• Journal of Conservation Science
• /
• v.23
• /
• pp.103-118
• /
• 2008

Hobun(Oyster shell W.) is a traditional material used as extender and white pigment from ancient times. The production method of it, however, has been discontinued. We have studied the traditional production method of Hobun through calcination of oyster shell, which is one of the traditional ways for preparing Hobun. Our work has the important meaning in that we can reproduce the manufacturing method of the discontinued traditional material and also it provides a solid background knowledge to stabilize the production and supply of Hobun for the cultural asset repairing materials. The result can be summarized as followings: The production processes of Hobun by calcination method are divided into 4 steps - calcination ${\rightarrow}$ slaking(pulverization) ${\rightarrow}$ separating fine powder by submergence in water ${\rightarrow}$ drying. In calcination step, the temperature is required to exceed $700^{\circ}$ to get pure white color of Hobun, since organic materials in the shell cause the final powder to be less white below $600^{\circ}$. And the calcination methods produce significant amount of calcium hydroxide, which is incongruent for pigment materials without additional treatments. The experimental study also demonstrated that the additional treatment process introduced in traditional paintings can be a probable process since the calcium of potassium hydroxide is observed to be promoted by this treatment. It is also concluded that, the calcination method of Hobun is appropriate for a small amount and high quality production.

• Journal of Conservation Science
• /
• v.27 no.2
• /
• pp.223-229
• /
• 2011

Buddha painting cultural properties couldn't avoid the change of colors and the exfoliation phenomenon by the characteristic of material and environmental factors. Especially, because in the beginning of the fine crack and the decoloration phenomenon on the surface of pigment would be significantly decrease stability of the whole object, it is necessary to take particular measure. Therefore, this is a study on conservation of Avalokitesvara in Potalaka in Hyeondeungsa in Gapyeong. It treated damaged parts of the object, carried out backing papers and matching colors. And then, it examined scientific analysis of pigments. Also, it performed nondestructive testing like XRF, FT-IR, and image microscope to investigate the quality of the material of hanji using the object and the component and characteristic of pigments. As a result, FT-IR spectrum matching Korean traditional paper(hanji) was detected in hanji of Avalokitesvara in Potalaka in Hyeondeungsa. The black pigment making a thin layer over the white pigment would estimate carbon compounds of unconfirmed ink stick or soot as XRF and FT-IR. Also, the white pigment was lead white($PbCO_3{\cdot}Pb(OH)_2$) involving Pb(Lead) and a carbonate. It was observed that the crystal of blue pigment had the different sizes of the particles from the microscope. In the case of this blue pigment, it showed cobalt blue and lead white was mixed when it used because both Cu and Pb were highly detected in XRF data.

• Journal of Conservation Science
• /
• v.30 no.4
• /
• pp.427-438
• /
• 2014

To measure the depth and extension on the surface cracks of the stone monument, ultrasonic pulse velocity targeted at the Mulgyeseowon Stele in Changnyeong was used in this research. Additionally, to establish a long-term countermeasure of management and conservation for this stele, we have investigated the material properties and damage on it and have conducted a precise diagnosis by a variety of non-destructive techniques. Our research has revealed that stones of the stele are composed mainly of three rock types according to the parts of it, alkali-feldspar granite, gabbro and diorite. The result of the deterioration evaluation has occurred that cracks, which are observed from every direction in the body of the stele, are the significant factors to reduce structural stability. The ultrasonic velocity for an evaluation on the properties of the stele has revealed that the speed was high in the order of body, pedestal and crown. Furthermore, to understand the present condition and occurrences of the cracks which have measured in many different forms on the stele quantitatively, we have estimated from 0.6 to 24.1cm deep of the cracks by To-Tc method using ultrasonic velocity.

