• Title/Summary/Keyword: Composite nanostructures

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Analytical solutions for bending of transversely or axially FG nonlocal beams

  • Nguyen, Ngoc-Tuan;Kim, Nam-Il;Lee, Jaehong
    • Steel and Composite Structures
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    • v.17 no.5
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    • pp.641-665
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    • 2014
  • This paper presents the analytical solutions for the size-dependent static analysis of the functionally graded (FG) beams with various boundary conditions based on the nonlocal continuum model. The nonlocal behavior is described by the differential constitutive model of Eringen, which enables to this model to become effective in the analysis and design of nanostructures. The elastic modulus of beam is assumed to vary through the thickness or longitudinal directions according to the power law. The governing equations are derived by using the nonlocal continuum theory incorporated with Euler-Bernoulli beam theory. The explicit solutions are derived for the static behavior of the transversely or axially FG beams with various boundary conditions. The verification of the model is obtained by comparing the current results with previously published works and a good agreement is observed. Numerical results are presented to show the significance of the nonlocal effect, the material distribution profile, the boundary conditions, and the length of beams on the bending behavior of nonlocal FG beams.

Large Area Deposition of Biomimetic Polydopamine-Graphene Oxide Hybrids using Langmuir-Schaefer Technique (랭뮤어-쉐퍼 기법 이용 생체모사 폴리도파민-산화그래핀 복합체 대면적 적층 기법 연구)

  • Kim, Tae-Ho;Song, Seok Hyun;Jo, Kyung-Il;Koo, Jaseung
    • Journal of Adhesion and Interface
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    • v.20 no.3
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    • pp.110-115
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    • 2019
  • Graphene oxide has been gathering interests as a way to exfoliate graphene. Since the oxidation group of graphene oxide can hydrogen bond with various functional groups, tremendous efforts have been actively conducted to apply various applications. However, graphene oxide alone cannot substantially possess the mechanical properties required for the practical application. Therefore, in this study, polydopamine, which is a bio-mimetic mussel protein-inspired material, was combined with graphene oxide to form a large-area composite membrane at the liquid-gas interface. In addition, the morphology of the polydopamine-graphene oxide composite thin film was also controlled to obtain a composite membrane having a nano-wrinkle structure. It can be expected to be used in the next generation seawater desalination membranes or carbon composites because it can form mechanically superior and sophisticated nanostructures.

Nanostructured Bulk Ceramics (Part I)

  • Han, Young-Hwan;Mukherjee, Amiya K.
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.225-228
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    • 2009
  • The processing and characterization of ceramic nanocomposites, which produce bulk nanostructures with attractive mechanical properties, have been emphasized and introduced at Prof. Mukherjee's Lab at UC Davis. The following subjects will be introduced in detail in Part II, III, and IV. In Part II, the paper will describe a three-phase alumina-based nanoceramic composite demonstrating superplasticity at a surprisingly lower temperature and higher strain rate. The next part will show that an alumina-carbon nanotube-niobium nanocomposite produced fracture toughness values that are three times higher than that of pure nanocrystalline alumina. It was possible to take advantage of both fiber-toughening and ductile-metal toughening in this investigation. In the fourth section, discussed will be a silicon-nitride/silicon-carbide nanocomposite, produced by pyrolysis of liquid polymer precursors, demonstrating one of the lowest creep rates reported so far in ceramics at the comparable temperature of $1400^{\circ}C$. This was first achieved by avoiding the oxynitride glass phase at the intergrain boundaries. One important factor in the processing of these nanocomposites was the use of the electrical field assisted sintering method. This allowed the sintering to be completed at significantly lower temperatures and during much shorter times. These improvements in mechanical properties will be discussed in the context of the results from the microstructural investigations.

