• 제목/요약/키워드: Conversion layer

검색결과 715건 처리시간 0.026초

고효율 페로브스카이트 태양전지에서의 무기 홀 전도체 CuSCN 용매 효과 (Impact of CuSCN Deposition Solvents on Highly Efficient Perovskite Solar Cells)

  • 정민수;석상일
    • 한국전기전자재료학회논문지
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    • 제33권2호
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    • pp.118-122
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    • 2020
  • Inorganic-organic hybrid perovskite solar cells have demonstrated a significant achievement by reaching a certified power conversion efficiency of 25.2% in 2019 as compared to that of 3.8% in 2009. However, organic hole conductors such as PTAA and spiro-OMeTAD are known to be expensive and unstable when they are exposed to operational conditions. In this study, the inorganic hole conductor CuSCN was used to overcome such concerns. The influence of dipropyl sulfide (DPS) and diethyl sulfide (DES) as CuSCN deposition solvents on the underlying perovskite active layer was investigated. DES solvent was observed to be advantageous in terms of CuSCN solubility and mild for the perovskite layer, thereby resulting in a power conversion efficiency of 16.9%.

수치지도 갱신을 위한 건설도면 자료의 GIS 데이터 변환에 관한 연구 (A Study on GIS Data Transform for Update the Digital Map with Construction drawings)

  • 박승용;박우진;유기윤
    • 한국측량학회:학술대회논문집
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    • 한국측량학회 2009년도 춘계학술발표회 논문집
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    • pp.11-13
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    • 2009
  • 본 연구는 최신의 수치지도 확보를 위한 갱신방안으로서 건축 및 다양한 SOC 건설공사에서 사용되고 있는 CAD 자료의 준공도면을 활용하여 수치지도를 갱신하기 위해 GIS 데이터로 변환하는 기법을 제시하였다. 변환과정은 레이어 추출, 객체변환, 좌표변환, 포맷변환으로 구성되며 CAD 데이터로부터 각 과정을 거쳐 변환된 GIS 데이터는 수치지도를 갱신할 수 있다.

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다층형 결합 선로를 이용한 반송파복원기와 위상 변위기를 갖는 6-단자 직접 변환 수신 전처리부 (Six-port direct conversion receiver front-end with carrier recovery circuit and phase shifter using multi-layer coupled line)

  • 김영완
    • 한국정보통신학회논문지
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    • 제13권11호
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    • pp.2267-2272
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    • 2009
  • 본 논문에서는 다층형 결합 선로를 이용한 6-단자 위상 상관기와 동일한 구조를 갖는 반송파 복원기 그리고 위상 변위기를 갖는 일원화된 6-단자 직접변환 수신 전처리부를 설계 제작한다. 전력 분배기와 하이브리드 결합기로 구성되는 6-단자 소자는 다층형 결합 선로 구조로 이루어지며, 수신부 위상 상관기와 반송파 복원기 그리고 위상 변위기의 기본 구조 요소로 작용한다. 다층형 결합 선로 구조로 구성되는 일원화된 수신 전처리부는 구성이 간단하고 집적화가 용이하다. 설계 제작된 다층형 결합 구조 6-단자 수신 전처리부는 일정한 반송파 신호를 재생하고, PSK 전송 신호를 복원한다.

Secondary Phase and Defects in Cu2ZnSnSe4 Solar Cells with Decreasing Absorber Layer Thickness

  • Kim, Young-Ill;Son, Dae-Ho;Lee, Jaebaek;Sung, Shi-Joon;Kang, Jin-Kyu;Kim, Dae-Hwan;Yang, Kee-Jeong
    • Current Photovoltaic Research
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    • 제9권3호
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    • pp.84-95
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    • 2021
  • The power conversion efficiency of Cu2ZnSnSe4 (CZTSe) solar cells depends on the absorber layer thickness; however, changes in the characteristics of the cells with varying absorber layer thickness are unclear. In this study, we investigated the changes in the characteristics of CZTSe solar cells for varying absorber layer thickness. Five absorber thicknesses were employed: CZTSe1 2.78 ㎛, CZTSe2 1.01 ㎛, CZTSe3 0.55 ㎛, CZTSe4 0.29 ㎛, and CZTSe5 0.15-0.23 ㎛. The efficiency of the CZTSe solar cells decreased as the absorber thickness decreased, resulting in power conversion efficiencies of 10.45% (CZTSe1), 8.67% (CZTSe2), 7.14% (CZTSe3), 3.44% (CZTSe4), and 1.54% (CZTSe5). As the thickness of the CZTSe absorber layer decreased, the electron-hole recombination at the grain boundaries and the absorber-back-contact interface increased. This caused an increase in the current loss, owing to light loss in the long-wavelength region. In addition, as the thickness of the CZTSe absorber layer decreased, more ZnSe was produced, and the resulting defects and defect clusters led to an open-circuit voltage loss.

산란계에 대한 펠렛사료의 급여효과 (Effects of Pelleting Layer Diets on Laying Hen Performance)

  • 이규호
    • 한국가금학회지
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    • 제24권1호
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    • pp.39-44
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    • 1997
  • Two experiments were carried out to determine the effects of pelleting layer diets on the laying perforrnance and nutrients utilizability, using either 50-wk-old(Experiment 1) or 80-wk-old (Experiment 2) layers. There was no effect of pelleting layer diets on hen-day egg production and average egg weight but decreased (P<0.05) feed conversion ratio(intake /egg weight) in both experiments. Although both egg specific gravity and eggshell thickness were not influenced by pelleting eggshell breaking strength was improved(P<0.05) only in Experiment 1. Utilizability of dietary fat was improved(P<0.05) by pelleting layer diets with no difference in other nutrients utilizability. There was no difference in the passage rate of mash and pelleted layer diets.

