• Carbon letters
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• 제4권3호
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• pp.111-116
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• 2003

Carbon/carbon composites were developed using PAN based carbon fibres and phenolic resin as matrix in different volume fractions and heat treated to temperatures between $1000^{\circ}C$ to $2500^{\circ}C$. Although both the starting precursors are nongraphitizing hard carbons individually, their composites lead to very interesting properties e.g. x-ray diffractograms show the development of graphitic phase for composites having fibre volume fractions of 30~40%. Consequently the electrical resistivity of such composites reaches a value of $0.8\;m{\Omega}cm$, very close to highly graphitic material. However, it was found that by increasing the fibre volume fraction to 50~60%, the trend is reversed. Optical microscopy of the composites also reveals the development of strong columnar type microstructure at the fibre (matrix interface due to stress graphitization of the matrix. The study forcasts a unique possibility of producing high thermal conductivity carbon/carbon composites starting with carbon fibres in the chopped form only.

• 한국재료학회지
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• 제21권4호
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• pp.196-201
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• 2011

It is known that the relative dielectric constant of insulating polyethylene matrix composites with conducting materials (such as carbon black and metal powder) increases as the conducting material content increases below the percolation threshold. Below the percolation threshold, dielectric properties show an ohmic behavior and their value is almost the same as that of the matrix. The change is very small, but its origin is not clear. In this paper, the dielectric properties of carbon black-filled polyethylene matrix composites are studied based on the effect medium approximation theory. Although there is a significant amount of literature on the calculation based on the theory of changing the parameters, an overall discussion taking into account the theory is required in order to explain the dielectric properties of the composites. Changes of dielectric properties and the temperature dependence of dielectric properties of the composites made of carbon particle and polyethylene below the percolation threshold for the volume fraction of carbon black have been discussed based on the theory. Above the percolation threshold, the composites are satisfied with the universal law of conductivity, whereas below the percolation threshold, they give the critical exponent of s = 1 for dielectric constant. The rate at which the percentages of both the dielectric constant and the dielectric loss factor for temperature increases with more volume fraction below the percolation threshold.

• Composites Research
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• 제37권2호
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• pp.115-125
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• 2024

환경에 대한 범세계적인 문제와 관심이 고조되는 가운데 자동차 산업에서도 친환경 소재로의 전환이 가속화되고 있다. 자동차 산업에서 친환경 복합재료는 차량 내부 및 비 구조 부품에 주로 사용된다. 특히 천연섬유 복합재료는 차량의 경량화로 연료 소비와 온실가스 배출을 줄이는데 도움을 주며 재활용이 가능하고 우수한 열적 특성과 내구성을 가지고 있어 자동차 내장 부품에 적합하다. 아울러 생산 비용 절감과 지속 가능성은 천연섬유 복합재료의 주요 장점이다. 친환경 복합재료 시장은 2022년부터 2030년까지 연평균 성장률 15.3%로 864억 3천만 달러 규모로 성장할 것으로 기대되며, 천연섬유 복합재료 시장은 2023년부터 2028년까지 연평균 5.3% 성장해 4억 2,400만 달러에 이를 것으로 예상된다. 본 리뷰 논문에서는 천연섬유 복합재료를 중심으로 차세대 자동차용 친환경 복합재료의 연구 동향과 실제 자동차 산업에서의 적용에 대해 탐구한다.

• 한국분말재료학회지
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• 제17권2호
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• pp.107-112
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• 2010

Carbon-nanotube-embedded bismuth telluride (CNT/$Bi_2Te_3$) matrix composites were fabricated by a powder metallurgy process. Composite powders, whereby 5 vol.% of functionalized CNTs were homogeneously mixed with $Bi_2Te_3$ alloying powders, were successfully synthesized by using high-energy ball milling process. The powders were consolidated into bulk CNT/$Bi_2Te_3$ composites by spark plasma sintering process at $350^{\circ}C$ for 10 min. The fabricated composites showed the uniform mixing and homogeneous dispersion of CNTs in the $Bi_2Te_3$ matrix. Seebeck coefficient of CNT/$Bi_2Te_3$ composites reveals that the composite has n-type semiconducting characteristics with values ranging $-55\;{\mu}V/K$ to $-95\;{\mu}V/K$ with increasing temperature. Furthermore, the significant reduction in thermal conductivity has been clearly observed in the composites. The results showed that CNT addition to thermoelectric materials could be useful method to obtain high thermoelectric performance.

