• Title/Summary/Keyword: Complex cavity

Search Result 232, Processing Time 0.027 seconds

Tooth-colored Restorative Resin Composites (임상가를 위한 특집 2 - 심미수복용 레진)

  • Kwon, Tae-Yub
    • The Journal of the Korean dental association
    • /
    • v.51 no.1
    • /
    • pp.12-17
    • /
    • 2013
  • Curing methods for denial resin-based materials are limited because of the need to polymerize quickly in the oral cavity at an ambient temperature. At present, most dental restorative composites use a camphorquinone-amine complex initiation, visible light-cure, one-component systems. Clinically, it is important to try to optimize the degree of conversion of res in composites using proper manipulation and adequate light-curing techniques to ensure the best outcome.

Solubilization by $\beta$-Cyclodextrin: A Fluorescence Quenching Study

  • Panda, M.;Mishra, A.K.
    • Journal of Photoscience
    • /
    • v.9 no.3
    • /
    • pp.75-79
    • /
    • 2002
  • Solubility of carbon tetrachloride ($CCl_4$) in water increases appreciably in presence of $\beta$-cyclodextrin ($\beta$CD). $CCl_4$ is a very good quencher of 1-naphthol (1ROH) fluorescence. By studying the quenching of fluorescence of 1ROH included in $\beta$CD cavity, it was found that there is an increase in the availability of $CCl_4$ around $\beta$CD in the aqueous medium. This could help to rationalize the enhanced solubility of $CCl_4$.

  • PDF

Development of Sleeve Parts for Continuous Hot Zinc Plating Roll Applied to Wear-Resistant Alloy Cast Steel

  • Park, Dong-Hwan;Hong, Jin-Tae;Kwon, Hyuk-Hong
    • Journal of the Korean Society of Manufacturing Technology Engineers
    • /
    • v.26 no.4
    • /
    • pp.357-364
    • /
    • 2017
  • Metal casting is a process in which molten metal or liquid metal is poured into a mold made of sand, metal, or ceramic. The mold contains a cavity of the desired shape to form geometrically complex parts. The casting process is used to create complex shapes that are difficult to make using conventional manufacturing practices. For the optimal casting process design of sleeve parts, various analyses were performed in this study using commercial finite element analysis software. The simulation was focused on the behaviors of molten metal during the mold filling and solidification stages for the precision and sand casting products. This study developed high-life sleeve parts for the sink roll of continuous hot-dip galvanizing equipment by applying a wear-resistant alloy casting process.

A Study on Combustion Characteristics in a Low-Pollutant Municipal Waste Incinerator - Development and Validation of a Multi-Block Simulation Code - (저공해 도시 쓰레기 소각로의 연소특성 연구 - 다중블럭 해석 프로그램의 개발 및 검증 -)

  • Sohn, Young-Min;Kim, Man-young;Baek, Seung-Wook
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.27 no.4
    • /
    • pp.534-541
    • /
    • 2003
  • To investigate the combustion characteristics in a low-pollutant municipal waste incinerator, the generalized multi-block simulation code that can be applied to turbulent reacting flow with gaseous hydrocarbon fuel in a 3D complex geometry has been developed with nongray radiation effects. To deal with the complex geometry, structured multi-block method and the scheme which treats interfaces implicitly are adopted. The developed code is validated through various engineering problems such as curved duct flow, driven cavity flow, gray multi-block radiation, nongray radiation. and combustion in a incinerator.

Oral and Oropharyngeal Reconstruction with a Free Flap

  • Jeong, Woo Shik;Oh, Tae Suk
    • Archives of Craniofacial Surgery
    • /
    • v.17 no.2
    • /
    • pp.45-50
    • /
    • 2016
  • Extensive surgical resection of the aerodigestive track can result in a large and complex defect of the oropharynx, which represents a significant reconstructive challenge for the plastic surgery. Development of microsurgical techniques has allowed for free flap reconstruction of oropharyngeal defects, with superior outcomes as well as decreases in postoperative complications. The reconstructive goals for oral and oropharyngeal defects are to restore the anatomy, to maintain continuity of the intraoral surface and oropharynx, to protect vital structures such as carotid arteries, to cover exposed portions of internal organs in preparation for adjuvant radiation, and to preserve complex functions of the oral cavity and oropharynx. Oral and oropharyngeal cancers should be treated with consideration of functional recovery. Multidisciplinary treatment strategies are necessary for maximizing disease control and preserving the natural form and function of the oropharynx.