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비정질 셀레늄의 누설전류 저감을 위한 다층구조 제작 및 특성 평가 (The Multi-layer Fabrication and Characteristic Performance for Dark Current Reduction of Amorphous Selenium)

  • 박지군;강상식;석대우;이형원;남상희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.849-852
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    • 2002
  • Recently, amorphous selenium is used as x-ray conversion material for flat-panel x-ray detector. In this paper, we investigated the effect of breakdown under high voltage and leakage current in PN-type multi-layer structure based on p-type a-Se and n-type conductive thin film. Experimental results show that the multi-layer based detector reduced leakage current because n-type CeO2 conductive layer prevent from hole injection into a-Se layer from collection electrode, Also, the breakdown voltage was improved by dielectric layer between a-Se and top electrode.

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Effect of Thermal Annealing of Gravure Printed Polymer Solar Cells

  • Lee, Ji-Yeon;Kim, Jung-Woo;Kim, Hyung-Sub;Cho, Sung-Min;Chae, Hee-Yeop
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1571-1572
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    • 2009
  • Polymer solar cells were fabricated with gravure printing process and the effect of thermal annealing of gravure printed organic layer was investigated. The layer structure of polymer solar cells is glass / ITO / hole transfer layer / active layer / Al structure was fabricated. For the active layer, 1:1 ratio of poly-3-hexylthiophene (P3HT) and [6,6]-phenyl C61-butyric acid methyl ester (PCBM) mixture was applied. The P3HT/PCBM blend was gravure printed onto the substrates. The effect of thermal annealing was investigated by changing annealing time and the number of printing. Maximum 3.6% of power conversion efficiency was achieved with gravure printing of organic layer and thermal annealing in this work.

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KCN 에칭 및 CdS 후열처리가 Cu(In,Ga)(S,Se)2 광흡수층 성능에 미치는 영향 (Effect of Pre/Post-Treatment on the Performance of Cu(In,Ga)(S,Se)2 Absorber Layer Manufactured in a Two-Step Process)

  • 김아현;이경아;전찬욱
    • 신재생에너지
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    • 제17권4호
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    • pp.36-45
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    • 2021
  • To remove the Cu secondary phase remaining on the surface of a CIGSSe absorber layer manufactured by the two-step process, KCN etching was applied before depositing the CdS buffer layer. In addition, it was possible to increase the conversion efficiency by air annealing after forming the CdS buffer layer. In this study, various pre-treatment/post-treatment conditions wereapplied to the S-containing CIGSSe absorber layerbefore and after formation of the CdS buffer layer to experimentally confirm whether similareffects as those of Se-terminated CIGSe were exhibited. Contrary to expectations, it was noted that CdS air annealing had negative effects.

Fabrication of NiS Thin Films as Counter Electrodes for Dye-Sensitized Solar Cells using Atomic Layer Deposition

  • 정진원;김은택;박수용;성명모
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.276.2-276.2
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    • 2016
  • Dye-sensitized solar cells (DSCs) are promising candidates for light-to-energy conversion devices due to their low-cost, easy fabrication and relative high conversion efficiency. An important component of DSCs is counter electrode (CE) collect electrons from external circuit and reduct I3- to I-. The conventional CEs are thermally decomposed Pt on fluorine-doped tin oxide (FTO) glass substrates, which have shown excellent performance and stability. However, Pt is not suitable in terms of cost effect. In this report, we demonstrated that nickel sulfide thin films by atomic layer deposition (ALD)-using Nickel(1-dimethylamino-2-methyl-2-butanolate)2 and hydrogen sulfide at low temperatures of $90-200^{\circ}C$-could be good CEs in DSCs. Notably, ALD allows the thin films to grow with good reproducibility, precise thickness control and excellent conformality at the angstrom or monolayer level. The nickel sulfide films were characterized using X-ray photoelectron spectroscopy, scanning electron microscopy, X-ray diffraction, hall measurements and cyclic voltammetry. The ALD grown nickel sulfide thin films showed high catalytic activity for the reduction of I3- to I- in DSC. The DSCs with the ALD-grown nickel sulfide thin films as CEs showed the solar cell efficiency of 7.12% which is comparable to that of the DSC with conventional Pt coated counter electrode (7.63%).

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Properties of the Dye Sensitized Solar Cell with Localized Surface Plasmon Resonance Inducing Au Nano Thin Films

  • Noh, Yunyoung;Kim, Kwangbae;Choi, Minkyoung;Song, Ohsung
    • 한국재료학회지
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    • 제26권8호
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    • pp.417-421
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    • 2016
  • We improve the energy conversion efficiency (ECE) of a dye sensitized solar cell (DSSC) by preparing a working electrode (WE) with localized surface plasmon resonance (LSPR) by inducing Au thin films with thickness of 0.0 to 5.0 nm, deposited via sputtering. Field emission scanning electron microscopy and atomic force microscopy were used to characterize the microstructure of the blocking layer (BL) of the Au thin films. Micro-Raman measurement was employed to confirm the LSPR effect, and a solar simulator and potentiostat were used to evaluate the photovoltaic properties, including the impedance and the I-V of the DSSC of the Au thin films. The results of the microstructural analysis confirmed that nano-sized Au agglomerates were present at certain thicknesses. The photovoltaic results show that the ECE reached a value of 5.34% with a 1-nm thick-Au thin film compared to the value of 5.15 % without the Au thin film. This improvement was a result of the increase in the LSPR of the $TiO_2$ layer that resulted from the Au thin film coating. Our results imply that the ECE of a DSSC may be improved by coating with a proper thickness of Au thin film on the BL.