• Journal of the Korean Wood Science and Technology
• /
• v.46 no.5
• /
• pp.610-621
• /
• 2018

In conservation treatment lacquer has been used variously as a restoration material. However, dealing with Lacquer is very difficult as it dried in high humidity that can be harmful to the base materials. Also being natural varnish, dried lacquer layer is very different from the drying condition and the quality of the lacquer. These make difficult to predict the result of drying lacquer. In this study, using the humidity control machine, firstly, the main contents of the two different type of lacquer was experimented. And these lacquers was cured in various conditions. The duration time was checked until totally hardened. After that, obtained lacquer layers was analyzed to understand optical properties. Therefore, this study made a result about the relationship between characteristics of lacquer layer and the hardening condition. As a result, duration time of the Korean lacquer drying which has average 13.4% more urushiol than the Chinese lacquer is recorded a twice or triple decrease over it of the Chinese one. And, in all types of lacquer, the higher humidity makes the faster a pace of lacquer dried. In same lacquer, the shorter the duration time of drying lacquer is much darker and glossier. However, gloss deteriorated in saturated humidity. In humidity lower than RH 70%, lacquer is not hardened in 336 hours. When the layer totally cured through long period more than 30 days, the drying lacquer is appeared high brightness and almost transparent. Thus, in lower than RH 70%, it is hard to obtain durable layer.

• Journal of Conservation Science
• /
• v.25 no.3
• /
• pp.255-271
• /
• 2009

This study was examined interpretation of making techniques and provenance interpretation of raw materials for the potteries from the Nongseori site in Giheung based on archaeometric characteristics. The potteries are classified into three groups according to the archaeological age. The texture of Neolithic age potteries is sandy soil added a lot of temper such as talc and mica, and Bronze age potteries contain sandy materials which occur naturally include quartz, orthoclase, plagioclase and mica. On the other hand, Proto-three Kingdom Age potteries made of silty soil that sift out coarse minerals from the clay. But all pottery and soil samples in the study were very similar patterns with geochemical evolution trend. This result is sufficient evidence that all pottery samples were produced using the same raw materials from the host rocks around of the site area. The Neolithic age potteries had loose texture and fired probably about 700 to $760^{\circ}C$. The Bronze age potteries had experienced firing about 850 to $900^{\circ}C$. And Proto-three Kingdom Age potteries had compact textured and fired from 900 to $1,050^{\circ}C$. The making techniques of potteries are not represented discontinuation characteristics about the periodic time sequences, and are suggested that revealed a transitional change patterns for production techniques.

• Journal of Conservation Science
• /
• v.25 no.3
• /
• pp.299-316
• /
• 2009

The Goryeo roof tiles from the Oegol site in Tangjeong, Asan are classified into three groups in color such as gray, red yellow and gray-yellow groups, respectively. While each group of tiles shows characteristic specific gravity, absorption ratio, LOI and vitrification degree, mineral content and distribution, and chemical composition are generally homogeneous among all groups of roof tiles. Also, all roof tiles and soils from the site show similar geochemical behavior of elements and clay-mineralization degree. This indicates that the soil from the site is probable to be a raw material of the roof tiles. Firing temperature of the roof tiles is estimated as 950 to $1,050^{\circ}C$ for the gray group, 800 to $900^{\circ}C$ for the red yellow group, and 900 to $950^{\circ}C$ for the gray-yellow group. In conclusion, roof tiles from the Oegol site is interpreted to be made of local clay without additive minerals, applying various firing conditions and standardized purifying process of raw clay materials.

• Journal of Conservation Science
• /
• v.27 no.1
• /
• pp.31-40
• /
• 2011

Copper-red (Dongwha, Jinsa) is Korean traditional inorganic pigment used for red-coloring on the porcelain surface during Goryeo and Joseon Periods. Trace amounts of copper-red porcelains are handed down because of the technical difficulty of making and coloring of the pigment. It is known that copper ore sources were extensively distributed in Korea according to old literatures and some of them are still producing copper ore at this present. Main types of copper-bearing mineral in Korea are chalcopyrite ($CuFeS_2$) and malachite ($Cu_2CO_3(OH)_2$), and they are easily collected from the ground surface. This means Korea had geographical and economic geological advantages for supplying raw material of the pigment. These two minerals showed good red-coloring in color test for porcelain pigment. As a coloring element, copper showed micro size less than $5{\mu}m$ in diameter in glaze matrix. The dispersion of copper particle is the most decisive factor for red chromaticity of copper-red porcelain, as well as copper content of the pigment.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.07a
• /
• pp.178-181
• /
• 2001

