• Geomechanics and Engineering
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• 제18권2호
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• pp.133-140
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• 2019

Strain-rate and temperature have significant effects on the one-dimensional (1D) compression behavior of soils. This paper focuses on the bonding degradation effect of soil structure on the time and temperature dependent behavior of soft structured clay. The strain-rate and temperature dependency of preconsolidation pressure are investigated in double logarithm plane and a thermal viscoplastic model considering the combined effect of strain-rate and temperature is developed to describe the mechanical behavior of unstructured clay. By incorporating the bonding degradation, the model is extended that can be suitable for structured clay. The extended model is used to simulate CRS (Constant Rate of Strain) tests conducted on structural Berthierville clay with different strain-rates and temperatures. The comparisons between predicted and experimental results show that the extended model can reasonably describe the effect of bonding degradation on the stain-rate and temperature dependent behavior of soft structural clay under 1D condition. Although the model is proposed for 1D analysis, it can be a good base for developing a more general 3D model.

• Bulletin of the Korean Chemical Society
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• 제29권3호
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• pp.555-561
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• 2008

In air stripping of ammonia from the aqueous solution, a new removal model was presented considering the equilibrium principles for the ammonia in aqueous solution and between the aqueous and air phase. The effects of pH, temperature and airflow rate on the ammonia removal were evaluated with the model. In addition, the saturation degree of ammonia in air was defined and used to evaluate the effect of each experimental factor on the removal rate. As pH (8.9 to 11.9) or temperature (20 to 50 oC) was increased, the overall removal rate constants in all cases were appeared to be increased. Our presented model shows that the degrees of saturation were about the same (0.45) in all cases when the airflow condition remains the same. This result indicates that the effect of pH and temperature were directly taken into consideration in the model equation. As the airflow increases, the overall removal rate constants were increased in all cases as expected. However, the saturation degree was exponentially decreased with increasing the airflow rate in the air phase (or above-surface) aeration. In the subsurface aeration the saturation degree remains a constant value of 0.65 even though the airflow rate was increased. These results indicate that the degree of saturation is affected mainly by the turbulence of the aqueous solution and remains the same above a certain airflow rate.

• Bulletin of the Korean Chemical Society
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• 제27권3호
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• pp.381-385
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• 2006

The temperature dependence on the electron transfer rate constant $(k_{app})$ for hydroquinone redox center in $H_2Q(CH_2)_n$SH-SAMs (n = 1, 4, 6, 8, 10, and 12) on gold electrode was investigated to obtain reorganization energy $(\lambda)$ using Laviron’s formalism and Arrhenius plot of ln $[k_{app}/T^{1/2}]$ vs. T^{-1} based on the Marcus densityof-states model. All the symmetry factors measured for the SAMs were relatively close to unity and rarely varied to temperature change as expected. The electron tunneling constant $(\beta)$ determined from the dependence of the $k_{app}$ on the distance between the redox center and the electrode surface gives almost the same $\beta$ values which are quite insensitive to temperature change. Good linear relationship of Arrhenius plot for all $H_2Q(CH_2)_n$SH-SAMs on gold electrode was obtained in the temperature range from 273 to 328 K. The slopes n Arrhenius plot deduced that $\lambda$ of hydroquinone moiety is ca. 1.3-1.4 eV irrespectively of alkyl chain length of the electroactive SAM.

• 자원ㆍ환경경제연구
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• 제12권4호
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• pp.663-686
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• 2003

본 연구는 미국 멕시코만의 Yellowedge Grouper 어업을 사례로 생물경제학 모델을 이용하여 자원회복계획 하의 총 허용어획량(TAC) 어업관리정책 효과를 분석하였다. 생물학적 자원평가모델인 잉여생산량 모델의 추정 결과 자원이 남획상태인 것으로 나타났고, 그 결과 10년 기간 동안 TAC제도를 이용하여 목표 자원량 달성을 위한 자원회복계획이 수립되어졌다. 모델 분석 결과, 통제관리가 잘 이루어진다면 자원회복기간 이후에 목표 자원량 수준이 달성되는 것으로 분석되었다. 하지만, 목표 자원량 달성을 위해서는 자원회복기간 동안의 어획량이 크게 감소되어야 하는 것으로 나타났는데, 특히 NMFS가 권고한 연간 342톤 어획량보다 더 크게 어획량이 감소해야 하는 것으로 분석되었다. 향후 25년 동안 발생할 어업 이익은 자원회복기간 동안의 어획량 감소로 인하여 현 상태유지 하에서보다 적은 것으로 나타났다. 그리고 사회적 할인율이 낮을 때는 변동어획량 TAC제도 하에서 고정어획량 TAC재도 하에서보다 큰 어업이익이 발생하였지만, 할인율이 높아질수록 고정어획량 TAC제도 하에서 변동어획량 TAC제도 하에서보다 큰 어업이익이 발생하였다.

• 대한금속재료학회지
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• 제48권5호
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• pp.424-429
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• 2010

In the RH process, it is possible to obtain quicker processing times by enhancing the decarburization rates at a low carbon range of steel melt through Ar gas injection into the vacuum vessel. The RH decarburization reaction was simulated through a dissolved oxygen removal reaction by injecting nitrogen into a 1/8 scale RH water model system. The gas nozzles for the N$_{2}$ injection into the vacuum vessel were located at the lowest level of the vessel's outer wall. The nitrogen bubbling in the vacuum vessel resulted in an increase in the reaction rate constant, which rose in accordance with an increase in the bubbling flow rate and number of nozzles used. However, there was almost no variation in the reaction rate constant, which depended on the horizontal positions of the bubbling nozzles.

