• Title/Summary/Keyword: Complex I

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A NOTE ON LINEAR COMBINATIONS OF AN IDEMPOTENT MATRIX AND A TRIPOTENT MATRIX

  • Yao, Hongmei;Sun, Yanling;Xu, Chuang;Bu, Changjiang
    • Journal of applied mathematics & informatics
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    • v.27 no.5_6
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    • pp.1493-1499
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    • 2009
  • Let $A_1$ and $A_2$ be nonzero complex idempotent and tripotent matrix, respectively. Denote a linear combination of the two matrices by A = $c_1A_1$ + $c_2A_2$, where $c_1,\;c_2$ are nonzero complex scalars. In this paper, under an assumption of $A_1A_2$ = $A_2A_1$, we characterize all situations in which the linear combination is tripotent. A statistical interpretation of this tripotent problem is also pointed out. Moreover, In [2], Baksalary characterized all situations in which the above linear combination is idem-potent by using the property of decomposition of a tripotent matrix, i.e. if $A_2$ is tripotent, then $A_2$ = $B_1-B_2$, where $B^2_i=B_i$, i = 1, 2 and $B_1B_2=B_2B_1=0$. While in this paper, by utilizing a method different from the one used by Baksalary in [2], we prove the theorem 1 in [2] again.

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Preparation and Structure of $[Ni(L)]I_2$ (L:3,5,10,12-Tetramethyl-1,4,8,11-tetraazacyclotetradecane) ($[Ni(L)]I_2$ (L:3,5,10,12-Tetramethyl-1,4,8,11-tetraazacyclo-tetradecane) 합작물의 합성 및 구조)

  • 최기영;김동원
    • Korean Journal of Crystallography
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    • v.8 no.2
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    • pp.119-123
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    • 1997
  • The complex [Ni(L)]I2 (1) (L:3,5,10,12-Tetramethly-1,4,8,11-tetraazacyclotetradecane) has been prepared and characterized by X-ray diffraction methods. The complex 1 crystallized in the orthorhombic system, space group Pcab with cell parameters a=13.293(1) Å, b=28.550(7) Å, c=10.804(1) Å, z=8. Least-squares refinement of 1 led to a R(Rw) factor of 0.043 (0.046) for 1851 observed reflections of Fo>3o (Fo). The crystal structure of 1 has a slightly distorted square-planar geometry and adopts the trans-III conformation.

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Li+ and Li+I-Li+ ions Solvated by 1,4-dioxane: An ion Mobility Spectrometry-Mass Spectrometry Study

  • Choi, Yunseop;Ji, Inyong;Seo, Jongcheol
    • Mass Spectrometry Letters
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    • v.12 no.4
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    • pp.152-158
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    • 2021
  • Electrospray ionization (ESI) and ion mobility spectrometry-mass spectrometry (IMS-MS) were employed to investigate the solvated structures of ionic species in the lithium iodide electrolyte solution in the gas phase. The Li+I-Li+ triple ion and single standalone Li+ ions solvated by 1,4-dioxane were successfully generated and observed by ESI-MS under the influence of dioxane vapor at the inlet region. Under the present experimental condition, (1,4-dioxane)m·Li+ complex ions (m = 1, 2, and 3) and a (1,4-dioxane)·Li+I-Li+ complex ion were observed, which were further examined by IMS to investigate their structures. The presence of multiple structural isomers was confirmed, which accounts for the endothermic conformational transition of 1,4-dioxane from a chair to a boat to achieve bidentate O-donor binding to Li+ and Li+I-Li+. Further structural details critical for the ion-solvent interactions were also examined and discussed with the help of density functional theory calculations.

