• Title/Summary/Keyword: Complex I

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Synthesis of (N-docosyl Pyridinium)-TCNQ (1:1) complex and Fabrication of Langmuir-Blodgett Ultra Thin Films ((N-docosyl pyridinium)-TCNQ(1 : 1) 착체의 합성과 Langmur-Blodgett 초박막 제작)

  • Sohn, Byoung-Chung;Jeong, Soon-Wook
    • Journal of the Korean Applied Science and Technology
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    • v.6 no.2
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    • pp.39-44
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    • 1989
  • (N-docosyl pyridinium)-TCNQ(1:1) complex was synthesized by reacting N-docosyl pyridinium bromide and LiTCNQ. This complex was investigated and confirmed by elemental analysis. U.V, I.R spectra. A stability to the dispersion solvent, which is acetonitrile, dichloromethane, benzene, chloroform and acetonitrile-benzene (1:1, V/V) of (N-docosyl pyridinium)-TCNQ(1:1) complex was investigated by U. V spectrophotometer and was confirmed stabilized on acetonitrile, benzene and acetonitrile-benzene(1:1'V/V) for 7 hours. Using ultra pure water as subphase for L-B film deposition, the Y-type L-B film of (N-docosyl pyridinium)-TCNQ(1:1) complex was farbricated. The electrical conductivities on a perpendicular direction of the L-B film were measured to be $5{\times}10^{-5}{\sim}5{\times}10^{-14}$S/cm according to the number of layer.

Studies on 1-Isonicotinoyl-2-furfurylidene hydrazine-Cu(II) Complex Compound. (1-Isonicotinoyl-2-furfurylidene Hydrazine-Cu(II) 착화합물에 관한 분석화학적연구)

  • 백남호;최윤수
    • YAKHAK HOEJI
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    • v.9 no.1_2
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    • pp.18-22
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    • 1965
  • A new organic reagent, 1-isonicotinoyl-2-furfurylidene hydrazine was synthesized from isonicotinic acid hydrazide and furfural, gives precipitate with copper(II), mercury(II) and argent(I), whereas, it gives a water soluble yellow complex with iron(III). Copper complex of the reagent is soluble in EtOH MtOH, pyridine, dioxane and dimethylformamide with green yellow coloration. The complex has a maximum absorption at 385 m.$\mu$ and molar ratio of copper; reagent was estimated as 1:1 by continuous variation method, slop method and chelate titration method. Molar extinction coefficient (9600) and apparant formation constant of this complex was spectrophotometrically determined. K=1.7 * $10^{7}$ (Babko's method) K=2.1 * $10^{7}$ (Anderson's method). This reagent reacted with copper so sensitive that it would be available for determination of Cu (II).

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A Study on the Planning Factor Evaluation of Environmental Friendiness by Apartment Residents (공동주택단지 거주자의 환경친화 계획요소 평가에 관한 연구)

  • Kim, Ick-Hwan
    • Journal of the Korean Society of Industry Convergence
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    • v.10 no.1
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    • pp.55-63
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    • 2007
  • The purpose of this study is to extract the main planning factors of environment friendly apartment complex through the residents' evaluations on importance levels of the planning factors. The major findings of this study are as follows; 1) Understanding on the environment friendly apartment complex is lacking, and the satisfaction level on the living space as the environment friendly apartment is very low. 2) The residents in the low-storied apartments want the introduction of facilities for energy saving, and those in the high-storied apartments demand to develop to green area. 3) In evaluating the importance of the environment friendly planning factors and the image of the apartment complex, the guarantee of green area and the development of water friendly space are closely related with the image of the apartment complex. So, they are the planning factors that should be handled importantly.

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Complex Planetary Gear Train for a Plug type Passenger Door (복합유성기어장치를 적용한 플러그 방식 출입문의 변속장치)

  • 김연수;홍재성;박성혁;백남욱;이병송
    • Proceedings of the KSR Conference
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    • 2001.05a
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    • pp.170-177
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    • 2001
  • Since plug type passenger door has two motion modes, power transmission unit must be capable of plug-in or plug-out, and sliding mode. Complex planetary gear train is proposed, which is composed of two 2K-H, I type planetary gear units. For the proposed complex planetary gear train, ranges of addendum modification coefficients which would not lead to interferences is analyzed, and optimal addendum modification coefficients among these ranges which generate the maximum efficiency are presented. Based on the interference, efficiency and torque ratio analysis results, complex planetary new train is designed and manufactured.

