• Journal of Industrial and Engineering Chemistry
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• v.67
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• pp.486-496
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• 2018

Bimetallic Pd@Ni nanostructure exhibited enhanced co-catalytic activity for the selective hydrogenation of benzaldehyde compare to their monometallic counterparts. Impregnation of these mono/bimetallic nanostructures on mesoporous $TiO_2$ leads to several surface modifications. The bimetallic PNT-3 ($Pd_3@Ni_1/mTiO_2$) exhibited large surface area ($212m^2g^{-1}$), and low recombination rate of the charge carriers ($e^--h^+$). The hydrogenation reaction was analyzed under controlled experiments. It was observed that under UV-light irradiations and saturated hydrogen atmosphere the bimetallic PNT-3 photocatalyst display higher rate constant $k=5.31{\times}10^{-1}h^{-1}$ owing to reduction in the barrier height which leads to efficiently transfer of electron at bimetallic/$mTiO_2$ interface.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.6
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• pp.743-752
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• 1998

Experiments were performed to characterize single-phase heat transfer behavior of submerged liquid jet with multiple nozzle normally impinging on the smooth and extended surfaces. Arrays of 9 and 36 nozzles were used, with diameters of 0.5 to 2.0mm providing nozzle area ratio (AR) from 0.05 to 0.2. The square pin fin arrays were chosen as extended surfaces and the effects of geometrical parameters such as fin height, the ratio of fin width to channel width on heat transfer enhancement were examined. Single nozzle characteristics were also evaluated for comparison. The results clearly showed that heat transfer enhancement could be realized by using multiple nozzles at the constant volume flow rate. The average Nusselt number of multiple nozzle impingement on the smooth surface was correlated by the following equation : Nu/$Pr\frac{1}{3}=0.94 Re^{0.56}N^{-0.12}AR^{0.50}$The average heat transfer coefficients of multiple nozzle impingement on the extended surfaces decreased with increasing fin height and the ratio of fin width to channel width. The effectiveness of ex-tended surfaces ranged from 1.5 to 3.5 depending on the fin height, the ratio of fin width to channel width of pin fin arrays, nozzle number and nozzle area ratio.

• Journal of Mechanical Science and Technology
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• v.17 no.9
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• pp.1358-1370
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• 2003

The effects of anode, cathode, and cooling channels for a Proton Exchange Membrane Fuel Cell (PEMFC) on flow fields have been investigated numerically. Continuous open-faced fluid flow channels formed in the surface of the bipolar plates traverse the central area of the plate surface in a plurality of passes such as a serpentine manner. The pressure distributions and velocity profiles of the hydrogen, air and water channels on bipolar plates of the PEMFC are analyzed using a two-dimensional simulation. The conservation equations of mass, momentum, and energy in the three-dimensional flow solver are modified to include electro-chemical characteristics of the fuel cell. In our three-dimensional numerical simulations, the operation of electro-chemical in Membrane Electrolyte Assembly (MEA) is assumed to be steady-state, involving multi-species. Supplied gases are consumed by chemical reaction. The distributions of oxygen and hydrogen concentration with constant humidity are calculated. The concentration of hydrogen is the highest at the center region of the active area, while the concentration of oxygen is the highest at the inlet region. The flow and thermal profiles are evaluated to determine the flow patterns of gas supplied and cooling plates for an optimal fuel cell stack design.

• Journal of the Korean Mathematical Society
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• v.47 no.5
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• pp.967-983
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• 2010

Let M be an n-dimensional complete simply connected Riemannian manifold with sectional curvature bounded above by a nonpositive constant $-{\kappa}^2$. Using the cone total curvature TC($\Gamma$) of a graph $\Gamma$ which was introduced by Gulliver and Yamada [8], we prove that the density at any point of a soap film-like surface $\Sigma$ spanning a graph $\Gamma\;\subset\;M$ is less than or equal to $\frac{1}{2\pi}\{TC(\Gamma)-{\kappa}^2Area(p{\times}\Gamma)\}$. From this density estimate we obtain the regularity theorems for soap film-like surfaces spanning graphs with small total curvature. In particular, when n = 3, this density estimate implies that if $TC(\Gamma)$ < $3.649{\pi}\;+\;{\kappa}^2\inf\limits_{p{\in}F}Area(p{\times}{\Gamma})$, then the only possible singularities of a piecewise smooth (M, 0, $\delta$)-minimizing set $\Sigma$ are the Y-singularity cone. In a manifold with sectional curvature bounded above by $b^2$ and diameter bounded by $\pi$/b, we obtain similar results for any soap film-like surfaces spanning a graph with the corresponding bound on cone total curvature.