• ETRI Journal
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• 제19권4호
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• pp.344-362
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• 1997

The delay which is one of the quality of service parameters is considered to be a crucial factor for the effective usage of real-time audio and video streams in interactive multimedia collaborations. Among the various causes of the delay, we focus in this paper on the local delay concerned with the schemes which handle continuous inflow of encoded data from constant or variable bit-rate audio and video encoders. We introduce two kinds of implementation approaches, pull model and push model. While the pull model periodically pumps out the incoming data from the system buffer, the push model receives events from the device drivers. From our experiments based on Windows NT 3.51, it is shown that the push model outperforms the other for both constant and variable bit-rate streams in terms of the local delay, when the system suffers reasonable loads. We interpret this experimental data with M/G/1 multiple vacation queuing theories, and show that it is consistent with the queuing theoretic interpretations.

• Nuclear Engineering and Technology
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• 제48권5호
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• pp.1264-1272
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• 2016

The accurate estimation of leak rate through cracks is crucial in applying the leak before break (LBB) concept to pipeline design in nuclear power plants. Because of its importance, several programs were developed based on the several proposed flow models, and used in nuclear power industries. As the flow models were developed for a homogeneous pipe material, however, some difficulties were encountered in estimating leak rates for bimaterial pipes. In this paper, a flow model is proposed to estimate leak rate in bimaterial pipes based on the modified Henry-Fauske flow model. In the new flow model, different crack morphology parameters can be considered in two parts of a flow path. In addition, based on the proposed flow model, a program was developed to estimate leak rate for a crack with linearly varying cross-sectional area. Using the program, leak rates were calculated for through-thickness cracks with constant or linearly varying cross-sectional areas in a bimaterial pipe. The leak rate results were then compared and discussed in comparison with the results for a homogeneous pipe. The effects of the crack morphology parameters and the variation in cross-sectional area on the leak rate were examined and discussed.

• 한국지하수토양환경학회지:지하수토양환경
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• 제8권1호
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• pp.48-56
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• 2003

간단한 모형시추공을 이용한 전기전도도 측정실험을 실시하고 이로부터 시추공에서의 수리상수 결정에 관련된 제반기초 환경을 검증하고 실험에 의한 모델방정식을 유도하였다. 실험은 상대적으로 높은 염도를 공내수로 하고 증류수를 지하수를 사용하여, 지하수의 유입과 유출되는 유량을 일정하게 유지한 상태에서 전기전도도를 측정하는 것으로 이루어졌다. 관찰의 주 대상은 지하수의 유량, 공내수와 지하수 사이의 염도차 및 밀도차에 따른 공내에서의 전기전도도 변화 양상에 있었다. 실험결과, 공내에서의 시간에 따른 전기전도도 변화가 매우 일정한 양상으로 나타남을 보였으며, 유량과 전기전도도 변화율 사이에 양호한 상관관계가 얻어졌다. 이 결과는 향후 추가될 일반적인 수리상수와 검층수리 상수들의 비교연구로 모델방정식에 대한 검증이 이루어진다면, 희석모델에 근거한 전기전도도검층 기법이 수리 상수 결정을 위한 효과적인 방법이 될 수 있음을 보여 주었다.

• 지질공학
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• 제29권4호
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• pp.367-381
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• 2019

We investigate pore pressure conditions and reservoir compaction associated with oil and gas production using 3 different permeability models, which are all based on one-dimensional radial flow diffusion model, but differ in considering permeability evolution during production. Model 1 assumes the most simplistic constant and invariable permeability regardless of production; Model 2 considers permeability reduction associated with reservoir compaction only due to pore pressure drawdown during production; Model 3 also considers permeability reduction but due to the effects of both pore pressure drawdown and coupled pore pressure-stress process. We first derive a unified stress-permeability relation that can be used for various sandstones. We then apply this equation to calculate pore pressure and permeability changes in the reservoir due to fluid extraction using the three permeability models. All the three models yield pore pressure profiles in the form of pressure funnel with different amounts of drawdown. Model 1, assuming constant permeability, obviously predicts the least amount of drawdown with pore pressure condition highest among the three models investigated. Model 2 estimates the largest amount of drawdown and lowest pore pressure condition. Model 3 shows slightly higher pore pressure condition than Model 2 because stress-pore pressure coupling process reduces the effective stress increase due to pore pressure depletion. We compare field data of production rate with the results of the three models. While models 1 and 2 respectively overestimates and underestimates the production rate, Model 3 estimates the field data fairly well. Our result affirms that coupling process between stress and pore pressure occurs during production, and that it is important to incorporate the coupling process in the permeability modeling, especially for tight reservoir having low permeability.

• Journal of the Korean Statistical Society
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• 제7권1호
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• pp.11-16
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• 1978

Bayesian procedures are in vogue to revise the parameter estimates of the forecasting model in the light of actual time series data. In this paper, we study the Bayes forecast for demand and the risk when (a) 'noise' and (b) mean demand rate in a constant process model have moderately non-normal probability distributions.