• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2003년도 추계학술발표대회 논문집
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• pp.75-78
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• 2003

In order to describe the Bauschinger and transient behavior of orthotropic fiber-reinforced composites, a combined isotropic-kinematic hardening law based on the non-linear kinematic hardening rule was considered here, in particular, based on the Chaboche type law. In this modified constitutive law, the anisotropic evolution of the back-stress was properly accounted for. Also, to represent the orthotropy of composite materials, Hill's 1948 quadratic yield function and the orthotropic elasticity constitutive equations were utilized. Furthermore, the numerical formulation to update the stresses was also developed based on the incremental deformation theory for the boundary value problems. Numerical examples confirmed that the new law based on the anisotropic evolution of the back-stress complies well with the constitutive behavior of highly anisotropic materials such as fiber-reinforced composites.

• The Korean Journal of Ceramics
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• 제4권3호
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• pp.171-175
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• 1998

$Al_2O_3$-TiC composites were prepared from aluminum, titanium oxide, and carbon fibers by self-propagating high-temperature synthesis(SHS). After the SHS reaction, the TiC phase in the sample was found either fibrous or non-fibrous shape. The fraction of the fibrous TiC phase varied with the amount of $Al_2O_3$ diluent addition. The optimum amount of diluent to make fibrous carbide was determined to be 30%. The fibers were hollow inside and made of multiple grains with a composition of titanium carbide. The hollow fiber formation mechanism was suggested and discussed. The synthesized powders were consolidated to dense composites by hot pressing at $1750^{\circ}C$ under 30 MPa.

• 한국세라믹학회지
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• 제39권7호
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• pp.622-627
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• 2002

Multi-layer composites consisting of silicon nitride, silicon nitride-silicon carbide and boron nitride-alumina layers were prepared fly stacking the corresponding ceramic tapes. The composites demonstrated self-diagnostic capability and non-catastrophic failure behavior. The composites consisting of many thin layers exhibited high strength and stepwise increase of the electrical resistance during the flexure test. The strength of the composite with too thick silicon nitride layers was low and the electrical resistance was abruptly increased to the detection limit of the digital multi-meter during the test. An extensive crack branching was observed in the weak (BN + Al$_2$O$_3$)layer.

• KSBB Journal
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• 제25권5호
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• pp.409-420
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• 2010

Biopolymer-based materials recently have garnered considerable interest as they can decrease dependency on fossil fuel. Biopolymers are naturally obtainable macromolecules including polysaccharides, polyphenols, polyesters, polyamides, and proteins, that play an important role in biomedical applications such as tissue engineering, regenerative medicine, drug-delivery systems, and biosensors, because of their inherent biocompatibility and biodegradability. However, the insolubility of unmodified biopolymers in most organic solvents has limited the applications of biopolymer-based materials and composites. Ionic liquids (ILs) are good solvents for polar organic, nonpolar organic, inorganic and polymeric compounds. Biopolymers such as cellulose, chitin/chitiosan, silk, and DNA can be fabricated from ILs into films, membranes, fibers, spheres, and molded shapes. Various biopolymer/biopolymer and biopolymer/synthetic polymer composites also can be prepared by co-dissolution of polymers into IL mixtures. Heparin/biopolymer composites are especially of interest in preparing materials with enhanced blood compatibility.

• 분석과학
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• 제21권1호
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• pp.25-33
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• 2008

Organic disulfide compounds are having higher theoretical capacity than the conventional cathode material and are considered as the important storage material. Here, we are reporting the preparation of poly (2,2'-dithiodianiline) PDDA/multiwall carbon nanotubes, (MWCNTs) composites under different experimental conditions. Amine functionalized and unfunctionalized MWCNTs were independently used for the preparation of composites. Composites were prepared in the presence of cetyl trimethyl bromide (CTAB), a cationic surfactant, and also in the absence of CTAB. A physical mixture of PDTDA and MWCNTs was formed with unfunctionalized MWCNTs. Grafting of PDDA onto MWCNTs was performed by chemical oxidative polymerization of 2, 2'-dithiodianiline in the presence of amine functionalized MWCNTs. The composites of MWCNTs and PDTDA were characterized for structure, morphology and thermal properties through Fourier transform infrared spectroscopy, Fourier transform Raman spectroscopy, scanning electron microscopy and UV-visible spectroscopy. The composite materials prepared by this method are expected to find applications as electrode materials for lithium batteries.