Carbon rich fly ash and their nanostructures

  • Salah, Numan;Habib, Sami S.;Khan, Zishan H.;Alshahrie, Ahmed;Memic, Adnan;Al-ghamdi, Attieh A.
    • Carbon letters
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    • v.19
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    • pp.23-31
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    • 2016
  • Carbon rich fly ash was recently reported to have compositions that are ideal for use as a precursor and catalyst for carbon nanotube growth. This fly ash powder is mostly composed of pure carbon, predominantly present as sp2. In this work, the effect of sonication time on the morphology and structural properties of carbon rich fly ash particles is reported. The obtained results show that ultrasound treatment is an effective tool for producing ultrafine particles/fragments with higher porosity, which might be suitable for the adsorption of gasses. Moreover, carbon nanoparticles (CNPs) of this fly ash were produced in parallel using the ball milling technique, and were evaluated as reinforcements for epoxy based composites. These CNPs have almost spherical shapes with particle sizes of around 30 nm. They were found to have strong C=O carbonyl group bonds, which might be generated during the ball milling process. The tensile testing results of a fly ash CNP reinforced epoxy composite showed significant improvements in the mechanical properties, mainly in the stiffness of the polymer. The stiffness value was increased by around 23% of that of neat epoxy. These CNPs with chemically active groups might also be useful for other applications.

Thermal characteristics of defective carbon nanotube-polymer nanocomposites

  • Unnikrishnan, V.U.;Reddy, J.N.;Banerjee, D.;Rostam-Abadi, F.
    • Interaction and multiscale mechanics
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    • v.1 no.4
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    • pp.397-409
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    • 2008
  • The interfacial thermal resistance of pristine and defective carbon nanotubes (CNTs) embedded in low-density polyethylene matrix is studied in this paper. Interface thermal resistance in nanosystems is one of the most important factors that lead to the large variation in thermal conductivities in literature and the novelty of this paper lies in the estimation of the interfacial thermal resistance for defective nanotubes-systems. Thermal properties of CNT nanostructures are estimated using molecular dynamics (MD) simulations and the simulations were carried out for various temperatures by rescaling the velocities of carbon atoms in the nanotube. This paper also deals with the mesoscale thermal conductivities of composite systems, using effective medium theories by considering the size effect in the form of interfacial thermal resistance and also using the conventional micromechanical methods like Hashin-Shtrikman bounds and Wakashima-Tsukamoto estimates.

Nano-Silica effect on the physicomechanical properties of geopolymer composites

  • Khater, H.M.
    • Advances in nano research
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    • v.4 no.3
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    • pp.181-195
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    • 2016
  • Addition of nano-$SiO_2$ (NS) to geopolymer composites has been studied through measurement of compressive strengths, FTIR and XRD analysis. Alumino-silicate materials are coarse aggregate included waste concrete and demolished walls with its cementing binder, cement kiln dust (CKD) used and can possess a pronouncing activation for the geopolymer reaction resulting from the high alkali contents within. Materials prepared at water/binder ratios in a range of 0.30: 0.40 under curing of $40^{\circ}C$ and 100% Relative Humidity (R.H.), while the used activator is sodium hydroxide in the ratio of 2 wt. %. First, CKD is added in the ratio from 10 up to 50 wt., %, and the demolished walls was varied depending on the used CKD content, while using constant ratio of waste concrete (40 wt., %). Second step, depending on the optimum CKD ratio resulted from the first one (40 wt. %), so the control geopolymer mix composed of cement kiln dust, demolished walls and waste concrete in the ratio (40:20:40, wt %). Nano-silica partially replaced waste concrete by 1 up to 8%. Results indicated that, compressive strengths of geopolymer mixes incorporating nano-silica were obviously higher than those control one, especially at early ages and specially with 3%NS.

Electro-mechanical vibration of nanoshells using consistent size-dependent piezoelectric theory

  • Ebrahimi, Narges;Beni, Yaghoub Tadi
    • Steel and Composite Structures
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    • v.22 no.6
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    • pp.1301-1336
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    • 2016
  • In this paper, the free vibrations of a short cylindrical nanotube made of piezoelectric material are studied based on the consistent couple stress theory and using the shear deformable cylindrical theory. This new model has only one length scale parameter and can consider the size effects of nanostructures in nanoscale. To model size effects in nanoscale, and considering the nanotube material which is piezoelectric, the consistent couple stress theory is used. First, using Hamilton's principle, the equations of motion and boundary condition of the piezoelectric cylindrical nanoshell are developed. Afterwards, using Navier approach and extended Kantorovich method (EKM), the governing equations of the system with simple-simple (S-S) and clamped-clamped (C-C) supports are solved. Afterwards, the effects of size parameter, geometric parameters (nanoshell length and thickness), and mechanical and electric properties (piezoelectric effect) on nanoshell vibrations are investigated. Results demonstrate that the natural frequency on nanoshell in nanoscale is extremely dependent on nanoshell size. Increase in size parameter, thickness and flexoelectric effect of the material leads to increase in frequency of vibrations. Moreover, increased nanoshell length and diameter leads to decreased vibration frequency.

