• Journal of the Korean Society for Heat Treatment
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• v.31 no.4
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• pp.171-179
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• 2018

Copper powder dispersed with 4 vol.% of $Cr_2O_3$ was successfully produced by a simple milling at 210 K with a mixture of $Cu_2O$, Cu and Cr elemental powders, followed by Hot Pressing (HP) at 1123 K and 50 MPa for 2h to consolidate the milled powder. The microstructure of the HPed material was characterized by standard metallographic techniques such as XRD (X-ray Diffraction), TEM and STEM-EDS. The results of STEMEDS analysis showed that the HPed materials comprised a mixture of nanocrystalline Cu matrix and $Cr_2O_3$ dispersoid with a homogeneous bimodal size distribution. The mechanical properties of the HPed materials were characterized by micro Vickers hardness test at room temperature. The thermodynamic considerations on the heat of formation, the incubation time to ignite MSR (Mechanically induced Self-sustaining Reaction), and the adiabatic temperature for the heat of displacement reaction between the oxide-metal are made for the delayed formation of $Cr_2O_3$ dispersoid in terms of MSR suppression. The results of TEM observation and hardness test indicated that the relatively large dispersoids in the HPed materials are attributed to the significant coarsening for the high temperature consolidation; this leads to the low Vickers hardness value. Based on the thermodynamic calculation for the operating processes with a limited number of parameters, the formation kinetics and coarsening of the $Cr_2O_3$ dispersoid are discussed.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2017.10a
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• pp.74-74
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• 2017

Electrorefining is a key step in pyroprocessing. The electrorefining process is generally composed of two recovery steps - the deposit of uranium onto a solid cathode and the recovery of the remaining uranium and TRU elements simultaneously by a liquid cadmium cathode. Uranium deposit recovered from the solid cathode is a dendritic powder. It is necessary to separate the adhered salt from the deposits prior to the consolidation of uranium deposit. The adhered salt is composed of lithium, potassium, uranium, and rare earth chlorides. Distillation process was employed for the cathode processing. One of the operation methods is distillation of the salt at low temperature ($900^{\circ}C$), and then melting of the deposit at high temperature to avoid a backward reaction. For the development of the salt distiller, the distillation behavior of the low vapor pressure chlorides should be studied. Rare earth chlorides in the adhered salt of uranium deposits have relatively low vapor pressures compared to the process salt (LiCl-KCl). In this study, the evaporation rates of the lanthanum and neodymium chlorides were measured for the salt separation from electrorefiner uranium deposits in the temperature range of $825{\sim}910^{\circ}C$. The evaporation rate of both chlorides increased with an increasing templerature. The evaporation rate of lanthanum chloride varied from 0.12 to $1.68g/cm^2/h$. Neodymium chloride was more volatile than lanthanum chloride. The evaporation rate of neodymium chloride varied from 0.20 to $4.55g/cm^2/h$. The evaporation rate of both chlorides are more than $1g/cm^2/h$ at $900^{\circ}C$. Even though the evaporation rates of both chlorides were less than that of the process salt, the contents of the lanthanide chlorides were small in the adhered salt. Therefore it can be concluded that $900^{\circ}C$ is suitable for the operation temperature of the salt distiller.

• Korean Journal of Metals and Materials
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• v.46 no.4
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• pp.223-226
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• 2008

The comparison of sintering behavior and mechanical properties of ultra-fine WC-10wt.%Co and WC-10wt.%Fe hard materials produced by high-frequency induction heated sintering (HFIHS) was accomplished using ultra fine powder of WC and binders(Co, Fe). The advantage of this process allows very quick densification to near theoretical density and prohibition of grain growth in nano-structured materials. Highly dense WC-10Co and WC-10Fe with a relative density of up to 99% could be obtained with simultaneous application of 60 MPa pressure and induced current within 1 minute without significant change in grain size. The hardness and fracture toughness of the dense WC-10Co and WC-10Fe composites produced by HFIHS were investigated.

