Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Spectrophotometric Determination of Copper(II) Using Diamine-Dioxime Derivative

  • Published : 2003.12.20
Download PDF
⟨ Previous Next ⟩

Abstract

A simple, rapid and sensitive spectrophotometric method is herewith proposed for the determination of copper(II) by using diamine-dioxime ligand, meso-3,6,6,9-tetramethyl-4,8-diazaundecane-2,10-dione dioxime or meso-HexaMethyl Propylene Amine Oxime (meso-HMPAO). This method is based on the formation of a stable 1 : 1 red-pink complex between copper(II) and meso-HMPAO in aqueous solution. Absorption measurements were carried at 497 nm, with a molar absorptivity value of 338 L $mol^{-1}\;cm^{-1}$. Beer's law was obeyed over the concentration range of 0.5-370 ${\mu}$g $mL^{-1}$ with a Sandell's sensitivity value of 0.18 ${\mu}$g $cm^{-2}$. The proposed method has been successfully applied for determination of copper(II) in foodstuffs and pharmaceutical samples. The results obtained from this method are comparable with those obtained AAS.

Keywords

References

  1. Brewer, G. J.; Yuzbasiyan-Gurkan, V. Wilson Disease, Medicine 1992, 71, 139.
  2. Blair, D.; Diehl, H. Talanta 1961, 7, 163. https://doi.org/10.1016/0039-9140(61)80006-4
  3. Shijo, Y.; Sato, H.; Uehara, N.; Aratake, S. Analyst 1996, 121, 325. https://doi.org/10.1039/an9962100325
  4. Petit de Pena, Y.; Gallego, M.; Valcarcel, M. Anal. Chem. 1995, 67, 2524. https://doi.org/10.1021/ac00111a005
  5. Neirinckx, R. D.; Canning, L. R.; Piper, I. M.; Nowotnik, D. P. J. Nucl. Med. 1987, 28, 191.
  6. Kukushkin, V. Y.; Tudela, D.; Pombeiro, A. J. L. Coord. Chem. Rev. 1996, 156, 333. https://doi.org/10.1016/0010-8545(95)01234-6
  7. Paganelli, G.; Magnani, P.; Zito, F.; Lucignani, G.; Fazio, F. Eur. J. Nucl. Med. 1994, 21, 314. https://doi.org/10.1007/BF00947966
  8. Brown, D. G. Prog. Inorg. Chem. 1973, 18, 177. https://doi.org/10.1002/9780470166192.ch2
  9. Thomas, T. W.; Underhill, A. E. Chem. Soc. Rev. 1972, 1, 99. https://doi.org/10.1039/cs9720100099
  10. Karaboocek, S.; Nohut, S.; Dalman, O.; Guner, S. Anal. Chim. Acta 2000, 408, 163. https://doi.org/10.1016/S0003-2670(99)00825-9
  11. Nohut, S.; Karabocek, S.; Guner, S.; Gok, Y. J. Pharm. Biomed. Anal. 1999, 20, 309. https://doi.org/10.1016/S0731-7085(99)00045-X
  12. Chimpalee, N.; Chimpalee, D.; Lohwithee, S.; Nakwatchara, L.; Burns, D. T. Anal. Chim. Acta 1996, 329, 315. https://doi.org/10.1016/0003-2670(96)00141-9
  13. Dalman, O.; Karabocek, S.; Tufecki, M.; Nohut, S.; Guner, S.; Karabocek, S. J. Pharm. Biomed. Anal. 2002, 27, 183. https://doi.org/10.1016/S0731-7085(01)00519-2
  14. Pennant, P. EP patent 1985, 8,506,249.
  15. Mendham, J.; Denny, R. C.; Barnes, J. D.; Thomas, M. Vogel's Textbook of Quantitative Chemical Analysis, 6th ed.; Addison Wesly Longman Singapore (Pte) Ltd.: Singapore, 2000; p 434.
  16. Fraser, J. W.; Hedwig, G. R.; Powell, H. K. J.; Robinson, W. T. Aust. J. Chem. 1970, 25, 747.

Cited by

  1. Synthesis of 6-(2-Methoxynaphthyl)-2,3-dihydro-1,2,4-triazine-3-thione as a New Reagent for Spectrophotometric Determination of Copper vol.2014, pp.1687-8779, 2014, https://doi.org/10.1155/2014/260179
  2. Spectrophotometric determination of palladium using 2-hydraziniopyridine vol.5, pp.1, 2014, https://doi.org/10.5155/eurjchem.5.1.150-154.926
  3. A Novel Chromogenic Scheme for the Determination of Cu(II) in Water Samples vol.11, pp.6, 2003, https://doi.org/10.1080/22297928.2021.1942203