The organic light-emitting devices (OLEDs) based on fluorescence have low efficiencies due to the requirement of spin-symmetry conservation. By using the phosphorescent material, the internal quantum efficiency can reach 100 %, compared to 25 % in the case of the fluorescent material. Thus, the phosphorescent OLEDs have recently been extensively studied and showed higher internal quantum efficiencies then the conventional OLEDs. In this study, we investigated the characteristics of the phosphorescent OLEDs, with the green emitting phosphor, Ir(ppy)$_3$ (tris(2-phenylpyridine)iridium). The devices with a structure of ITO/TPD/Ir(PPy)$_3$ doped in the host material/BCP/Alq$_3$/Li:Al/Al were fabricated, and its electrical and optical characteristics were studied. By changing the doping concentration of Ir(PPy)$_3$ and the host materials, we fabricated several devices and investigated the device characteristics.

• Korean Journal of Heritage: History & Science
• /
• v.55 no.4
• /
• pp.180-193
• /
• 2022

The East Nine Royal Tombs is a representative place in the Royal Tombs of Joseon (a World Heritage Site). It consists of 1,289 stone artifacts including 979 related stone structures, 310 stone statues, and objects. Most of the stone structures in the East Nine Royal Tombs are composed of biotite granite, but some tombs are composed of light red granite. As a result of magnetic susceptibility measurement, the average data from Geonwolleung to Mongneung, excluding Hyeolleung, were similar, so it is estimated that stones were obtained from the same quarry. In the case of Sungneung, Sureung, and Gyeongneung, the range of susceptibility measurement is widely distributed. It assumed that the newly produced stones were mixed in the moving and construction process. Also, stones might be gathered from different quarries. As a result of a conservation status investigation, both the mound member and the ridge stone had the highest damage rate due to peeling and granular decomposition according to surface weathering. In the case of surface discoloration, yellowing and soils were found in the burial mound members. Yellowing, blackening, and soil were identified in the ridge stone structures. Bio-degradation is the major factor of deterioration of the East Nine Royal Tombs and the conservation status of the tombs were detected as grades 4 to 5. It seems that it is easy for the environment of the royal tombs to form soil for the microorganisms and fine conditions for continuous moisture. In the case of structures, they are in relatively good condition. As a result of a comprehensive damage rating for each tomb, the overall condition is good, but the Geonwolleung Royal Tomb and Hyeolleung Tomb, which were created in the early period, had relatively high weathering ratings. Stone objects in East Nine Royal Tombs have lost many pieces and gateway members due to surface deterioration. Also, secondary damage is ongoing. Each damage factor of the stone artifacts of the East Nine Royal Tombs combines to cause various and continuous damages. Therefore, it is necessary to establish regular conservation status data of the stone artifacts for efficient management after processing as well as conservation treatment of the royal tombs, and specific management manuals and systems. This study investigated the conservation status of stone structures in the East Nine Royal Tombs, a World Heritage Site, and systematically classified them to provide priority and necessity for conservation processing. We look forward to establishing a plan for the conservation and management of the East Nine Royal Tombs with this database in the future.

• Journal of Conservation Science
• /
• v.24
• /
• pp.1-11
• /
• 2008

The Unhyungung Water Container in the possession of the Seoul Museum of History in Korea is consisted of a calcareous marble developed laminated bedding and numerous argillaceous veinlets. This monument should need to conservation treatment because of black discoloration and seriously numerous cracks. Vertical and horizontal cracks in the monument are developed following stratification and argillaceous veinlets that are relatively low coherence between the rock materials. We have proved that the material inducing discoloration on the surface is carbon which is formed by deposited organic matters. As the result of the ultrasonic measurements, although highly surface weathering degree, the physical properties of the Unhyungung Water Container is confirmed slightly weathered state. The depths of cracks in the monument are calculated at maximum 60mm in some cracks completely penetrating into the wall and at minimum 9mm in the other crack. The cracks, developed following veinlet, are revealed that there penetrate from an outer wall to an inside wall for the monument. And most depths of cracks, developed following stratification, are calculated 20 to 30mm. This result will offer a significant data for conservation of the Unhyungung Water Container.