• Title/Summary/Keyword: Complex surface

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Synthesis and surface characterization of mesoporous carbon for the adsorption of methane gas (메탄가스 흡착을 위한 메조포러스 카본 합성과 표면 특성 연구)

  • Park, Sang-Won;Lee, Kamp-Du;Noh, Min-Soo
    • Journal of Environmental Science International
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    • v.22 no.7
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    • pp.837-845
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    • 2013
  • This study was designed to synthesize mesoporous carbon, porous carbonic material and to characterize its surface in an attempt to adsorption methane gas($CH_4$). Synthesis of mesoporous carbon was carried out under two steps ; 1. forming a RF-silica complex with a mold using CTMABr, a surfactant, and TEOS, raw material of silica, and 2. eliminating silica through carbonization and HF treatment. The mesoporous carbon was synthesized under various conditions of synthesis time and calcination. Eight different types of mesoporous carbon, which were designated as MC1, MC2, MC3, MC4, MCT1, MCT2, MCT3, and MCT4, were prepared depending upon preparation conditions. The analysis of mesoporous carbon characteristics showed that the calcination of silica stabilized the mixed structure of silica and carbonic complex, and made the particle uniform. The results also showed that hydrothermal synthesis time did not have a strong influence on the size of pore. The bigger specific surface area was obtained as the hydrothermal synthesis time was extended. However, the specific surface area was getting smaller again after a certain period of time. In adsorption experiments, $CH_4$ was used as adsorbate. For the case of $CH_4$, MCT3 showed the highest adsorption efficiency.

Dielectric Insulation Properties of Double Pancake Coil Type HTS Transformer (Double Pancake Coil형 고온초전도 변압기의 전기적 절연 특성)

  • 백승명;정종만;이현수;한철수;김상현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.2
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    • pp.151-156
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    • 2003
  • High temperature superconductor can only be applied against an engineering specofication that has to be determined for each particular application form the design requirements for economic viability and for operation margins in service. However, in order to realize the HTS transformer, it is necessary to establish the high voltage insulation technique in cryogenic temperature. Therefore, the composite insulation of double pancake coil type transformer are described and AC breakdown voltage characteristics of liquid nitrogen(LN$_2$) under HTS pancake coil electrode made by Bi-2223/Ag are studied. The Breakdown of LN$_2$ is dominated electrode shape and distance. The influence of pressure on breakdown voltage is discussed with th different electrode. For the electrical insulation design of turn-to-turn insulation for the HTS transformer, we tested breakdown strength of insulation sheet under varying pressure. And we investigated surface flashover properties of LN$_2$ and complex conition of cryogenic gaseous nitrogen(CGN$_2$) obove a LN$_2$ surface. The surface voltage of GFRP was measured as a function of thickness and electrode distance in LN$_2$ and complex condition of CGN$_2$ above a LN$_2$ surface. this research presented information of electrical insulation design for double pancake coil(DPC) type HTS transformer.

Statistical Analysis of Characteristics of Scanning Electron Microscope (주사전자현미경 특성의 통계적 해석)

  • Kim, T.S.;Kim, W.;Kim, D.H.;Kim, B.
    • Journal of the Korean institute of surface engineering
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    • v.40 no.4
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    • pp.185-189
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    • 2007
  • A scanning electron microscope (SEM) is a complex system, consisting of many sophisticated components. For a systematic characterization, a $2^4$ full factorial experiment was conducted. The SEM components examined include condenser lens 1 and 2 (denoted as A and B, respectively), and Objective lens (coarse and fine-denoted as C and D respectively). A statistical analysis was conduced to investigate factor effects and variations In response surfaces. Among four factors, main effect analysis revealed that A and D were Identified as the dominant factor. Moreover, B showed conflicting effect against C. The $R^2$ of statistical regression model constructed was about 69.6%. The model generated 3D response surface plots facilitated understanding of complex tactor effects.