• Journal of Powder Materials
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• v.10 no.4
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• pp.262-269
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• 2003

Nano-sized Ni-ferrite powder was fabricated by spray pyrolysis process using the waste solution resulting from shadow mask processing. The average particle size of the powder was below 100 nm. The effects of the concentration of raw material solution, the nozzle tip size and air pressure on the properties of powder were studied. As the concentration increased, the average particle size of the powder gradually increased and its specific surface area decreased, but size distribution was much wider and the fraction of the Ni-ferrite phase greatly increased as the concentration increasing. As the nozzle tip size increased from 1 mm to 2 mm, the average particle size of the powder decreased. In case of 3 mm nozzle tip size, the average particle size of the powder increased slightly. On the other hand, in case of 5 mm nozzle tip size, average particle size of the powder decreased. Size distribution of the powder was unhomogeneous, and the fraction of the Ni-ferrite phase decreased as the nozzle tip size increasing. As air pressure increased up to 1 kg/$cm^2$, the average particle size of the powder decreased slightly, on the other hand, the fraction of the Ni-ferrite phase was almost constant. In case of 3kg/$cm^2$ air pressure, average particle size of the powder and the fraction of the Ni-ferrite phase remarkably decreased, but size distribution was narrow.

• Solar Energy
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• v.20 no.1
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• pp.97-108
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• 2000

The purpose of this study is to minimize the heat transfer surface area and cold fluid exit temperature of heat exchanger which applied to the refrigeration and air-conditioning system by utilizing the thermoelectric principle. Both uniform and non-uniform current distribution methods which applied to the analysis of the TE elements that incorporates heat exchanger were investigated. The non-uniform current distribution method had the better coefficient of performance and had the lower cold fluid exit temperature of the TE cooling system than the uniform current distribution method. It was found that if a TE cooling system incorporates a heat exchanger, a non-uniform current distribution should guarantee to the lowest cold fluid exit temperature. Also, the hybrid method (combination of the uniform and non-uniform current distribution method) is investigated to achieve the best results by combining the uniform and non-uniform current distributions. The results show that it can lower the cold fluid exit temperature and reduce the heat transfer surface area for the parallel flow arrangement if we apply the constant current in some entry region and the non-uniform increasing current in the direction of the cold fluid flow afterwards.

• Laser Solutions
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• v.16 no.3
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• pp.22-26
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• 2013

Fiber laser welding was performed on SUS Materials metal bellows. The results can be summarized as follows: When we tried to change welding focus location. we get the best welding line when focus location placed 0mm. In product welding, We could make a satisfactory product in constant area by applying optimized conditions and show a table that is able to help producer easily to apply it to manufacturing. In comparison with existing TIG and plasma welding, welded bellows by fiber laser has faster processing speed, smaller thermal effect, very narrow welding area and fine surface.

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.5
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• pp.77-82
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• 2003

A parametric study was conducted on pressure drop in a catalytic converter for automobile. In this work, we proposed a new pressure drop relation which contains the various parameters needed to calculate and got a few results. In a monolith of catalyst, the flow originally turbulent flow changes to laminar flow and thus the pressure drop through the monolith is linearly proportional to the velocity. The exhaust pressure is doubly affected by the increase of mean velocity and length when we decrease the diameter of monolith while the volume keeps constant. Theoretical parameters such as $\alpha$ and $\beta$ are suggested to use as a reference value when there is no a experimental data. Especially in the part load test, these values should be modified to consider the property change of exhaust gas.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 1999.05a
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• pp.123-127
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• 1999

This paper suggests the establishment of high-accuracy and high-efficiency machining method of scroll shape workpiece by using the feed control method. The cutting paths for machining the inside and outside surfaces of the scroll-shape workpiece are calculated, and the calculation method of the cutting chip areas based on the coordinate of the base circle is shown. A feed control method is proposed for a constant cutting area and cutting force. By machining test of scroll shape workpiece, The machined accuracy of wrap, tool wear, and surface roughness are evaluated. By this method, Reduction of the machining time and large increase of the efficiency can be expected.

• Corrosion Science and Technology
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• v.9 no.1
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• pp.29-33
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• 2010

Laser machining technique, which is used focusing pulse YAG laser beam irradiation was applied to form area ratio controlled model cut-edge on pre painted Zn coated steels. A corrosion behavior of formed model cut-edge was investigated by rest potential measurement in 1 mol $m^{-3}$ NaCl with and without 0.5 kmol $m^{-3}$ $H_3BO_4$/0.05kmol$m^{-3}$ $Na_2B_4O_7$. The rest potential showed almost constant value with fluctuations. The amplitude of fluctuations increased with exposed area of steel surface. White corrosion products of zinc oxide and simonkollite was formed after the experiments at the formed model cut-edge.