• 제목/요약/키워드: Complete Dissolution

검색결과 38건 처리시간 0.025초

관계해지의도의 결과변수에 관한 연구 (A Study on the Consequences of Dissolution Intention)

  • 강보현;오세조
    • 한국유통학회:학술대회논문집
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    • 한국유통학회 2005년도 춘계학술대회 발표논문집
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    • pp.87-110
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    • 2005
  • 지금까지의 관계해지에 관한 연구들은 관계해지의도를 최종 결과변수로 간주하여 연구를 수행하였으며, 관계해지의도가 형성된 이후에 관해서는 연구된 바가 전혀 없었다. 즉, 관계해지의도를 완전한 관계해지와 동일시함으로써 관계해지의도의 형성으로부터 일어나는 관계해지의 모습을 간과한 문제점을 가지고 있었다. 본 연구는 이에 대한 문제점을 해소하고 관계해지의도가 형성된 후에 어떤 경로를 통해 완전한 관계해지로 나아가는 지를 알아보기 위한 최초의 시도로써 수행되었다. 즉, 관계해지의도가 형성된 이후부터 완전한 관계해지가 일어나기 전까지의 영역을 대상으로 하여 관계해지의도의 결과변수들이 기회주의의 증가와 거래특유투자의 감소, 그리고 협력의 감소임을 밝히고 관계해지의도와 결과변수들 간의 관계를 제시함으로써 관계해지의도로부터 완전한 관계해지로 이루어지는 과정을 실증적으로 살펴보았다. 국내신문사(판매자)와 신문지국(구매자)의 관계에서 신문지국의 관점을 대상으로 설문조사를 수행하여 실증분석을 한 결과, 본 연구에서 제시한 5개의 가설들이 모두 지지되었다. 즉, 관계해지의도를 가지게 된 주체는 기회주의가 증가되고 거래특유투자를 감소시킴으로써 판매자와의 협력이 붕괴되는 과정을 통해 완전한 관계해지로 나아감을 밝혔다. 마지막으로, 본 연구의 이론적 공헌점들 및 관리적 시사점들이 논의되었고, 연구의 한계점들 및 향후의 연구방향들이 제 시 되었다.

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Aluminum Hydroxide의 유무기산(有無機酸)에 의한 용해특성(溶解特性) 연구(硏究) (A Study on the Dissolution of Aluminum Hydroxide with Mineral and Organic Acid)

  • 이화영
    • 자원리싸이클링
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    • 제18권2호
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    • pp.56-61
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    • 2009
  • 알루미늄 화합물을 합성하기 위한 전단계 연구로써, 국산 99.7% 순도의 수산화알루미늄을 대상으로 무기산 및 유기산을 이용한 용해실험을 수행하였다. 본 실험에서 사용한 수산화알루미늄의 평균입도는 각각 $14.4{\mu}m$, $22.9{\mu}m$$62.3{\mu}m$이었으며, 반응온도, 산농도, 반응시간에 따른 수산화알루미늄 용해율을 조사하였다. 실험결과 염산에 의한 용해시 염산농도가 증가할수록 용해율은 증가하였으며, $70^{\circ}C$에서 4시간 용해시 염산농도 5 mole/l의 경우 70% 이상의 용해율을 보였다. 또한, 황산을 사용하여 수산화알루미늄을 용해하고자 하는 경우 적정 황산농도는 6 mole/l 부근으로 유지하는 것이 바람직하였다. 옥살산을 사용하는 경우 반응온도는 $90^{\circ}C$가 적절하며, 옥살산농도 1.0 mole/l, 고체농도 20 g/l의 조건에서 16시간 용해하였을 때 거의 100%에 근접하는 용해율을 얻을 수 있었다.

Self-Nanoemulsifying Drug Delivery System of Lutein: Physicochemical Properties and Effect on Bioavailability of Warfarin

  • Yoo, Juno;Baskaran, Rengarajan;Yoo, Bong-Kyu
    • Biomolecules & Therapeutics
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    • 제21권2호
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    • pp.173-179
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    • 2013
  • Objective of present study was to prepare and characterize self-nanoemulsifying drug delivery system (SNEDDS) of lutein and to evaluate its effect on bioavailability of warfarin. The SNEDDS was prepared using an oil, a surfactant, and co-surfactants with optimal composition based on pseudo-ternary phase diagram. Effect of the SNEDDS on the bioavailability of warfarin was performed using Sprague Dawley rats. Lutein was successfully formulated as SNEDDS for immediate self-emulsification and dissolution by using combination of Peceol as oil, Labrasol as surfactant, and Transcutol-HP or Lutrol-E400 as co-surfactant. Almost complete dissolution was achieved after 15 min while lutein was not detectable from the lutein powder or intra-capsule content of a commercial formulation. SNEDDS formulation of lutein affected bioavailability of warfarin, showing about 10% increase in $C_{max}$ and AUC of the drug in rats while lutein as non-SNEDDS did not alter these parameters. Although exact mechanism is not yet elucidated, it appears that surfactant and co-surfactant used for SNEDDS formulation caused disturbance in the anatomy of small intestinal microvilli, leading to permeability change of the mucosal membrane. Based on this finding, it is suggested that drugs with narrow therapeutic range such as warfarin be administered with caution to avoid undesirable drug interaction due to large amount of surfactants contained in SNEDDS.