입계기공의 확산성장 모델을 이용한 고온 기기의 크립균열전파 해석 (2)

  • Jeon, Jae-Young
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.20 no.4
    • /
    • pp.1186-1193
    • /
    • 1996
  • The analytic solution of the stress field at creep crack in the presence of grain boundary caviation is to be obtained by solving the governing equation which was derived through the previous paper. The complex integral technique is used to slove the singular integral equation. under the help of the information about stress behaviors at the ends of integral region know by numerical solution. The resultant stress disstribution obtained shows the relaxed crack-tip singularity of $r^{1/2+\theta}$ due to the intervention of cavitation effect, otherwise, it should assumed to be $r^{1/2}$ singularity of linear elastic fracture mechanics with no cavitation.

Microwave Absorbing Properties of Grid-type Magnetic Composites (격자형 자성 복합재의 전파흡수 특성)

  • Park, Myung-Joon;Kim, Sung-Soo
    • Korean Journal of Metals and Materials
    • /
    • v.50 no.5
    • /
    • pp.389-393
    • /
    • 2012
  • Improvement in microwave absorbance has been investigated by insertion of a periodic air cavity in rubber composites filled with magnetic powders. A mixture of $Co_2Z$ hexagonal ferrite and Fe powders were used as the absorbent fillers in silicone rubber matrix. The complex permeability and complex permittivity of the magnetic composites were measured by reflection/transmission technique. In the grid-type magnetic absorbers, the equivalent permeability (${\mu}_{eq}$) and permittivity (${\varepsilon}_{eq}$) are calculated as a function of air volume rate (K) on the basis of effective medium theory. Reduction in the material parameters (especially, dielectric permittivity and magnetic loss) has been estimated with the increase of K. Plotting the ${\mu}_{eq}$ and ${\varepsilon}_{eq}$ on the solution map of wave-impedance matching, wide bandwidth microwave absorbance has been predicted in the magnetic composites with an optimum value of K.

The Crystal Structure of Dehydrated Fully $Ag^+$-Exchanged Zeolite A Successively Treated with Ethylene and Bromine Vapor

  • Jeong, Mi-Suk;Jang, Se-Bok;Kim, Yang
    • Bulletin of the Korean Chemical Society
    • /
    • v.15 no.11
    • /
    • pp.940-944
    • /
    • 1994
  • The crystal structure of an ethylene sorption complex of dehydrated $Ag_{12}-A $reacted with bromine vapor has determined by single-crystal X-ray diffraction techniques in the cubic space group of Pm3m at 22(l)$^{\circ}$C (a=12.180(2) ${\AA}$). The crystal was prepared by dehydration of $Ag_{12}$-A at 400 $^{\circ}$C and $2 {\times} l0^{-6}$ Torr for 2 days, followed by exposure to 200 Torr of ethylene gas at 24(l) $^{\circ}$C for 1 hr. After the ethylene gas was evacuated for 1 hr, the crystal was exposed to 180 Torr of bromine vapor at 24(l) $^{\circ}$C for 1.5 h. The structure was refined to the final error indices, $R_1=0.066\;and\;R_2$ (weighted)=0.055, using 137 independent reflections for which I>3${\sigma}$I. About 55% of the sodalite unit contain two 6-ring $Ag^+$ ions and the remaining 45% contain $Ag_6$ molecules complexed to 2 $Ag^+$ ions at 6-ring sites to give $(Ag^+)_2(Ag_6).$ Upon sorption of ethylene, 4.75 ethylene molecules were sorbed per unit cell and of these, only 1.25 ethylene molecules were brominated by treatment of dibromine because of the limitation of the available space for the reaction products in the large cavity. In the large cavity, each of 3.5 $Ag^+$ ions forms a lateral ${\pi}$ complex with an ethylene molecule. About 2.5 8-ring $Ag^+$ ions per unit cell interact with 1.25 1,2-dibromoethane and each of ca. 1.25 6-ring $Ag^+$ ions also interacts with one of bromine atoms of 1,2-dibromoethane. Each bromine atom approaches a carbon atom with C-Br(l)=2.07(20) ${\AA}$ and C-Br(2)=2.07(10) ${\AA}$, respectively.

