• Title/Summary/Keyword: Concentration Gradient

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The concentration differences of dental caries induced organic acids which are produced after intake of sucrose and carbonated drinks (자당 및 탄산음료 섭취 후 생성되는 구강 내 치아우식 유발성 유기산의 농도 차이)

  • Park, Jung-Eun;Jang, Jong-Hwa
    • Journal of Korean society of Dental Hygiene
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    • v.17 no.3
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    • pp.381-394
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    • 2017
  • Objectives: This study aims to evaluate carbonated drinks induced dental caries with qualitative analysis and to compare with oral organic acids including lactate, acetate, propionate, formate, butyrate, pyruvate and valerate which cause caries when taking either 10% sucrose drinks or carbonated drinks. Methods: Saliva was collected from six study subjects before and after (start, 5, 10, 30 minutes) taking water intake upon (A) 10% sucrose intake, (B) 10% sucrose intake, and (C) carbonated drink intake, then they were centrifuged at 1,200 rpm followed by removing bacteria and enzymes with syringe filtering, performing a qualitative analysis with HPLC conductivity detection (GP50 gradient pump, ED 50 detector) after saliva pre-treatment under isocratic 100 mM NaOH mobile phase. Results: Higher risk of dental caries was evaluated in order of C>B>A, with the results of total oral organic acids' concentration, lactates of organic acids and organic acids produced after 5 minutes from the 3 types of drinks intake. Conclusions: Carbonated beverages were estimated to develop higher dental caries induction than beverages containing 10% sucrose because of the high organic acid concentration in the mouth after its intake.

Degradation Efficiency and Characterization of Lincomycin by Electron Beam Irradiation

  • Ham, Hyun-Sun;Cho, Hyun-Woo;Myung, Seung-Woon
    • Mass Spectrometry Letters
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    • v.5 no.3
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    • pp.89-93
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    • 2014
  • Lincomycin is one of the major species among the Pharmaceuticals and Personal Care Products (PPCPs) detected from the four major rivers in Korea. The structure characterization was performed of six degradation products of lincomycin formed under the irradiation of electron beam, and the degradation efficiency as a function of the various irradiation dose and sample concentration was investigated. Electron beam (10 MeV, 0.5 mA and 5 kW) experiments for the structural characterization of degradation products that are fortified with lincomycin, were performed at the dose of 10 kGy. The separation of degradation products and lincomycin was carried out using a C18 column ($2.1{\times}100$ mm, $3.5{\mu}m$), using gradient elution with 20 mM ammonium acetate and acetonitrile. The structures of six degradation products of lincomycin were proposed by interpretation of mass spectra and chromatograms by LC-MS/MS. The mass fragmentation pathways of mass spectra in tandem mass spectrometry were also proposed. Experiments were performed of the degradation efficiency as a function of the irradiation dose intensity and the initial concentration of lincomycin in an aqueous environment. In addition, increased degradation efficiency was observed with a higher dose of electron beam and lower concentration.

Analysis of Characteristics of Spent Fuels on Long-Term Dry Storage Condition

  • Yoon, Suji;Park, Kwangheon;Yun, Hyungju
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.2
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    • pp.205-214
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    • 2021
  • Currently, the interim storage pools of spent fuels in South Korea are expected to become saturated from 2024. It is required to prepare an operation plan of a domestic dry storage facility during a long-term period, with the researches on safety evaluation methods. This study modified the FRAPCON code to predict the spent fuel integrity evaluation such as the axial cladding temperature, the hoop stress and hydrogen distribution in dry storage. The cladding temperature in dry storage was calculated using the COBRA-SFS code with the burnup information which was calculated using the FRAPCON code. The hoop stress was calculated using the ideal gas equation with spent fuel information such as rod internal pressure. Numerical analysis method was used to calculate the degree of hydrogen diffusion according to the hydrogen concentration and temperature distribution during a dry storage period. Before 50 years of dry storage, the cladding temperature and hoop stress decreased rapidly. However, after 50 years, they decreased gradually and the cladding temperature was below 400 K. The initial temperature distribution and hydrogen concentration showed a parabolic line, but hydrogen was transferred by the hydrogen concentration and temperature gradient over time.

