• 제목/요약/키워드: Concentration Gradient

검색결과 583건 처리시간 0.023초

Electrokinetic 정화 처리 중 토체내의 특성변화를 고려한 수치해석 프로그램 개발 (Development of Numerical Analysis Program Considering Variation of Soil Properties During Electrokinetic Remediation)

  • 한상재;김치열;김수삼
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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    • pp.202-205
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    • 2001
  • In this study, the electrokinetic remediation test for the kaolin contaminated by lead was performed and voltage, zeta potential, pH distribution, current, contamination transport in soil sample were studied and finite differential numerical analysis program(HERP) for a contaminated soil were compared with those of test. From the result of HERP, in the anode it was represented that the rest concentration was decreased with the voltage. Hence, if treatment time was continued for a long in the constant voltage, comparing with sample having no change in the rest concentration, it is considered that the voltage gradient is the control factor of the rest concentration.

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CIP 방법을 이용한 건물 주위의 오염물 확산에 대한 수치해석 (Numerical Simulations of Using CIP Method for Dispersion of Pollutants around a Building)

  • 홍보영;박찬국
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집B
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    • pp.723-728
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    • 2001
  • Wind flow perturbations, recirculations and turbulence generated by buildings often dominate air pollutant distributions around buildings. This paper describes dispersion of contaminants in the vicinity of a building by solving the concentration equation based on previously simulated wind flow field. Turbulence closure is achieved by using the standard k-e two-equation model. The paper shows application of the CIP method for solving a species concentration equation of contaminant gas around a rectangular building for two different sources under conditions of neutral atmospheric stratification. Results have been compared to the experimental data and the previous numerical results by hybrid scheme. The computational results of concentration profiles by the CIP method agree well with experimental data.

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Lipophilic Acyclic Polyether Dicarboxylic Acid 에 의한 액체막을 통한 금속이온의 이동 (Transport of Metal Ions Across Bulk Liquid Membrane by Lipophilic Acyclic Polyether Dicarboxylic Acids)

  • 조문환;조성호;이인종
    • 대한화학회지
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    • 제38권2호
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    • pp.129-135
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    • 1994
  • Acyclic polyether dicarboxylic acid는 액체막계에서 금속이온의 운반체로 연구되었다. 수소이온이 이온화될 수 있는 리간드는 금속이온의 이동에 수소이온이 반대방향으로 이동된다. 이와 같은 리간드는 pH를 변화시키면 효과적으로 금속이온을 분리할 수 있고 농축시킬 수도 있다. 금속이온의 이동은 source phase의 염기의 농도와 receiving phase의 산의 농도를 증가시키면 증가된다. Acyclic polyether dicarboxylic acids를 운반체로 사용한 경쟁이동반응에서 칼슘이온을 선택적으로 분리할 가능성이 있다.

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계면활성제가 포함된 삼성분계 해석을 통한 마란고니 대류 발생 연구 (Onset of Marangoni Convection in a Ternary Mixture with Surfactant)

  • 김제익;강용태;최창균
    • 설비공학논문집
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    • 제15권11호
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    • pp.964-969
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    • 2003
  • The objective of this study is to investigate the effect of surfactant on the onset of Marangoni convection adapting a non-linear surface equation of state. The surface tension gradient with respect to the absorbate concentration, ${\gamma}$, is linearly related to the surface concentration of a surfactant with a coeffcient $x_{A}$. The numerical results show that the role of the initial surfactant concentration to Marangoni instability changes from the stabilizer to the destabilizer depending on the change of the sign of $x_{A}$ from negative to positive. It is concluded that for $x_{A}$>0 there is a critical modified Marangoni number of surfactant $M_{Ac}$ $^{*}$ above which liquid layer is always unstable against long wave disturbances.rbances.

Quantitative Analysis of Tooth Mineral Content by High Resolution Micro-computed Tomography

  • Song, Dae-Sung;Kim, Jung-Woo;Hwang, Hee-Su;Oh, Sin-Hye;Song, Ju Han;Kim, Il-Shin;Hwang, Yun-Chan;Koh, Jeong-Tae
    • International Journal of Oral Biology
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    • 제42권4호
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    • pp.155-161
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    • 2017
  • Teeth and bones are highly mineralized tissues containing inorganic minerals such as calcium phosphate, and a growing number of evidences show that their mineral content is associated with many diseases. Although the quantification of mineral contents by micro-computed tomography(micro- CT) has been used in diagnosis and evaluation for treating bone diseases, its application for teeth diseases has not been well established. In this study, we attempted to estimate a usefulness of a high-resolution micro-CT in analysis of human teeth. The teeth were scanned by using the Skyscan 1172 micro-CT. In order to measure tooth mineral content, beam hardening effect of the machine was corrected with a radiopaque iodine-containing substance, iodoacetamide. Under the maximum resolution of $6.6{\mu}m$, X-ray densities in teeth and hydroxyapatite standards were obtained with Hounsfield unit (HU), and they were then converted to an absolute mineral concentration by a CT Analyzer software. In enamel layer of cusp area, the mean mineral concentration was about $2.14mg/mm^3$ and there was a constant mineral concentration gradient from the enamel surface to the dentinoenamel junction. In the dentin of middle 1/3 of tooth, the mean mineral concentration was approximately $1.27mg/mm^3$ and there was a constant mineral concentration gradient from the outer of root to the pulp side, ranging from 1.3 to $1.06mg/mm^3$. In decay region of dentin, the mineral content was gradually decreased from the intact inner side to the decayed surface. These results suggest that high-resolution micro-CT can be as a useful tool for non-invasive measurement of mineral concentration in teeth.