Sorption of Se(-II) on illite, MX-80 bentonite, shale, and limestone in Na-Ca-Cl solutions

  • Walker, Andrew;Racette, Joshua;Saito, Takumi;Yang, Tammy (Tianxiao);Nagasaki, Shinya
    • Nuclear Engineering and Technology
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    • v.54 no.5
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    • pp.1616-1622
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    • 2022
  • Selenium has been identified as an element of interest for the safety assessment of a deep geological repository (DGR) for used nuclear fuel. In Canada, groundwaters at DGR depths in sedimentary rocks have been observed to have a high ionic strength. This paper examines the sorption behavior of Se(-II) onto illite, MX-80 bentonite, Queenston shale, and argillaceous limestone in Na-Ca-Cl solutions of varying ionic strength (0.1-6 mol/kgw (m)) and across a pH range of 4-9. Little ionic strength dependence for Se(-II) sorption onto all solids was observed except that sorption at high ionic strength (6 m) was generally slightly lower than sorption at low ionic strength (0.1 m). Illite and MX-80 exhibited the expected results for anion sorption, while shale and limestone exhibited more constant sorption across the pH range tested. A non-electrostatic surface complexation model successfully predicted sorption of Se(-II) onto illite and MX-80 using the formation of an inner-sphere surface complex and an outer-sphere surface complex. Optimized values for the formation reactions of these surface species were proposed.

Cladosporium sp. is the Major Causal Agent in the Microbial Complex Associated with the Skin Sooty Dapple Disease of the Asian Pear in Korea

  • Park, Young-Seob;Kim, Ki-Chung;Lee, Jang-Hoon;Cho, Song-Mi;Choi, Yong-Soo;Kim, Young-Cheol
    • The Plant Pathology Journal
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    • v.24 no.2
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    • pp.118-124
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    • 2008
  • Skin sooty dapple disease, a fungal disease that lowers Asian pear fruit quality, has emerged recently in Korea but has not yet been thoroughly characterized. This disease affects the surface of fruit, leaves, and young shoots of the Asian pear, typically appearing as a dark or pale black dapple on the fruit surface. The disease initiates on the fruit with small circular lesions that become bigger, eventually spreading to form large circular or indefinite lesions. Sparse dark or flourishing white-greyish aerial mycelia and appearance of a dark or pale black dapple on the fruit surface are typical signs of this disease. The disease was severe during cold storage of the Niitaka and Chuhwangbae varieties, but more limited on the Gamcheonbae and Hwangkeumbae varieties. To identify causal pathogens, 123 fungal isolates were obtained from lesions. The fungi that caused typical skin sooty dapple disease symptoms in our bioassay were identified. Based on their morphological characteristics, 74% of the isolates were Cladosporium sp. and 5-7 % of the isolates were Leptosphaerulina sp., Tripospermum sp., or Tilletiopsis sp. None of the isolates caused severe soft rot by injection to a wound plug, but some of the Cladosporium sp. isolates caused mild maceration. Therefore this microbiol complex cannot account for the soft rot also observed in stored fruits. The high frequency of isolation of Cladosporium sp. from disease tissues and bioassay on pear fruit surface suggest that Cladosporium sp. could be a major pathogen in the microbial complex associated with skin sooty dapple disease of the Asian pear in Korea.

Heat/Mass Transfer Characteristics on Stationary Turbine Blade and Shroud in a Low Speed Annular Cascade (I) - Near-tip Blade Surface - (환형 캐스케이드 내 고정된 터빈 블레이드 및 슈라우드에서의 열/물질전달 특성 (I) - 블레이드 끝단 인접 표면 -)

  • Rhee Dong-Ho;Cho Hyung Hee
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.4 s.235
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    • pp.485-494
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    • 2005
  • For the extensive investigation of local heat/mass transfer on the near-tip surface of turbine blade, experiments were conducted in a low speed stationary annular cascade. The turbine test section has a single stage composed of sixteen guide vanes and blades. The chord length and the height of the tested blade are 150 mm and about 125 mm, respectively. The blade has flat tip geometry and the mean tip clearance is about $2.5{\%}$ of the blade chord. Detailed mass transfer coefficient on the blade near-tip surface was obtained using a naphthalene sublimation technique. The inlet flow Reynolds number based on chord length and incoming flow velocity is changed from $1.0{\times}10^{5}\;to\;2.3{\times}10^{5}.$ Extremely complex heat transfer characteristics are observed on the blade surface due, to complicated flow patterns, such as flow acceleration, laminarization, transition, separation bubble and tip leakage flow. Especially, the suction side surface of the blade has higher heat/mass transfer coefficients and more complex distribution than the pressure side surface, which is related to the leakage flow. For all the tested Reynolds numbers, the heat/mass transfer characteristics on the turbine blade are the similar. The overall averaged $Sh_{c}$ values are proportional to $Re_{c}^{0.5}$ on the stagnation region and the laminar flow region such as the pressure side surface. However, since the flow is fully turbulent in the near-tip region, the heat/mass transfer coefficients are proportional to $Re_{c}^{0.8}.$