• Journal of the Korean Geotechnical Society
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• v.24 no.8
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• pp.149-160
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• 2008

Offshore pile foundations are prone to lateral soil pressures resulting from embankment construction for the reclamation on deepwater soft clay. Since the 1990s, offshore reclamation has actively progressed in Korea, connecting with the development of Songdo newtown, Incheon newport, and Busan newport representatively. Special attention has been given to lateral soil-structure interaction problems related to passively-loaded offshore pile foundations. Based on a plane strain large deformation finite element (LDFE) approach, this paper presents the results of investigation into undrained (short-term) and drained (long-term) behavior of passively-loaded offshore pile foundations. This study examines the effects of major factors, such as soil profile, pile head boundary condition, magnitude of embankment load, and average degree of consolidation. The results allowed quantification of differences in the magnitude of lateral soil pressure acting on the piles between undrained and drained phases.

• Journal of the Korean Geotechnical Society
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• v.22 no.12
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• pp.89-98
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• 2006

In this paper the behavior of saturated sand deposits where liquefaction occurred before is studied for successive earthquakes. The relationship between past pore pressure generation and reliquefaction resistance is examined by using cyclic direct simple shear tests. If the soil sample in direct simple shear produced nearly 90% of excess pore pressure during first time loading, its liquefaction resistance increased during following cyclic loading after consolidation. However, a fully liquefied soil during first time loading has a densely packed condition but shows less liquefaction resistance for the following cyclic loading. UBCSAND model that can account for pore pressure change and stiffness loss of soil during shaking is used to analyze the centrifuge test simulating reliquefaction. The pore pressure rise during first time cyclic loading controls liquefaction resistance. The measurements from reliquefaction centrifuge test are compared with numerical predictions. By considering frequent earthquakes having occurred at the Southern Korea near Japan, such effective stress approach is necessary for reliquefaction study.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.6C
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• pp.277-285
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• 2009

A series of undrained cyclic triaxial tests were carried out to investigate the cyclic shear stress strength characteristics of sands with respect to the silt content. Silty sand was collected around the basin of Nak-Dong River and remolded in laboratory with the range of silt content 0~50% in sand located. As results, with the change of silt content cyclic shear stress ratio (CSR) at N=10 showed the maximum value at 5% and the minimum at 20% in all relative density. The development tendency of the pore water pressure analyzed by the relationship cyclic ratio and pore water pressure ratio is unrelated the change of CSR varying silt content. Comparing the results of the void ratio and skeleton void ratio after consolidation, CSR varying silt content was much affected by skeleton void ratio which is known to affect shear behavior of silty sand.

• Geomechanics and Engineering
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• v.36 no.3
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• pp.259-276
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• 2024

The undrained shear strength is widely acknowledged as a fundamental mechanical property of soil and is considered a critical engineering parameter. In recent years, researchers have employed various methodologies to evaluate the shear strength of soil under undrained conditions. These methods encompass both numerical analyses and empirical techniques, such as the cone penetration test (CPT), to gain insights into the properties and behavior of soil. However, several of these methods rely on correlation assumptions, which can lead to inconsistent accuracy and precision. The study involved the development of innovative methods using extreme gradient boosting (XGB) to predict the pile set-up component "A" based on two distinct data sets. The first data set includes average modified cone point bearing capacity (q_t), average wall friction (f_s), and effective vertical stress (σ_vo), while the second data set comprises plasticity index (PI), soil undrained shear cohesion (S_u), and the over consolidation ratio (OCR). These data sets were utilized to develop XGBoost-based methods for predicting the pile set-up component "A". To optimize the internal hyperparameters of the XGBoost model, four optimization algorithms were employed: Particle Swarm Optimization (PSO), Social Spider Optimization (SSO), Arithmetic Optimization Algorithm (AOA), and Sine Cosine Optimization Algorithm (SCOA). The results from the first data set indicate that the XGBoost model optimized using the Arithmetic Optimization Algorithm (XGB - AOA) achieved the highest accuracy, with R2 values of 0.9962 for the training part and 0.9807 for the testing part. The performance of the developed models was further evaluated using the RMSE, MAE, and VAF indices. The results revealed that the XGBoost model optimized using XGBoost - AOA outperformed other models in terms of accuracy, with RMSE, MAE, and VAF values of 0.0078, 0.0015, and 99.6189 for the training part and 0.0141, 0.0112, and 98.0394 for the testing part, respectively. These findings suggest that XGBoost - AOA is the most accurate model for predicting the pile set-up component.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.36 no.4
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• pp.705-713
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• 2016