Effect of Individual Low Sodium Dialysate on Blood Pressure, Interdialytic Weight Gain, Thirst and Intradialytic Discomfort In End-Stage Renal Disease Patients (개별적 저 나트륨 투석 액 적용이 말기 신부전증 환자의 혈압, 투석 간 체중 증가, 갈증 및 투석 중 불편감에 미치는 영향)

  • Kim, Sangsuk;Choi, Youngsil
    • Journal of Korean Biological Nursing Science
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    • v.21 no.3
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    • pp.169-177
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    • 2019
  • Purpose: The purpose of this paper was to identify blood pressure, interdialytic weight gain, thirst and intradialytic discomfort in subjects after applying individual low-sodium dialysis fluid (1,2,3 mEq/L) to hemodialysis patients for 12 weeks. Methods: This study was a non-equivalent pre-post design. For 12 weeks, dialysate concentration was maintained at 1 mEq/L or 2 mEq/L or 3 mEq/L based on average sodium concentration of each individual, and the difference was compared after applying individually. Results: Change in blood pressure significantly decreased in the group where in pre-hemodialysis systolic pressure decreased the gradient of sodium concentration in serum sodium and dialysis solution by 2mEq/L. Interdialytic weight gain, and thirst showed significant decrease in all three groups. But in all three groups, intradialytic discomfort among dialysis showed no significant changes. Conclusion: Although application of low sodium dialysis fluid showed no change in intradialytic discomfort, lowered blood pressure, thirst, and interdialytic weight gain, which could be used for individual showing increased interdialytic weight gain and increased blood pressure. There is need for continued study on this.

Growth and characterization of semi-insulating GaAs co-doped with Cr and In by vertical gradient freeze technique (수직온도구배냉각법으로 크롬과 인듐이 함께 도핑된 반절연 갈륨비소 단결정의 성장 및 특성평가)

  • Young Ju Park;Suk-Ki Min;Kee Dae Shim;Mann J. Park
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.1
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    • pp.83-91
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    • 1994
  • We have constructed a vertical gradient freeze (VGF) grower for GaAs single crystals 2 inch in diameter and have grown semi-insulating GaAs co-doped with Cr and In. For the co-doped crystal, the segregation coefficients of the dopants remain unchanged when compared to those doped with only Cr or In. The concentration of Cr and in atoms range from about $2{\Times}10_{16} to 3{imes}10^{17} cm^{-3}$ and $2{\Times}10^{19} to 3{\Times}10^{20} cm^{-3}$ at the seed to the tail part of the grown crystal, respectively. The averaged dislocation etch pit density is found to be less than $8000 cm^{-2}$ throughout the ingot. It is also found that there is some evidence of lattice hardening for the crystal in which the dislocation density is decreased to less than $1000 cm^{-2}$ as In concentration increases. The resistivity increases abruptly from $10^{-2}$ up to $10^8$ Ohm-cm, while the carrier concentration decreases from $10^{16}$ to $10^8 cm^{-3}$ along the growth direction of the GaAs crystal. Semi-insulating properties can be obtained above a critical concentration of Cr of about $6{\Times}10{^16} cm^{-3}$ in the crystal. The main deep levels existing in the GaAs: Cr,In sample are two electron traps at $E_C-0.81eV, E_C-0.35eV$, and two hole traps at $E_V+0.89eV, E_V+0.65eV$.

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Preliminary Measurements of Mercury Exchange Rates Across the Soil-Air Boundary in a Residential Area of Seoul (토양-대기의 수은 교환작용 -서울시 주거지역에 대한 예비측정-)