Analysis on the free surface flow induced by a pair of source-sink in Stokes flow (스톡스 유동장 내의 한 쌍의 소오스-싱크에 의한 자유표면 유동해석)

  • Jeong, Jae-Tack;Park, Jong-Sun
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.304-307
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    • 2008
  • Two-dimensional Stokes flow due to the line source and line sink of same strength in semi-infinite flow region with free surface is analysed using complex variable theory and conformal mapping. Surface tension effects are included while gravity is neglected. From the results of analysis, flow pattern and free surface shape are obtained and velocity distribution on the free surface is determined with 2 independent parameters Ca (capillary number) and h (non-dimensionalized distance between source and sink). When the location of the sink is above the source, velocity on the free surface converges and a cusp occurs on the free surface for the value of Ca above some critical capillary number.

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A Study on Tool Path Generation for Machining Impellers with 5-Axis Machining Center (5축 Machining Center를 이용한 임펠러 가공을 위한 공구경로 생성에 관한 연구)

  • 장동규;조환영;이희관;공영식;양균의
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.3
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    • pp.83-90
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    • 2004
  • This paper proposes a tool path generation method for machining impellers with 5-axis machining center. The shape of impeller is complex, being composed of pressure surface, suction surface and leading edge, and so on. The compound surface which is made of ruled surface such as pressure surface and suction surface and leading edge such as fillet surface, makes the tool path generation much complicated. To achieve efficient roughing, cutting area is divided into two region and then tool radius of maximum size that do not cause tool intereference is selected for shortening machining time. In finishing, accuracy is improved using side cutting for blade surface and point milling for leading edge.

Cadmium Detoxification Mechanism in Klebsiella aerogenes ATCC 10031 (Klebsiella aerogenes ATCC 10031의 카드뮴 해독기작)

  • 이기성;유순애;곽인영;박영식;최영길
    • Korean Journal of Microbiology
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    • v.28 no.2
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    • pp.134-144
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    • 1990
  • In order to examine that what kind of system correlated with cadmium detoxification mechanism in Klebsiella aerogenes ATCC 10031, we tried to investigate the effect of phosphate upon the detoxification and also elucidate whether the cadmium phosphate and/or polymeric Cd-Pi complex is formed actually in cell or not. As the results, it was shown that growing pattern had long lag adaptive phase of 12 hr to 24 hr, at the concentrations of 0.02 mM and 0.08 mM cadmium, respectively. Cadmium was accumulated more highly in the fraction of cell wall and membrane than in those of cytoplasm. In case of phosphate starving cells added cadmium, inorganic polyphosphate system was primarily correlated with Cd-detoxification during the lag phase for the accommodation to cadmium, on the other hand, Cd:Sulfide complex system secondarily correlated it during the stationary phase. These results implied that polyphosphate system and Cd:sulfide complex system, these two systems were operated compensatively each other. Considering the results obsdrved with EM and examined tha changes of sulfide and polyphosphate amount, it was reflected that Cd:S complex was located at the cell surface. In the results of $in-vivo^{31}$P NMR spectra in the cells with cadmium pressure, several phosphate signals arose newly from the polyphosphate region with moving chemical shift of it. This phinomenon strongly implied the actual existence of Dd:Pi comples and /or Cd:poly-P complex in the cell and also the cellular compartmentalization of cadmium detoxifying mechanism.

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A Study on the correction of production related problems in stainless steel rolling stocks (스테인레스강 차체의 제작 관련 문제 및 대책에 관한 연구)

  • Seo, Sung-Il
    • Proceedings of the KSR Conference
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    • 2004.06a
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    • pp.826-831
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    • 2004
  • In this study. problems caused during production process of stainless steel carbody are investigated and solutions are found out. Roll forming process to make complex shape is introduced and surface crack on high strength stainless steel plate is investigated. Also, surface indentation is discussed and the effect of welding condition is clarified. Insulated tip to reduce the indentation is recommended for improvement of surface smoothness. Lastly. corrosion of welded joint is discussed and the effects of material, stress and environment are investigated.

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