국제표준화기구 기준에 의한 의료기기용 하이드로겔의 세포독성 평가 (Cytotoxicity Evaluation on Hydrogels for Medical Devices based on the International Organization for Standardization)

  • 김현기;김예태;조양하;노혜원;김민아;김소연;허강무;박정숙
    • Journal of Pharmaceutical Investigation
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    • 제39권2호
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    • pp.127-131
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    • 2009
  • Hydrogels for medical devices such as hydrophilic dressing, moisturizing healing band, hydrophilic intravenous catheter and soft contact lens were evaluated for their cytotoxicity according to the International Organization for Standardization (ISO) procedures. To test indirect cytotoxicity of hydrogel products, dissolution medium and dissolution condition were selected based on the guideline for medical devices. Cytotoxicity was low in all the case of hydrogel products. Soft contact lens showed no significant difference in dissolution between complete medium and saline. Currently, there is no specific guidelineto test hydrogel for medical devices in Korea with consideration of characteristics of hydrogel. Thus, proper method of cytotoxicity evaluation should be selected depending on the characteristics and usages of hydrogels for medical devices.

VC 첨가가 Ti(CN)계 써메트의 미세구조 및 기계적 성질에 미치는 영향 (Effect of VC Addition on the Microstructure & Mechanical Properties of Ti(CN)-based Cermet)

  • 안성용;강신후
    • 한국세라믹학회지
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    • 제35권12호
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    • pp.1316-1322
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    • 1998
  • The amount of VC and C/N ratio in Ti(CN) was varied to investigate the effect of VC addition on the mi-crostructural change in Ti(CN)-Ni system. As the amount of VC addition increases in Ti(C0.7N0.3)-20Ni sys-tem a complete solid solution was observed in Ti(C0.7N0.3)-20Ni-25VC system. It implies that the ratio of the dissolution rates of Ti(C0.7N0.3)to that of VC is nearly 2:1 at the sintering conditions used in this study. It was found from the experiments that the system composed of the Ti(C0.7N0.3) phase exhibits a rimless structure and relatively small amount of solid solution. That is among Ti(C0.7N0.3) phase exhibits a rimless structure and relatively small amount of solid solution. This is among Ti(C1-xNx) phases the dissolution rate of Ti(C0.3N0.7) is the lowest. Also fracture toughness(KIC) of the cermet was measured by indentation method. Attentions were paid to crack propagation path to look for a dominant fracture mode and to cor-relate it with fracture toughness values. The fracture toughness was relatively high with the addition of VC content. But the addition of a large VC content reduced the overall toughness of the cermet. This result is explained with the difference in fracture mode.

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밀링조건이 사용 후 PDP패널의 유가금속 용출효율에 미치는 영향 (The Effect of Milling Conditions for Dissolution Efficiency of Valuable Metals from PDP Waste Panels)

  • 김효섭;김찬미;이철희;이성규;홍현선;구자명;홍순직
    • 한국분말재료학회지
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    • 제20권2호
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    • pp.107-113
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    • 2013
  • In this study, the microstructure and valuable metals dissolution properties of PDP waste panel powders were investigated as a function of milling parameters such as ball diameter size, milling time, and rotational speed during high-energy milling process. The complete refinement of powder could achieved at the ball diameter size of 5 mm due to sufficient impact energy and the number of collisions. With increasing milling time, the average particle size was rapidly decreased until the first 30 seconds, then decreased gradually about $3{\mu}m$ at 3 minutes and finally, increased with presence of agglomerated particles of $35{\mu}m$ at 5 minutes. Although there was no significant difference on the size of the particle according to the rotational speed from 900 to 1,100 rpm, the total valuable metals dissolution amount was most excellent at 1,100 rpm. As a result, the best milling conditions for maximum dissolving amount of valuable metals (Mg: 375 ppm, Ag 135 ppm, In: 17 ppm) in this research were achieved with 5 mm of ball diameter size, 3min of milling time, and 1,100 rpm of rotational speed.