자기공명 Tailored-RF 경사자계반향영상법을 이용한 고양이 뇌에서의 First-Pass관찰 (First-Pass Observation using Tailored-RF Gradient Echo (TRFGE) MR Imaging in Cat Brain)

  • 문치웅;노용만
    • 대한의용생체공학회:의공학회지
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    • 제16권2호
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    • pp.209-216
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    • 1995
  • Recently, a new tailored RF gradient echo (TRFGE) sequence was reported. This technique not only enhances the magnetic susceptibility effect but also allows us to measure local changes in brain oxygenation. In this study, a phantom and cat brain experiments were performed on a 4.7 Tesla BIQSPEC (BRUKER) instrument with a 26 cm gradient system. We have demonstrated that the signal intensity (SI) of the TRFGE sequence varies according to the concentration of susceptibility contrast agent. Three capillary tubes with different concentrations of Gd-DTPA (0.01, 0.05, 0.1 mMOI/l) were placed at the middle of a cylindrical water phantom. Using both TRFGE and conventional gradient echo (CGE) sequences, phantom images of the slices which contain all three tubes were obtained. For the animal experiment, cats were anesthetized and ventilated using halotane (0.5%) and a $N_2O/ O_2$ mixture (2:1), and blood pressure and heart rate were monitored and kept normal. For the observation of tue first pass of Gd- DTPA, imaging was started at t = 0. At t = 8 ~ 12s, 0.2 mMol/Kg Gd-DTPA was manually injected in the femoral vein. The imaging parameters were TRITE = 25/10 msec, flip angle = $30^{\circ}$, FOV = 10cm, image matrix size = $128{\times}128$ with 64 phase encodings and the image data acquisition window was 10 msec. SI-time curves were then obtained from a series of 30 images which were collected at 2 sec intervals using both CGE and TRFGE pulse sequences before, during, and following the contrast injection.

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Flux-gradient similarity theory 적용에 따른 태화산 산림지표 토양NO플럭스 분석 (Practical Use of Flux Gradient Similarity Theory for Forest Soil NO Flux at Mt. Taewha)

  • 김득수
    • 한국대기환경학회지
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    • 제30권6호
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    • pp.531-537
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    • 2014
  • Terrestrial vegetation has been known as a main source of biogenic volatile organic compounds (BVOCs). Isoprene and monoterpene among the BVOCs are most abundant species emitted by forests, and have a significant impact on atmospheric chemistry. Abundancy of these species could lead to an increase or decrease in the production of natural tropospheric ozone in forests, depending on the nitric oxide (NO) concentration. Soil is the most significant source of natural NO. Understanding of NO emission from forest soil could be critical in evaluation of air quality in the forest area. Flux-gradient similarity theory (FGST) was applied for practical use to estimate forest soil NO emission at Mt. Taewha where is available micro-meteorological data near surface monitoring from flux tower. NO fluxes calculated by FGST were compared to flux results by flow-through dynamic chamber (FDC) measurement. Surface NO emission trends were shown between two different techniques, however their magnitudes were found to be different. NO emissions measured from FDC technique were relatively higher than those from theoretical results. Daily mean NO emissions resulted from FGST during Aug. 13, 14 and 15 were $0.28{\pm}8.45$, $2.17{\pm}15.55$, and $-3.18{\pm}13.65{\mu}gm^{-2}hr^{-1}$, respectively, while results from FDC were $2.26{\pm}1.44$, $5.11{\pm}3.85$, and $2.23{\pm}6.45{\mu}gm^{-2}hr^{-1}$. Trends of daily means were shown in similar pattern, which NO emissions were increasing during late afternoon ($r^2$=0.04). These emission trends could be because soil temperature and moisture influence importantly soil microbiology.