For the soft ground construction, the factors not considered in the design stage occurs in the construction stage so that they cause the increase of the construction cost due to the structural stability and the design change. The subject of the study is the construction section of the industrial complex access road made in the Ochang region of Chungcheongbuk-do. The study is concerned with selecting the soft ground handling method such as the replacement method using rock debris and the surcharge reflecting the service load as the soft ground handling measure and analyzing the effect of reducing the construction cost with the stability of structures and the reduction of the construction period. The soft ground in the study section consists of sandy and cohesive soil and is 2.4m to 5.5m deep. It is distributed unevenly between the 1.5m to 5.9m stratums under the ground surface. Settlement is not serious, but the future uneven settlement and difference are expected so that the future settlement behavior is estimated by analyzing the site measurement results after the soft ground treatment. Moreover, in consideration of the regional characteristics and economic efficiency, soil with good quality is replaced with rock debris as the replacement material so that 29% of the construction cost is reduced due to the increase of stability and the reduction of duration. If the estimation of the dispersion of the pore water pressure within the dam body and the change of the underground water level and the relation of the actually measured soft ground with consolidation is studied further on the basis of the study, it is expected that the behavior of the soft ground will be correctly estimated in various site conditions.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.1C
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• pp.39-51
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• 2011

A large number of small particles may surround large gravels which are non-contact and dispersed within the ground. The strength of such soil may be influenced by the mechanical properties of a few coarse gravels. A specimen or gravel size can impact the shear characteristics of sand with dispersed gravels. In this study, the size of gravel and specimen varies and its effect on shear characteristics of a granular soil was evaluated. Five sizes of gravels with 7, 12, 15, 18, and 22 mm were used repeatedly and inserted in the middle of each compacted layer. A specimen consists of five or ten equal layers depending on gravel size, which is 5 cm or 10 cm in diameter and 10 cm or 20 cm in height. An embedded gravel ratio by weight is 3% and constant for all cases with gravel. After consolidation, a series of undrained triaxial compression tests under three confining pressures was performed on sand with dispersed gravels. The maximum deviator stress of a specimen with 10 cm in diameter was at average 30% higher than that with 5 cm in diameter and increased up to 90% for a specimen with gravel. When a gravel size of 7 and 12 mm used, the maximum deviator stress of a specimen with 10 cm in diameter was higher than that of one without gravel, whereas the maximum deviator stress of a specimen with 5 cm was higher or lower than that without gravel. The gravel size and specimen diameter influenced the undrained behavior of sand. The maximum deviator stress of a specimen with gravel either increased or decreased compared to that without gravel, depending on the ratio of gravel size to specimen diameter, 1/5.

• Journal of Powder Materials
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• v.13 no.3 s.56
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• pp.178-186
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• 2006

The effect of use of $H_2O$ as PCA(process control agent) to prevent the carbon contamination during mechanical alloying process and the precipitation behavior in Ni-20Cr-20Fe-5Nb bulk alloy after aging were investigated. NbC and $Cr_2O_3$ were formed during mechanical alloying and consolidation processes in the Ni-20Cr-20Fe-5Nb alloy in which methanol($CH_3OH$) was added as PCA. Formation of NbC in this alloy decreased the amount of Nb dissolved in the Ni matrix. The use of $H_2O$ as PCA in Ni-20Cr-20Fe-5Nb alloy prevented the formation of NbC and increased the hardness. The increase of hardness in this alloy was attributed to the increased amount of Nb dissolved in the Ni matrix. After aging treatment for 20 hours at $600^{\circ}C\;and\;720^{\circ}C$ of Ni-20Cr-20Fe-5Nb bulk alloy in which $H_2O$ added as PCA, ${\gamma}"$$(Ni_3Nb,\;tetragonal)\;and\;{\delta}\;(Ni_3Nb,\;orthorhombic)$ precipitates were formed, respectively. The precipitation temperatures of ${\gamma}"$ and ${\delta}$ in this bulk alloy were lower than those in commercial IN 718 alloy. It seemed that the lower precipitation temperatures for ${\gamma}"$ and ${\delta}$ in this bulk alloy than in commercial IN 718 alloy were due to severe plastic deformation during mechanical alloying.