Vibrational characteristic of FG porous conical shells using Donnell's shell theory

  • Yan, Kai;Zhang, Yao;Cai, Hao;Tahouneh, Vahid
    • Steel and Composite Structures
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    • v.35 no.2
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    • pp.249-260
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    • 2020
  • The main purpose of this research work is to investigate the free vibration of conical shell structures reinforced by graphene platelets (GPLs) and the elastic properties of the nanocomposite are obtained by employing Halpin-Tsai micromechanics model. To this end, a shell model is developed based on Donnell's theory. To solve the problem, the analytical Galerkin method is employed together with beam mode shapes as weighting functions. Due to importance of boundary conditions upon mechanical behavior of nanostructures, the analysis is carried out for different boundary conditions. The effects of boundary conditions, semi vertex angle, porosity distribution and graphene platelets on the response of conical shell structures are explored. The correctness of the obtained results is checked via comparing with existing data in the literature and good agreement is eventuated. The effectiveness and the accuracy of the present approach have been demonstrated and it is shown that the Donnell's shell theory is efficient, robust and accurate in terms of nanocomposite problems.

Light Efficiency Enhancement Technology of OLED: Fabrication of Random Nano External Light Extraction Composite Layer (OLED의 광 효율 향상 기술: 랜덤 나노 외부 광 추출 복합 층 제작)

  • Choi, Geun Su;Jang, Eun Bi;Seo, Ga Eun;Park, Young Wook
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.3
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    • pp.39-44
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    • 2022
  • The light extraction technology for improving the light efficiency of OLEDs is the core technology for extracting the light inside the OLEDs to the outside. This study demonstrates a simple method to generate random nanostructures (RNSs) containing high refractive index nanoparticles to improve light extraction and viewing angle characteristics. A simple dry low-temperature process makes the nanostructured scattering layer on the polymer resin widely used in the industry. The scattering layer has the shape of randomly distributed nanorods. To control optical properties, we focused on changing the shape and density of RNSs and adjusting the concentration of high refractive index nanoparticles. As a result, the film of the present invention exhibits a perpendicular transmittance of 85% at a wavelength of 550 nm. This film was used as a scattering layer to reduce substrate mode loss and improve EL efficiency in OLEDs.

Nano-delamination monitoring of BFRP nano-pipes of electrical potential change with ANNs

  • Altabey, Wael A.;Noori, Mohammad;Alarjani, Ali;Zhao, Ying
    • Advances in nano research
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    • v.9 no.1
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    • pp.1-13
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    • 2020
  • In this work, the electrical potential (EP) technique with an artificial neural networks (ANNs) for monitoring of nanostructures are used for the first time. This study employs an expert system to identify size and localize hidden nano-delamination (N.Del) inside layers of nano-pipe (N.P) manufactured from Basalt Fiber Reinforced Polymer (BFRP) laminate composite by using low-cost monitoring method of electrical potential (EP) technique with an artificial neural networks (ANNs), which are combined to decrease detection effort to discern N.Del location/size inside the N.P layers, with high accuracy, simple and low-cost. The dielectric properties of the N.P material are measured before and after N.Del introduced using arrays of electrical contacts and the variation in capacitance values, capacitance change and node potential distribution are analyzed. Using these changes in electrical potential due to N.Del, a finite element (FE) simulation model for N.Del location/size detection is generated by ANSYS and MATLAB, which are combined to simulate sensor characteristic, therefore, FE analyses are employed to make sets of data for the learning of the ANNs. The method is applied for the N.Del monitoring, to minimize the number of FE analysis in order to keep the cost and save the time of the assessment to a minimum. The FE results are in excellent agreement with an ANN and the experimental results available in the literature, thus validating the accuracy and reliability of the proposed technique.