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Development on a Transmission Unit for a Plug Type Passenger Door (플러그 방식 승객용 출입문의 변속장치 개발)

  • 김연수;홍재성;박성혁;이관섭;백영남
    • Journal of the Korean Society for Railway
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    • v.4 no.2
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    • pp.55-61
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    • 2001
  • Since the plug type passenger door has two modes of motion, a power transmission unit must be capable of plug-in or plug-out mode, and sliding mode. Complex planetary gear train is proposed, which is composed of two 2K-H, I type planetary gear units. For the proposed complex planetary gear train, ranges of addendum modification coefficients which would not lead to interferences are analyzed, and optimal addendum modification coefficients among these ranges which generate the maximum efficiency are presented. Based on the results of analysis on interferences, efficiencies and torque ratios, the specifications for the complex planetary gear train were determined. It has been shown by tests of the complex planetary gear train manufactured that the gear train worked well with good agreements of analysis.

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HOLONOMY DISPLACEMENTS IN THE HOPF BUNDLES OVER $\mathcal{C}$Hn AND THE COMPLEX HEISENBERG GROUPS

  • Choi, Young-Gi;Lee, Kyung-Bai
    • Journal of the Korean Mathematical Society
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    • v.49 no.4
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    • pp.733-743
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    • 2012
  • For the "Hopf bundle" $S^1{\rightarrow}S^{2n,1}{\rightarrow}\mathbb{C}H^n$, horizontal lifts of simple closed curves are studied. Let ${\gamma}$ be a piecewise smooth, simple closed curve on a complete totally geodesic surface $S$ in the base space. Then the holonomy displacement along ${\gamma}$ is given by $$V({\gamma})=e^{{\lambda}A({\gamma})i}$$ where $A({\gamma})$ is the area of the region on the surface $S$ surrounded by ${\gamma}$; ${\lambda}=1/2$ or 0 depending on whether $S$ is a complex submanifold or not. We also carry out a similar investigation for the complex Heisenberg group $\mathbb{R}{\rightarrow}\mathcal{H}^{2n+1}{\rightarrow}\mathbb{C}^n$.

Genomic Species Identification of Acinetobacter calcoaceticus - Acinetobacter baumannii Complex Strains by Amplified Ribosomal DNA Restriction Analysis (ARDRA) (Amplified Ribosomal DNA Restriction Analysis (ARDRA) 방법을 이용한 국내 분리 Acinetobacter calcoaceticus - Acinetobacter baumannii Complex 균주의 유전자종 동정)

  • Oh, Jae-Young;Cho, Jae-We;Park, Jong-Chun;Lee, Je-Chul
    • The Journal of the Korean Society for Microbiology
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    • v.35 no.1
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    • pp.69-76
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    • 2000
  • Members of the genus Acinetobacter are recognized as newer pathogens of the nosocomial infection with an increasing frequency in recent years. Strains that belonged to A. calcoaceticus A. baumannii complex (genomic species 1, 2, 3, and 13TU) were major groups associated with nosocomial infection. Phenotypic identification was unreliable and laborious method to classify Acinetobacter strains into 19 genomic species. Rapid and reliable identification of clinical isolates is essential to diagnosis and epidemiology of Acinetobacter. We investigated the suitability of amplified ribosomal DNA restriction analysis (ARDRA) to identify genomic species of 131 Acinetobacter isolates. The 16S rRNA genes (ribosomal DNA) were enzymatically amplified and the amplified PCR products were restricted independently with the enzymes, AluI, CfoI, and MboI. Genomic species of Acinetobacter was classified by the combinations of restriction patterns. The analysis was showed that restriction profiles were characteristic for each genomic species. One hundred fourteen isolates were identified as A. baumannii, twelve were identified as genomic species 13TU, and one was identified as genomic species 3. Four isolates were found to be unknown organisms. All of the isolates which were identified to A. baumannii by phenotypic tests were completely discriminated into A. baumannii and genomic species 13TU by ARDRA. This study demonstrates that ARDRA is a rapid and simple techniques for the identification of Acinetobacter species according to the genomic species.