Macrocyclic Isomers with S2O-Donor Set as Silver(I) Ionophores

  • Park, Sung-Bae;Yoon, Il;Seo, Joo-beom;Kim, Hyun-Jee;Kim, Jae-Sang;Lee, Shim-Sung
    • Bulletin of the Korean Chemical Society
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    • v.27 no.5
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    • pp.713-717
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    • 2006
  • $S_2O$-donor macrocyclic isomers incorporating a xylyl group in o- ($L^1$), m- ($L^2$) and p-positions ($L^3$) extract no metal ions except silver(I) from aqueous to chloroform phase. And the magnitudes of %Ex for silver(I) are in the order of $L^1$ > $L^2$ > $L^3$. Taking this result into account, $L^1$-$L^3$ were utilized as membrane active components to prepare potentiometric silver(I)-selective electrodes. The proposed macrocycles-based electrodes E1 ($L^1$), E2 ($L^2$) and E3 ($L^3$) exhibited comparable results which show considerable selectivity toward silver(I) over alkali, alkali earth and other transition metal ions. Comparative NMR study on $L^1$-$L^3$ and their complexes with silver(I) in solution was also accomplished. In addition, a unique sandwich-type complex $[Ag(L^1)_2]CIO_4$ was prepared from the assembly reaction of $L^1$ with $AgClO_4$ and structurally characterized by an X-ray diffraction analysis.

Preparation and crystal structure of azido bridged one-dimensional polymeric cadmium(II) complex, [Cd(N3)2(2-ethylimidazole)2]

  • Suh, Seung Wook;Kim, Inn Hoe;Kim, Chong-Hyeak
    • Analytical Science and Technology
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    • v.18 no.5
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    • pp.391-395
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    • 2005
  • The title complex, $[Cd(N_3)_2(2-ethylimidazole)_2]$, I, has been prepared and characterized by X-ray single crystallography. The complex I crystallizes in the monoclinic system, Cc space group with a = 16.200(3), b = 12.926(3), $c=7.007(1){\AA}$, ${\beta}=102.29(3)^{\circ}$, $V=1433.7(5){\AA}^3$, Z = 4, $R_1=0.0239$ and ${\omega}R_2=0.0604$ for 1874 independent reflections. Cd(II) atom has a slightly distorted octahedral coordination geometry, with four end-on (${\mu}-1$,1) bridging azido ligands and two 2-ethylimidazole ligands bonding through nitrogen atom. The central cadmium(II) atoms are run in parallel to the c-axis and are doubly bridged with neighboring cadmium(II) atoms by the end-on (${\mu}-1$,1) bridging azido ligands. Thus, this complex has a one-dimensional zigzag chain structure in which the 2-ethylimidazole is in the cis conformation.

The Runoff Characteristics of Non-point Pollution Sources in Industrial Complex(I): Focusing on the analysis of runoff water according to the initial rainfall of the C Industrial Complex (산업단지 비점오염원의 유출특성(I): C산업단지의 초기강우에 따른 유출수 분석을 중심으로)

  • Woo, Jae-Suk;Shin, Hyun-Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.30 no.1
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    • pp.23-32
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    • 2022
  • In this study, rainfall water outlet water quality monitoring was performed on the C industrial complex to evaluate the characteristics of non-point pollutant runoff from the industrial complex during rainfall and to use it as basic data for calculating the load and unit of non-point pollutant. As a result of the IETD analysis, it was selected as a representative rainfall event for simulating non-point pollutants when the rainfall duration was about 21 hours and the rainfall was 26.44mm. Also as a result of monitoring the flow and water quality survey, the first rainfall was 12.2 mm, the rainfall duration was 12 hr, the number of preceding dry days was 3 days, the second rainfall was 22.1 mm, the rainfall duration was 12 hr, and the number of preceding dry days was 7 days.