  • 김기현;김민영
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.4
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    • pp.369-377
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    • 1998
  • To examine various aspects of Hg exchange processes, we measured Hg$^{\circ}$concentration gradients over soil surfaces in a residential area of Seoul during Sept. 1997. From these measurements, we found that Hg$^{\circ}$concentrations in lower(20 cm) and upper(200 cm) levels varied in the range of 3.15~14.38 (5.30$\pm$1.88: N=236) and 2.07~15.10ng/m$^3$(4.06$\pm$1.69: N=236), respectively. When our data were divided into emission and dry deposition, emission of Hg$^{\circ}$was overwhelmingly dominant (up to 98% in frequency) over dry deposition. The concentration gradients for emission and deposition events were 1.29$\pm$0.86(N=231) and -1.0$\pm$1.27ng/m$^3$(N=5), respectively. The observation of excessively high concentrations in both levels and development of strong gradients suggest that our study site be greatly affected by certain pollution sources of mercury. In face, those data were quite comparable to that had previously been observed from highly contaminated soil environs of Tennessee, USA. To provide some insights into the processes governing the Hg$^{\circ}$exchange processes, we have conducted correlation analyses between Hg$^{\circ}$data and other concurrently determined meteorological plus chemical data. In general, Hg$^{\circ}$concentrations of both levels exhibited similarly the existence of strong correlations with parameters like windspeed, temperature, and relative humidity. Although its concentration gradient data showed similarly strong correlations with meteorological parameters, they showed somewhat unique patterns in that their correlations with Hg$^{\circ}$concentration were noticeably stronger for the lower level than the upper level. To provide rough estimates of Hg$^{\circ}$fluxes in this study, we computed its flux using our gradient data and the predicted K values from previous studies. According to this approach, Hg$^{\circ}$emissions were generally in the range of 103$\pm$80(N=231), while its depositions, being scarcely found, were on the similar magnitude of -92$\pm$128ng/m$^2$/hr(N=5). The findings of excessive emission of Hg$^{\circ}$in residential area of Korea suggests that contamination of mercury be a significant process and hence be dealt more seriously.

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Microwave Radiation Characteristics of Glacial Ice in the AMSR-E NASA Team2 Algorithm (AMSR-E NASA Team2 알고리즘에서 빙하빙의 마이크로파 복사특성)

  • Han, Hyang-Sun;Lee, Hoon-Yol
    • Korean Journal of Remote Sensing
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    • v.27 no.5
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    • pp.543-553
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    • 2011
  • Sea ice concentration calculated from the AMSR-E onboard Aqua satellite by using NASA Team2 sea ice algorithm has proven to be very accurate over sea ice in Antarctic Ocean. When glacial ice such as icebergs and ice shelves are dominant in an AMSR-E footprint, the accuracy of the ice concentration calculated from NASA Team2 algorithm is not well maintained due to the different microwave characteristics of the glacial ice from sea ice. We extracted the concentrations of sea ice and glacial ice from two ENVISAT ASAR images of George V coast in southern Antarctica, and compared them with NASA Team2 sea ice concentration. The result showed that the NASA Team2 algorithm underestimates the concentration of glacial ice. To interpret the large deviation of estimation over glacial ice, we analyzed the characteristics of microwave radiation of the glacial ice in PR(polarization ratio), GR(spectral gradient ratio), $PR_R$(rotated PR), and ${\Delta}GR$ domain. We found that glacial ice occupies a unique region in the PR, GR, $PR_R$, and ${\Delta}GR$ domain different from other types of ice such as ice type A, B, and C, and open water. This implies that glacial ice can be added as a new category of ice to the AMSR-E NASA Team2 sea ice algorithm.

Supplementing Rhodobacter sphaeroides in the diet of lactating Holstein cows may naturally produce coenzyme Q10-enriched milk

  • Bae, Gui-Seck;Choi, Ahreum;Yeo, Joon Mo;Kim, Jong Nam;Song, Jaeyong;Kim, Eun Joong;Chang, Moon Baek
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.1
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    • pp.40-46
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    • 2018
  • Objective: To examine the effects of Rhodobacter sphaeroides (R. sphaeroides) supplementation as a direct-fed microbial (DFM) on rumen fermentation in dairy cows and on coenzyme Q10 (CoQ10) transition into milk, an in vitro rumen simulation batch culture and an in vivo dairy cow experiment were conducted. Methods: The characteristics of in vitro ruminal fermentation were investigated using rumen fluids from six cannulated Holstein dairy cows at 2 h post-afternoon feeding. A control treatment was included in the experiments based on a typified total mixed ration (TMR) for lactating dairy cows, which was identical to the one used in the in vivo study, plus R. sphaeroides at 0.1%, 0.3%, and 0.5% TMR dry matter. The in vivo study employed six ruminally cannulated lactating Holstein cows randomly allotted to either the control TMR (C-TMR) treatment or to a diet supplemented with a 0.5% R. sphaeroides culture (S-TMR, dry matter basis) ad libitum. The presence of R. sphaeroides was verified using denaturing gradient gel electrophoresis (DGGE) applied to the bacterial samples obtained from the in vivo study. The concentration of CoQ10 in milk and in the supernatant from the in vitro study was determined using high performance liquid chromatography. Results: The results of the in vitro batch culture and DGGE showed that the concentration of CoQ10 significantly increased after 2 h of R. sphaeroides supplementation above 0.1%. When supplemented to the diet of lactating cows at the level of 0.5%, R. sphaeroides did not present any adverse effect on dry matter intake and milk yield. However, the concentration of CoQ10 in milk dramatically increased, with treated cows producing 70.9% more CoQ10 than control cows. Conclusion: The CoQ10 concentration in milk increased via the use of a novel DFM, and R. sphaeroides might be used for producing value-added milk and dairy products in the future.