Crystal Structure of a Benzene Sorption Complex of Dehydrated Fully $Cd^{2+}$-Exchanged Zeolite X

  • 김양;염영훈;최은영;김안나;한영욱
    • Bulletin of the Korean Chemical Society
    • /
    • v.19 no.11
    • /
    • pp.1222-1227
    • /
    • 1998
  • The crystal structure of a benzene sorption complex of fully dehydrated Cd2+-exchanged zeolite X, Cd46Si100Al92O384·43C6H6 (a=24.880(6) Å), has been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd3 at 21 ℃. The crystal was prepared by ion exchange in a flowing stream of 0.05 M aqueous Cd(NO3)2 for 3 d, followed by dehydration at 400 ℃ and 2 x 10-6 Torr for 2 d, followed by exposure to about 92 Torr of benzene vapor at 22 ℃. The structure was determined in this atmosphere and refined to the final error indices R1=0.054 and Rw=0.066 with 561 reflections for which I > 3σ(I). In this structure, Cd2+ ions are found at four crystallographic sites: eleven Cd2+ ions are at site 1, at the centers of the double six-oxygen rings; six Cd2+ ions lie at site I', in the sodalite cavity opposite to the double six-oxygen rings; and the remaining 29 Cd2+ ions are found at two nonequivalent threefold axes of unit cell, sites Ⅱ' (in the sodalite cavity ) and site Ⅱ (in the supercage) with occupancies of 2 and 27 ions, respectively. Each of these Cd2+ ions coordinates to three framework oxylkens, either at 2.173(13) or 2.224(10) Å, respectively, and extends 0.37 Å into the sodalite unit or 0.60 Å into the supercage from the plane of the three oxygens to which it is bound. The benzene molecules are found at two distinct sites within the supercages. Twenty-seven benzenes lie on threefold axes in the large cavities where they interact facially with the latter 27 site-Ⅱ Cd2+ ions (Cd2+-benzene center=2.72 Å; occupancy=27 molecules/32 sites). The remaining sixteen benzene molecules are found in 12ring planes; occupancy=16 molecules/16 sites. Each hydrogen of these sixteen benzenes is ca. 2.8/3.0 Å from three 12-ring oxygens where each is stabilized by multiple weak electrostatic and van der Waals interactions with framework oxygens.

Simulated Annealing for Overcoming Data Imbalance in Mold Injection Process (사출성형공정에서 데이터의 불균형 해소를 위한 담금질모사)

  • Dongju Lee
    • Journal of Korean Society of Industrial and Systems Engineering
    • /
    • v.45 no.4
    • /
    • pp.233-239
    • /
    • 2022
  • The injection molding process is a process in which thermoplastic resin is heated and made into a fluid state, injected under pressure into the cavity of a mold, and then cooled in the mold to produce a product identical to the shape of the cavity of the mold. It is a process that enables mass production and complex shapes, and various factors such as resin temperature, mold temperature, injection speed, and pressure affect product quality. In the data collected at the manufacturing site, there is a lot of data related to good products, but there is little data related to defective products, resulting in serious data imbalance. In order to efficiently solve this data imbalance, undersampling, oversampling, and composite sampling are usally applied. In this study, oversampling techniques such as random oversampling (ROS), minority class oversampling (SMOTE), ADASYN(Adaptive Synthetic Sampling), etc., which amplify data of the minority class by the majority class, and complex sampling using both undersampling and oversampling, are applied. For composite sampling, SMOTE+ENN and SMOTE+Tomek were used. Artificial neural network techniques is used to predict product quality. Especially, MLP and RNN are applied as artificial neural network techniques, and optimization of various parameters for MLP and RNN is required. In this study, we proposed an SA technique that optimizes the choice of the sampling method, the ratio of minority classes for sampling method, the batch size and the number of hidden layer units for parameters of MLP and RNN. The existing sampling methods and the proposed SA method were compared using accuracy, precision, recall, and F1 Score to prove the superiority of the proposed method.