COMMON FIXED POINT THEOREMS FOR TWO MAPPINGS WITH ψ-ϕ-CONTRACTIVE OR EXPANSIVE TYPE CONDITIONS ON COMPLEX-VALUED METRIC SPACES

  • JIN, HAI-LAN;PIAO, YONG-JIE
    • Journal of the Chungcheong Mathematical Society
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    • v.28 no.3
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    • pp.451-463
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    • 2015
  • A continuous and non-decreasing function ${\psi}$ and another continuous function ${\phi}$ with ${\phi}(z)=0{\Leftrightarrow}z=0$ defined on $\mathbb{C}^+=\{x+yi:x,y{\geq}0\}$ are introduced, the ${\psi}-{\phi}$-contractive or expansive type conditions are considered, and the existence theorems of common fixed points for two mappings defined on a complex valued metric space are obtained. Also, Banach contraction principle and a fixed point theorem for a I-expansive type mapping are given on complex valued metric spaces.

Effects of Light on Disassembly of Chloroplast during Senescence of Detached Leaves in Phaseolus vulgaris

  • Dong-Hee Lee;Jun
    • Journal of Environmental Science International
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    • v.1 no.2
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    • pp.69-80
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    • 1992
  • Effects of light on leaf senescence of Phseolus vulgaris were investigated by measuring the disassembly of chlorophyll-protein complexes in detached leaves which had been kept in the dark or under light. The loss of chlorophyll accompanied by degradation of chlorophyll- protein complexes. PSI (photosystem I) complex containing LHCI (light harvesting complex of PSI) apoproteins was rapidly decreased after the early stage of dark-induced senescence. RC(reaction center)-Cores was slightly increased until 4 d and slowly decreased thereafter. As disassembly of LHCII trimer progressed after the late stage of senescence, there was a steady increase in the relative amount of SC(small complex)-2 containing LHCII monomer. On the other hand, white and red light adaptation caused the structural stability of chlorophyll-protein complexes during dark-induced senescence. Particularly, red light was more effective in the retardation of LHCII breakdown than white light, whereas white light was slightly effect in protecting the disassembly of PSI complex compared to red light. These results suggest, therefore, that light may be a regulatory factor for stability of chlorophyll-protein complexes in the senescent leaves.

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Simons' Type Formula for Kaehlerian Slant Submanifolds in Complex Space Forms

  • Siddiqui, Aliya Naaz;Shahid, Mohammad Hasan;Jamali, Mohammed
    • Kyungpook Mathematical Journal
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    • v.58 no.1
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    • pp.149-165
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    • 2018
  • A. Bejancu [2] was the first who instigated the new concept in differential geometry, i.e., CR-submanifolds. On the other hand, CR-submanifolds were generalized by B. Y. Chen [7] as slant submanifolds. Further, he gave the notion of a Kaehlerian slant submanifold as a proper slant submanifold. This article has two objectives. For the first objective, we derive Simons' type formula for a minimal Kaehlerian slant submanifold in a complex space form. Then, by applying this formula, we give a complete classification of a minimal Kaehlerian slant submanifold in a complex space form and also obtain its some immediate consequences. The second objective is to prove some results about semi-parallel submanifolds.

Planning Guidelines for Outdoor Space in the Apartment Complex by Investigating Usage Behavior (이용행태조사를 통한 아파트 외부공간 계획방안에 관한 연구)

  • 김정례;박희진
    • Journal of the Korean housing association
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    • v.12 no.3
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    • pp.1-12
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    • 2001
  • The purpose of this study was to investigate the outdoor space of the recent built apartment complex in Ulsan and to provide the basic information for planning and apartment outdoor space. Multiple methods were utilized such as questionnaire, observation, behavior-mapping, and photography. The sample consisted of 382 residents living in four apartment complex in Ulsan. data were analyzed by frequency and percentage using SPSS PC+. The observation was performed in seven outdoor space, i.e., green area, road area, exercise area, play area, parking area, and approach area. According to the findings of this study, residents did not actively involve in outdoor activities and seldom use the outdoor space. Various changes and erosions were observed as a trace, especially near fence and grass area because of unplanned location of entrances. Finally this study suggested several planning guidelines for outdoor space in apartment complex.

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