• 한국전기전자재료학회논문지
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• 제20권4호
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• pp.348-351
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• 2007

Recently, Nanotechnology becomes a major issue in most part of industries. Nanotechnology is expected to develop various application products due to nano material mired composites is improved physical and electrical properties compared to conventional composites materials. Dielectric and insulation materials need to develop and improve like other field about nanotechnology. In this paper, we reported dielectric dispersion by size(no filler, $1.2{\mu}m$, 500 nm, 10 nm), frequencies(60, 120, 1 kHz), and temperatures($30{\sim}170^{\circ}C$). Dielectric constant of composites materials with filler shows higher than composites materials without filler and increased depending on rising temperatures in low frequency region. It was the effect that nano-filler and impurities in composites contributed to electrical conductivity. And dielectric properties depending on temperatures shows to change in low frequency region dramatically We analyzed interfacial polarization in low frequency region($10^{-2}$ Hz) and oriented polarization in high frequency region($10^{-5{\sim}6}$ Hz) on composites materials.

• 한국분말재료학회지
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• 제30권3호
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• pp.262-267
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• 2023

Boron carbide (B₄C) is highly significant in the production of lightweight protective materials when added to aluminum owing to its exceptional mechanical properties. In this study, a method for fabricating Al-B₄C composites using high-energy ball milling and directed energy deposition (DED) is presented. Al-4 wt.% B4C composites were fabricated under 21 different laser conditions to analyze the microstructure and mechanical properties at different values of laser power and scan speeds. The composites fabricated at a laser power of 600 W and the same scan speed exhibited the highest hardness and generated the fewest pores. In contrast, the composites fabricated at a laser power of 1000 W exhibited the lowest hardness and generated a significant number of large pores. This can be explained by the influence of the microstructure on the energy density at different values of laser power.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 춘계학술발표대회 논문집
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• pp.122-125
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• 2001

The objective of this research is to develop hybridized yarns for thermoplastic composites, and to examine tile effect of cooling rate on mechanical properties of the composites. The co-braided yarn utilizing carbon fibers as reinforcements and Nylon 66 fibers as matrix materials has been fabricated. Thermoplastic composites have been manufactured by the hot-press forming process. For the processing conditions, cooling rates of $-2.5^{\circ}C$/min and $-60^{\circ}C$/min have been considered. Three-point bending test and losipescu shear test were performed to investigate the effect of the cooling rate and the surface treatment of carbon fibers. SEM photographs were used to investigate the fracture surfaces of the tested samples. The cooling rate of $-60^{\circ}C$/min resulted in the higher strength and elastic modulus for bending and shear tests. The composites of the epoxy-sized carbon fibers showed the lowest strength due to the degradation of the sizing material during the thermoforming process.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 추계학술발표대회 논문집
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• pp.29-32
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• 2001

The objective of this work was to optimize processing parameters of hybrid thermoplastic composites in compression molding. The mechanical properties of the composites manufactured with various forming conditions were measured to characterize processing parameters. Polypropylene(PP) composites containing randomly oriented long carbon fiber and carbon black were used in this work. The composite materials contained 5%, 10%, 15%, and 20% carbon fiber and 5%, 10%, 15%, 20%, and 25% carbon black by weight. Compression molding was conducted at various mold temperatures. The temperature of the material in the mid-plain was monitored during the forming. Crystallinity was also measured by using XRD. The tensile modulus of the composites increase, with increasing the mold temperature. However, the impact strength of the composites decreases as mold temperature increases.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 추계학술발표대회 논문집
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• pp.129-132
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• 2001

Fiber waviness is one of manufacturing defects encountered frequently in thick composite structures. It affects significantly on the behavior as well as strength of thick composites. The effects of fiber waviness on tensile/compressive nonlinear elastic behavior and strength of thick composite with fiber waviness are studied theoretically and experimentally. FEA(Finite Element Analysis) models are proposed to predict tensile/compressive nonlinear behavior and strength of thick composites. In the FEA models, both material and geometric nonlinearities were incorporated into the model using energy density, iterative mapping and incremental method. Also Tsai-Wu criteria was adopted to predict the strength of thick composites with fiber waviness. Tensile and compressive tests were conducted on the specimens with uniform fiber waviness. It was observed that the degree of fiber waviness in composites significantly affected the nonlinear behavior and strength of the composites

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 추계학술발표대회 논문집
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• pp.29-32
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• 2002

The mechanical and thermal properties of spun carbon fabric/continuous carbon fabric interplay hybrid composite materials have been studied. The properties of the hybrid composites are compared with those of the continuous carbon fabric/phenolic composites and spun carbon fabric /phenolic composites. Through hybridization, tensile strength and flexural strength of hybrid composites were increased by about 17%, and 10%, respectively compared with spun carbon composites. The thermal conductivity of the hybrid composite is lower approximately 4~6% along the direction parallel to the laminar plane than that of the continuous carbon/phenolic composite.