The Features Associated with the Yellow Sand Phenomenon Observed in Korea in Wintertime (겨울철 황상 현상의 특징)

  • 전영신;김지영;부경온;김남욱
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.5
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    • pp.487-497
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    • 2000
  • Spring time is a favorable season to be easily observed the Yellow Sand phenomenon in East Asia. In particular most of the phenomenon tend to occur in April. However, Yellow Sand phenomenon was observed from almost the whole country of Korea in winter of 1966, 1977 and 1999. The features of the synoptic weather pattern in the source regions, air stream flow between the source region and Korea, the measurement of TSP concentration, aerosol size distribution, and chemical composition of snow samples associated with Yellow Sand phenomenon were investigated. The result showed the characteristic evolutionary feature of the synoptic system associated with Yellow Sand phenomena, that is, a strong low level wind mobilized the dust within 2 or 3 days before Yellow Sand phenomenon being observed in Seoul. The wind was remarkably intensified in the source region on January 24, 1999 under the strong pressure gradient, A trajectory analysis showed that the Yellow Sand particle could be reached to Korea within 2 days from the source region, Gobi desert, through Loess plateau and Loess deposition region. The TSP concentration at the top of Kwanak mountain during the Yellow Sand phenomenon is abruptly increasing than the monthly mean concentration. The size resolved number concentration of aerosols ranging from 0.3 to 25${\mu}{\textrm}{m}$ was analyzed during Yellow Sand episode. It was evident that aerosols were distinguished by particles in the range of 2-3 ${\mu}{\textrm}{m}$ to result in the abrupt increase in January 1999, After Yellow Sand phenomenon, there was heavy snow in Seoul. By the analysis of snow collected during that time, it was observed that both the Ca(sup)2+ concentration and pH were increased abnormally compared to those in the other winter season.

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Effect of Low Salt Concentrations on Microbial Changes During Kimchi Fermentation Monitored by PCR-DGGE and Their Sensory Acceptance

  • Ahmadsah, Lenny S. F.;Min, Sung-Gi;Han, Seon-Kyeong;Hong, Yeun;Kim, Hae-Yeong
    • Journal of Microbiology and Biotechnology
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    • v.25 no.12
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    • pp.2049-2057
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    • 2015
  • Various salt concentrations (1.0%, 1.3%, 1.6%, 1.9%, and 2.1% labeled as sample A, B, C, D, and E, respectively) were investigated for microbial diversity, identification of Lactic Acid Bacteria (LAB) in salted kimchi cabbage, prepared under laboratory conditions. These samples were stored at 4°C for 5 weeks in proper aluminum-metalized pouch packaging with calcium hydroxide gas absorber. A culture-independent method known as polymerase chain reaction - denaturing gradient gel electrophoresis was carried out to identify LAB distributions among various salt concentration samples that had identified 2 Weissella (W. confusa and W. soli), 1 Lactobacillus (Lb. sakei), and 3 Leuconostoc (Lc. mesenteroides, Lc. lactis, and Lc. gelidum) in the overall kimchi samples. The pH, titratable acidity, viable cell counts, and coliform counts were not affected by salt variations. In order to assess sensory acceptance, the conducted sensory evaluation using a 9-point hedonic scale had revealed that samples with 1.3% salt concentration (lower than the manufacturer's regular salt concentration) was more preferred, indicating that the use of 1.3% salt concentration was acceptable in normal kimchi fermentation for its quality and safety. Despite similarities in pH, titratable acidity, viable cell counts, coliform counts, and LAB distributions among the various salt concentrations of kimchi samples, the sample with 1.3% salt concentration was shown to be the most preferred, indicating that this salt concentration was suitable in kimchi production in order to reduce salt intake through kimchi consumptions.