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Crystallization and Preliminary X-Ray Crystallographic Analysis of UDP-N-Acetylglucosamine Enolpyruvyl Transferase from Haemophilus influenzae in Complex with UDP-N-Acetylglucosamine and Fosfomycin

  • Yoon, Hye-Jin;Ku, Min-Je;Ahn, Hyung Jun;Lee, Byung Il;Mikami, Bunzo;Suh, Se Won
    • Molecules and Cells
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    • v.19 no.3
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    • pp.398-401
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    • 2005
  • The bacterial enzyme UDP-N-acetylglucosamine enolpyruvyl transferase catalyzes the first committed step of peptidoglycan biosynthesis, i.e., transfer of enolpyruvate from phosphoenolpyruvate to UDP-N-acetyl-glucosamine. We have overexpressed the enzyme from Haemophilus influenzae in Escherichia coli and crystallized it in the apo-form, as well as in a complex with UDP-N-acetylglucosamine and fosfomycin using ammonium sulfate as the precipitant. X-ray diffraction data from a crystal of the apo-form were collected to $2.8{\AA}$ resolution at 293 K. The crystal quality was improved by co-crystallization with UDP-N-acetylglucosamine and fosfomycin. X-ray data to $2.2{\AA}$ have been collected at 100 K from a flash-frozen crystal of the complex. The complex crystals belong to the orthorhombic space group I222 (or $I2_12_12_1$) with unit-cell parameters of a = 63.7, b = 124.5, and $c=126.3{\AA}$. Assuming a monomer of the recombinant enzyme in the crystallographic asymmetric unit, the calculated Matthews parameter ($V_M$) is $2.71{\AA}^3Da^{-1}$ and solvent content is 54.6%.

A Study on the Heat Resistance and Polarization Characteristics of Poly(vinyl alcohol)-I2 Complex Films Prepared with a Potassium iodide (KI를 사용하여 제조한 Poly(vinyl alcohol)-I2 착체 필름의 편광특성 및 열저항에 관한 연구)

  • Oh, Se Young;Shin, Dong Yoon
    • Applied Chemistry for Engineering
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    • v.10 no.4
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    • pp.603-607
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    • 1999
  • The polarization characteristics of poly(vinyl alcohol)-iodine complex, (PVA-KI system) prepared by the oxidation process of PVA film containing a potassium iodide (KI) were investigated. The UV-visible spectrum of the PVA-KI system polarizing film showed avsorption bands corresponding to $I^{-}$, $I{_3}{^-}$ and $I{_5}{^-}$ chromophoric species at 220 nm, 290~360 nm, respectively. The polarization efficiency and transmittance of PVA-KI system film were significantly influenced by oxidation time, stretching ratio and concentration of KI. The prepared polarizing film exhibited a high polarization efficiency(99.5%) and transmittance(45%). Especially, the heat resistance of the polarizing film was higher than that of a commercial PVA-$I_2$ polarizing film. It may be argued that the result should come from a difference in oxidation process of PVA polarizing film.

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A NOTE ON THE LOCAL HOMOLOGY

  • Rasoulyar, S.
    • Bulletin of the Korean Mathematical Society
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    • v.41 no.2
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    • pp.387-391
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    • 2004
  • Let A be Noetherian ring, a= (${\tau}_1..., \tau_n$ an ideal of A and $C_{A}$ be category of A-modules and A-homomorphisms. We show that the connected left sequences of covariant functors ${limH_i(K.(t^t,-))}_{i\geq0}$ and ${lim{{Tor^A}_i}(\frac{A}{a^f}-)}_{i\geq0}$ are isomorphic from $C_A$ to itself, where $\tau^t\;=\;{{\tau_^t}_1$, ㆍㆍㆍ${\tau^t}_n$.