• 한국식품위생안전성학회지
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• 제35권2호
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• pp.177-182
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• 2020

본 연구에서는 건조 고춧가루의 가공 및 저장라인에서 구리의 이용가능성을 조사하였다. 구리와 스테인리스강 표면과의 접촉을 통한 고춧가루의 색도 변화를 평가한 결과, 55℃에서 2시간 구리 판에 처리한 시료의 명도가 다소 증가하였다. 구리와 스테인리스강 접촉에 의한 고춧가루 내 미생물 저해는 중온성의 호기성 세균보다 곰팡이 및 효모의 저해에 더 효과적이었고, 55℃에서 2시간 구리 접촉에 의해 곰팡이와 효모의 수는 0.64 log 감소하여 유의적인 효과를 나타내었다. 산화방지 활성은 구리와 스테인리스강 접촉 고춧가루의 DPPH 라디칼 소거활성은 감소한 반면 ABTS 라디칼 소거활성은 증가하였다. 본 연구는 구리 또는 구리와 스테인리스강 등의 합금을 이용하여 고춧가루를 포함한 다양한 분말 식품의 가공 및 저장 과정에 활용할 수 있는 가능성을 제시하고 있다.

• 대한핵의학회지
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• 제1권1호
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• pp.21-35
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• 1967

Anemia is a usual finding in advanced malignant diseases. Various mechanisms were reported as to be involved in the development of anemia of this kind, and they may differ in individual cases. Tumor anemias may be due, for instance, to chronic blood loss, shortened life span of the red blood cells or a decreased hemopoiesis in the bone marrow. The serum iron and copper levels, total iron binding capacity, apparent half survival of $^{51}Cr$-labelled red blood cells were measured along with the ferrokinetic studies using $^{59}Fe$ in 64 patients with various malignant tumors. Following were the results: 1. The serum iron levels were decreased in all cases. There existed no correlation between the serum iron levels and the severity of the diseases. 2. The serum copper levels were increased, particularly in lung cancer, rectal cancer, hepatoma and various sarcomas. There was also no correlation between the serum copper levels and the severity of the diseases. 3. The serum iron levels appeared to be inversely proportional to the serum copper levels. 4. The total iron binding capacities were within normal limits in all cases. There were also no correlations between the total iron binding capacities, serum iron levels and the severity of the diseases. 5. The patients could be classified according to the ferrokinetic patterns, namely, that of iron deficiency anemia in 10 cases, that of refractory anemia in 6 cases, normal in 1 case and that of atypical abnormal in 9 cases. 6. Apparent half survival time of $^{51}Cr$-labelled red blood cells were definitely shortened in half of the cases.

• 자원환경지질
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• 제18권4호
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• pp.301-308
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• 1985

I.P exploration is conducted mainly at the alluvium covered granodiorite stock of the Red Hill area at the Dongjeom coal mine, employing Canadian Mcphar equipments of variable frequencies-domain method along a total of 8.5 survey line. Mineralization zone is found by LP anomalies along the I.P the profile of frequency mode. Comparing with the past drilling data, the cause of each anomly is furthermore identified as copper bearing mineralized zones. As alteration and mineralization cover all over the Red-Hill altered grandiorite, copper bearing sulfide veinlets and strings filled out the fractured and altered zones.

• 한국어류학회지
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• 제29권1호
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• pp.41-51
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• 2017

어류양식용 가두리로서 동합금가두리망의 현장활용 가능성을 파악하기 위해 양식어류인 2년산 참돔을 동합금망과 합성섬유망에서 9개월 동안 각각 사육관리하면서 참돔에 미치는 양식생물학적 및 병리학적 영향을 조사하여 생물학적 안전성을 평가하였다. 동합금가두리망은 지름 25 m, 깊이 10 m의 규모로 제작하여 경남 통영시 욕지면 주변해역 연구교습어장에 설치하였다. 동합금가두리망과 합성섬유망에서 사육한 참돔의 생존율은 각각 99.75%와 99.70%로 유의한 차이는 나타나지 않았다. 일일체중성장률은 동합금가두리망과 합성섬유망에서 각각 2.13 g/day와 1.65 g/day로 동합금가두리망에서 사육한 참돔의 성장률이 빠른 것으로 나타났다. 혈액성분 분석에 따른 건강도 평가는 합성섬유망에 비해 동합금가두리망에서 양호한 것으로 나타났다. 가두리망 종류별 사육중인 참돔의 구리와 아연의 축적은 다른 기관에 비해 생식소에서 축적이 높게 나타났으며, 가용부분인 근육내 중금속 축적은 허용기준치에 비해 매우 낮았다. 또한 병원체 감염조사결과 동합금가두리망과 합성섬유망에서 기생충은 Microcotyle tai, 세균은 Vibrio alginolyticus 외 5종 등이 공통적으로 관찰되었으나, 동합금가두리망에서 Vibrio속의 세균 감염률에는 다소 차이를 보여 항균작용이 있을 것으로 예상된다. 따라서 동합금가두리망의 시스템안정성, 재활용가능성, 항균성 및 식품안전성 등을 고려할 때 어류양식용 가두리로 현장에서 활용이 가능할 것으로 여겨진다.

