parameters with full recognition of the embedded uncertainties. The discussion in this paper builds on a major collection of operating experience data (more than 11,000 pipe failure records) and the associated lessons learned from data analysis and data applications spanning three decades. The piping reliability analysis lessons learned have been obtained from the derivation of pipe leak and rupture frequencies for corrosion resistant piping in a raw water environment, loss-of-coolant-accident frequencies given degradation mitigation, high-energy pipe break analysis, moderate-energy pipe break analysis, and numerous plant-specific applications of a statistical piping reliability model framework. Conclusions are presented regarding the feasibility of determining and incorporating aging effects into probabilistic safety assessment models.

Probabilistic Damage Mechanics Assessment of CANDU Pressure Tube using Genetic Algorithm (유전자 알고리즘을 이용한 CANDU 압력관의 확률론적 손상역학 평가)

  • Ko, Han-Ok;Chang, Yoon-Suk;Choi, Jae-Boong;Kim, Young-Jin;Kim, Hong-Key;Choi, Young-Hwan
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.192-192
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    • 2008
  • As the lifetime of nuclear power plants (NPPs) reaches design life, the probability for fatal accidents increases. Most of accidents are known to be caused by degradation of mechanical components. Pressure tubes are the most important components in CANDU reactor. They are subjected to various aging mechanisms such as delayed hydride cracking (DHC), irradiation and corrosion, etc. Therefore, the integrity of pressure tube is key concern in CANDU reactor. Up to recently, conventional deterministic approaches have been utilized to evaluate the integrity of components. However, there are many uncertainties to prevent a rational evaluation. The objective of this paper is to assess the failure probability of pressure tube in CANDU. To do this, probability fracture mechanics (PFM) analysis based on the Genetic Algorithm (GA) is performed. For the verification of the analysis, a comparison of the PFM analysis using a commercial code and mathematical method is carried out.

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Numerical Analysis of Heat Transfer and Fabrication of Carbon Material for Heat Dissipation in Solar Panel (태양광 패널 적용 방열용 탄소소재의 제조 및 열전달 수치해석)

  • Park, Hun-Su;Kang, Chul-Hee;Kim, Hong-Gun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.12
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    • pp.82-90
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    • 2019
  • This analysis demonstrates the effective removal of heat generated from a solar panel's output degradation factor solar cells (the solar panel's output deterioration factor), and solves the problems of oxidation and corrosion in existing metal heat sinks. The heat-dissipating test specimen was prepared using carbon materials; then, its thermal conductivity and its effectiveness in reducing temperatures were studied using heat transfer numerical analysis. As a result, the test specimen of the 30g/㎡ basis weight containing 80% of carbon fiber impregnated with carbon ink showed the highest thermal conductivity 6.96 W/(m K). This is because the surface that directly contacted the solar panel had almost no pores, and the conduction of heat to the panels appeared to be active. In addition, a large surface area was exposed to the atmosphere, which is considered advantageous in heat dissipation. Finally, numerical analysis confirmed the temperature reduction effectiveness of 2.18℃ in a solar panel and 1.08℃ in a solar cell, depending on the application of heat dissipating materials.