• Composites Research
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• 제31권1호
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• pp.23-29
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• 2018

RFI 공정은 수지 점도에 제한이 없어 매우 두꺼운 구조물에도 적용이 가능하다. 수지필름 두께를 설정할 때 수지필름의 두께가 얇은 경우 미함침 구간이 발생하여 기계적 물성이 저하되고, 수지필름 두께가 두꺼운 경우 필요이상의 여분 수지가 발생하게 된다. 따라서 본 연구에서는 RFI 공정에서 수지필름 두께 설정을 위한 방법을 제시하였다. 적정 수지필름 두께를 설정하는 방법으로 섬유압착거동 시험을 제시하였고, 제시된 방법의 검증을 위해 숏빔전단강도시험, 압축시험, 기공률 측정을 통해 복합재 물성을 평가하였다. 복합재 물성 평가 결과, 섬유압착거동시험 결과를 바탕으로 적정 수준의 수지필름 두께를 찾을 수 있었다.

• Elastomers and Composites
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• 제47권2호
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• pp.121-128
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• 2012

제대로 재활용되지 못하고 있는 폐 EPDM 즉, 자동차 Weather strip이나 세탁기 가스켓 등에서 재생한 폐EPDM 분말을 적합하고 경제성있는 Polyolefin계 Elastomer와 수지(Binder), 그리고 Filler 및 기타 첨가제를 선정하여, 다양한 배합조건으로 고무 복합소재를 압출 제조하였다. 본 실험에 유익한 기초 실험으로서, 폐 EPDM의 초음파처리 효과, 폐 EPDM복합소재의 폐타이어 복합소재와의 물성 비교, Virgin EPDM과 Devulcanized EPDM과의 비교, 그리고 12 축압출기로 압출한 재료의 물성에의 영향을 고찰하였다. 폐 EPDM을 이용하여 인조잔디 충전재와 카매트용 복합소재를 2 축압출기를 사용하여 압출한 후, 인장시편을 사출하여 인장강도, 신율, 경도의 세가지 물성을 주요 평가지표로 삼고 경제적인 배합처방을 개발하였다.

• Carbon letters
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• 제5권1호
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• pp.18-22
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• 2004

The failure behaviours of unidirectional pultruded carbon fiber reinforced polymer (CFRP) composites were monitored by the electrical resistance measurement during tensile loading, three-point-bending, interlaminar shear loading. The tensile failure behaviour of carbon fiber tows was also investigated by the electrical resistance measurement. Infrared thermography non-destructive evaluation was performed in real time during tensile test of CFRP composites to validate the change of microdamage in the materials. Experiment results demonstrated that the CFRP composites and carbon fiber tows were damaged by different damage mechinsms during tensile loading, for the CFRP composites, mainly being in the forms of matrix damage and the debonding between matrix and fibers, while for the carbon fiber tows, mainly being in the forms of fiber fracture. The correlation between the infrared thermographs and the change in the electrical resistance could be regarded as an evidence of the damage mechanisms of the CFRP composites. During three-point-bending loading, the main damage forms were the simultaneity fracture of matrix and fibers firstly, then matrix cracking and the debonding between matrix and fiber were carried out. This results can be shown in Fig. 9(a) and (b). During interlaminar shear loading, the change in the electrical resistance was related to the damage degree of interlaminar structure. Electrical resistance measurement was more sensitive to the damage behaviour of the CFRP composites than the stress/time curve.

• 한국분말재료학회지
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• 제13권2호
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• pp.144-149
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• 2006

In this research we tried to make nano-sized TiNx by using planetary milling, and we made the composites double layered of titanium and nano-sized TiNx by using spark plasma sintering apparatus after mixing with the different ratio of pure titanium powder, and they were heat treated at $850^{\circ}C$ for 30 minutes. The crystal structures of nano-sized TiNx powders and the composites were analyzed by X-ray diffraction (XRD). The microstructures of the powders were analyzed by using scanning electron microscopy (FESEM) and the 40-50 nm size of nano-sized TiNx particle on the surface of agglomerated particles was investigated. With increasing the ratio of nano-sized TiNx of the composites, the microvickers hardness of the composites was increased.

• 폴리머
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• 제35권1호
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• pp.60-65
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• 2011

고분자 나노복합재의 성능을 극대화 하기 위해서는 나노업자 분산도의 향상과 더불어 분산상태가 물성 변화에 미치는 영향을 정확히 이해하는 것이 매우 중요하다. 본 연구에서는 탄소나노튜브 첨가 고분자 복합재의 분산상태를 정량적으로 평가할 수 있는 방법을 제시하고자 하였다. 자외선-가시광선 분광광도법을 이용하여 탄소나노튜브의 분산상태에 따른 투과도를 측정하였으며, 동일 농도에서 분산상태가 향상됨에 띠라 투과도가 감소하는 것을 확인하였다. 이러한 결과를 바탕으로 기존의 Beer-Lambert 투과도 법칙에 분산상태의 변화를 포함할 수 있는 새로운 분산도 평가인자인 유효 농도 인자를 제시하였다. 이를 통해 탄소나노튜브의 분산상태의 변화와 함께 다양한 탄소나노튜브의 농도 및 시편 두께에 따른 투과도 결과를 분석함으로써 제시한 분산도 평가방법과 유효 농도 인자의 유효성을 확인하였다.