• 한국결정성장학회지
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• 제27권5호
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• pp.243-248
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• 2017

본 연구에서는 산화주석(IV) 첨가량을 달리하여 동화유약 시편을 제조하고 발색기구를 분석하기 위하여 분광 분석, 결정상 분석, 미세구조 분석을 실시하여 색상과의 상관성을 분석하였다. 산화주석(VI) 첨가량이 증가함에 따라 동화유약의 붉은색은 사라지고 CIEab 값이 감소하여 무채색으로 발색하였다. 산화주석은 유약층에 고르게 분포하여 Cu nuclei가 성장하여 붉은색으로 발색하는 것을 방해하고 기포 주변의 metal Cu와 반응하여 합금을 형성하였다. 이로 인해 산화주석 첨가량이 증가함에 따라 금속 Cu 피크는 사라지고 미세한 $Cu_2O$ 피크만 남게 된다. 산화주석을 3.79 % 첨가하였을 때는 유약에 붉은색을 내는 $Cu_2O$보다 검정색을 나타내는 CuO와 Cassiterite $SnO_2$가 색상에 더 영향을 미치는 것으로 보여진다.

• 한국세라믹학회지
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• 제23권6호
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• pp.15-24
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• 1986

• Bulletin of the Korean Chemical Society
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• 제24권12호
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• pp.1767-1770
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• 2003

A simple, rapid and sensitive spectrophotometric method is herewith proposed for the determination of copper(II) by using diamine-dioxime ligand, meso-3,6,6,9-tetramethyl-4,8-diazaundecane-2,10-dione dioxime or meso-HexaMethyl Propylene Amine Oxime (meso-HMPAO). This method is based on the formation of a stable 1 : 1 red-pink complex between copper(II) and meso-HMPAO in aqueous solution. Absorption measurements were carried at 497 nm, with a molar absorptivity value of 338 L $mol^{-1}\;cm^{-1}$. Beer's law was obeyed over the concentration range of 0.5-370 ${\mu}$g $mL^{-1}$ with a Sandell's sensitivity value of 0.18 ${\mu}$g $cm^{-2}$. The proposed method has been successfully applied for determination of copper(II) in foodstuffs and pharmaceutical samples. The results obtained from this method are comparable with those obtained AAS.

• 한국전기전자재료학회논문지
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• 제30권10호
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• pp.651-655
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• 2017

This work reports the surface morphology and transmittance of copper oxide thin films for semitransparent solar cell applications. We prepared the oxide specimens by subjecting copper thin films to an oxidation reaction at annealing temperatures ranging between $100^{\circ}C$ and $300^{\circ}C$. The color of the as-deposited specimen was red, but changed to purple at the annealing temperature of $300^{\circ}C$. The surface morphology and transmittance of the specimens were significantly dependent on the annealing temperature and thickness of the copper films. Copper oxide nanoparticles prepared from a 20-nm-thick copper film at an annealing temperature of $300^{\circ}C$ provided a maximum transmittance of 93%. The obtained optical characteristics and surface morphology suggest that copper oxide thin films prepared by an oxidation reaction can be potentially employed as color- and transmittance-adjusting layer in semitransparent thin solar cells.

• 상하수도학회지
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• 제33권2호
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• pp.131-140
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• 2019

This study used a packed column reactor and a horizontal flow mesh reactor to examine the removal of copper ions from aqueous solutions using pine bark, a natural adsorbent prepared from Korean red pine (Pinus densiflora). Both equilibrium and nonequilibrium adsorption experiments were conducted on copper ion concentrations of 10mg/L, and the removals of copper ions at equilibrium were close to 95%. Adsorption of copper ions could be well described by both the Langmuir and Freundlich adsorption isotherms. The bark was treated with nitric acid to enhance efficiency of copper removal, and sorption capacity was improved by about 48% at equilibrium; mechanisms such as ion exchange and chelation may have been involved in the sorption process. A pseudo second-order kinetic model described the kinetic behavior of the copper ion adsorption onto the bark. Regeneration with nitric acid resulted in extended use of spent bark in the packed column. The horizontal flow mesh reactor allowed approximately 80% removal efficiency, demonstrating its operational flexibility and the potential for its practical use as a bark filter reactor.

• 대한임상독성학회지
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• 제19권1호
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• pp.59-63
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• 2021

Copper sulfate is widely used as a fungicide and pesticide. Acute copper sulfate poisoning is rare but potentially lethal in severe cases. Copper sulfate can lead to cellular damage of red blood cells, hepatocytes, and myocytes. Toxic effects include intravascular hemolysis, acute tubular necrosis and, rhabdomyolysis. A 76-year-old man presented with vomiting and epigastric pain. He had ingested a copper-containing fungicide (about 13.5 g of copper sulfate) while attempting suicide 2 hours prior to presentation. From day 3 at the hospital, laboratory findings suggesting intravascular hemolysis were noted with increased serum creatinine level. He was treated with a chelating agent, dimercaptosuccinic acid (succimer). His anemia and acute kidney injury gradually resolved with a 19-day regimen of succimer. Our case suggests that succimer can be used for copper sulfate poisoning when other chelating agents are not available.