Remediation of Electroplating Contaminated Soil by a Field Scale Electrokinetic System with Stainless Steel Electrodes

  • Yuan, Ching;Tsai, Chia-Ren;Hung, Chung-Hsuang
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제19권5호
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    • pp.26-34
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    • 2014
  • A $1.5m(L){\times}1.0m(W){\times}1.1m(H)$ polypropylene (PP) field scale electroniketic system coupled with stainless steel electrodes was designed to examined metal removal performance applied 0.2-0.35 V/cm potential gradient and 0.05-0.5M lactic acid for 20 day. Electroosmosis permeabilities of $2.2{\times}10^{-5}cm^2/V-s$ to $4.8{\times}10^{-5}cm^2/V-s$ were observed and it increased with the potential gradient increased. The reservoir pH controlled at $7.0{\pm}1.0$ has been effectively diminished the clogging of most metal oxides. The best removal efficiency of Zn, Pb, and Ni was 78.4%, 84.3%, and 40.1%, respectively, in the field scale EK system applied 0.35 V/cm and 0.05M lactic acid for 20 days. Increasing potential gradient would more effectively enhance metal removal than increasing concentration of processing fluid. The reservoir and soil temperatures were majorly related to potential gradient and power consumptio. A $4-16^{\circ}C$ above room temperature was observed in the investigated system. It was found that the temperature increase in soil transported the pore water and metals from bottom to the topsoil. This vertical transport phenomenon is critical for the electrokinetic process to remediate in-situ deep pollution.

Effects of Elevated $CO_2$ and Temperature on Seedling Emergence of Herbs in a Japanese Temperate Grassland

  • Lee, Jae-Seok;Takehisa Oikawa;Shigeru Mariko;Lee, Ho-Joon
    • The Korean Journal of Ecology
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    • 제23권6호
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    • pp.423-429
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    • 2000
  • To understand the effects of elevated $CO_2$ concentration and temperature on seedling emergence of seven herbaceous species, the seedling emergence was monitored between November 1997 and May 1998 using a temperature gradient chamber and a $CO_2$-temperature gradient chamber. Experiment was conducted under current ambient condition (Control plot), 2$^{\circ}C$-warmed condition with ambient $CO_2$ (T2 Plot), 4$^{\circ}C$-warmed condition with ambient $CO_2$ (T4 plot). and 4$^{\circ}C$-warmed condition with 1.8 fold of ambient $CO_2$ (CT4 plot). Species tested in this study were Digitaria adscendens, Echinochloa crus-galli, Panicum bisulcatum, Setaria viridis. Oenothera biennis, Andropogon virginicus, and Imperata cylindrica. Each species often dominates in the herbaceous stage of secondary succession in Japan. The mean seedling emergence times for all species were significantly increased to 23.6 and 32.2 d in the T2 and T4 plot compared to the Control plot, respectively. The most sensitive and insensitive species in seedling emergence time in T2 plot were O. biennis and D. adscendens, respectivel.y, and those in the T4 and CT4 plot were I. cylindrica and D. adscendens, E. crus-galli and A. virginicus, respectively. All experimental species showed no significant difference in the seedling emergence rate between treatments except for O. biennis and I. cylindrica. O. biennis showed a great decrease in the seedling emergence rate from 83.3% in the Control plot to 38.0%, 14.7%, and 29.3% in the T2, T4, and CT4 plot, respectively. Elevated $CO_2$ had very little effect on the seedling emergence. From these observations, it is expected that increased temperature would greatly advance the vegetative recovery time after disturbance through the advancement of seedling emergence time.

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중금속으로 오염된 해양퇴적토의 전기동력학적 정화 (Electrokinetic Extraction of Metals from Marine Sediment)

  • 김경조;유종찬;양중석;백기태
    • Korean Chemical Engineering Research
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    • 제51권6호
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    • pp.733-738
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    • 2013
  • 퇴적토는 미사 및 점토와 같은 미세토의 함량이 높으며, 유기물질이 많으며, 완충능이 크기 때문에 퇴적토로부터 중금속을 제거하는 것은 매우 어렵다. 본 연구에서는, 중금속으로 오염된 퇴적토에서 중금속을 제거하기 위해 2 V/cm의 일정한 전압경사를 적용한 실험실 규모의 전기동력학적 (EK) 정화공법을 사용하였다. 실험을 위해 적용한 음극 전해질로는 0.1 M의 ethylenediaminetetraacetic acid (EDTA), citric acid (CA), $HNO_3$, HCl, 그리고 수돗물을 사용하였으며, 양극 전해질로는 수돗물을 사용하여 순환시켜 주었다. 음극 전해질로 CA를 사용한 실험군에서 Ni, Cu, Zn, Pb는 각각 초기와 비교하여 92.4, 96.1, 97.1, 88.1%의 중금속 제거효율을 보였다. 높은 전압경사를 적용하게 되면, 음극 전해질내에 citrate 및 EDTA가 퇴적토로 이동이 용이하게 되며, 그로 인해 중금속-킬레이트 화합물을 형성하여 중금속의 추출률을 높일 수 있었다. 이러한 결과를 바탕으로, 높은 전압경사를 적용한 EK 실험에서 음극 전해질로 EDTA 혹은 CA를 사용하면 퇴적토로부터 중금속을 효과적으로 추출할 수 있다고 판단된다.