중층심해에 분사된 액체 이산화탄소의 용해특성 (Dissolution Characteristics of Liquid $CO_2$ Injected at the Intermediate Depth of the Ocean)

  • 김남진;이재용;서태범;김종보
    • 태양에너지
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    • 제20권2호
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    • pp.75-84
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    • 2000
  • Global wanning induced by greenhouse gases such as carbon dioxide is a serious problem for mankind. Carbon dioxide ocean disposal is one of the promising options to reduce carbon dioxide concentration in the atmosphere because the ocean has vast capacity for carbon dioxide sequestration. However, the dissolution rate of liquid carbon dioxide in seawater must be known in advance in order to estimate the amount of carbon dioxide sequestration in the ocean. Therefore, the solubility, the surface concentration, the droplet size and other factors of liquid carbon dioxide at various depths are calculated. The results show that liquid carbon dioxide changes to carbon dioxide bubble around 500 m in depth, and the droplet is completely dissolved below 500 m in depth if carbon dioxide droplet is released both at 1000 m in depth with the initial droplet diameter of 0.011 m or less and at 1500 m in depth with the diameter of 0.015 m or less. In addition, the hydrate film acts as a resistant layer for the dissolution of liquid carbon dioxide. The surface concentration of carbon dioxide droplet with the hydrate film is about 50% at 1500 m in depth and about 60% at 1000 m in depth of the carbon dioxide solubility. Also, the ambient carbon dioxide concentration in the plume is an another crucial parameter for complete dissolution at the intermediate ocean depth, and the injection of liquid carbon dioxide from a moving ship is more effective than that from a fixed pipeline.

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Solubility of TiO2 in NaF-CaF2-BaF2 Melts

  • Yoo, Jeong-Hyun;Cho, Sung-Wook
    • Metals and materials international
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    • 제24권6호
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    • pp.1386-1393
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    • 2018
  • The solubility of $TiO_2$ in $NaF-CaF_2-BaF_2$ ternary eutectic melts was investigated at the temperature range of $1025-1150^{\circ}C$. The least-squares equation was obtained from the relationship between the reciprocal temperature and the natural logarithm of the titanium concentration in the melts saturated with $TiO_2$. The corresponding partial molar enthalpy of dissolution of $TiO_2$ was found to be 188 kJ/mol. The titanium saturation concentration was 3.73 wt% at $1100^{\circ}C$. From the titanium concentration change with the added amount of $TiO_2$ at different holding time after a final stirring, it was found that not only complete dissolution of $TiO_2$ but also enough sedimentation of excessive $TiO_2$ should be guaranteed to obtain more reliable solubility data. The holding time of 10 h was found to be enough for the excessive $TiO_2$ particles to settle down in our experimental conditions. It is noteworthy that in case of adding $TiO_2$ in excess of its solubility, the $Ba_{1.12}(Ti_8O_{16})$ phase was observed at the lower and bottom of the solidified salt ingots.

철도레일 테르밋 용접부의 기계적 특성 향상 방안에 관한 연구 ((A) Study on the Mechanical Properties Improvement of Thermite Welded Zone of Railroad Rail)

  • 최상규;박성상;백응률;전봉길
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2011년도 정기총회 및 추계학술대회 논문집
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    • pp.2101-2106
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    • 2011
  • It is reported that about more than 45% of damage shown in railroad rails include breakage of rail end which cross the center of Thermit welded zone. Thermite welding is always accompanied by numerous aluminum oxide and secondary inclusions, which may have a negative influence on the ductility and toughness of the weld metal. In this study the aluminum powder recycled by waste aluminum can was used for iron oxide generated after the process of welding rod and the remain aluminum was reduced by minimizing the quantity of aluminum. And complete dissolution was induced by using ferro Mn powder as the additive element. This study reviewed the applicability of heat treatment in the welded zone of rail using ceramic heating pad by carrying it out. This study could observe the improvement of the mechanical characteristics (UTS and elongation) and the changes of failure mechanism from brittleness to ductility. It could be found that improved strength and elongation result from pearilte fine structure.

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Investigation of carbon nanotube growth termination mechanism by in-situ transmission electron microscopy approaches

  • Kim, Seung Min;Jeong, Seojeong;Kim, Hwan Chul
    • Carbon letters
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    • 제14권4호
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    • pp.228-233
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    • 2013
  • In this work, we report in-situ observations of changes in catalyst morphology, and of growth termination of individual carbon nanotubes (CNTs), by complete loss of the catalyst particle attached to it. The observations strongly support the growth-termination mechanism of CNT forests or carpets by dynamic morphological evolution of catalyst particles induced by Ostwald ripening, and sub-surface diffusion. We show that in the tip-growth mode, as well as in the base-growth mode, the growth termination of CNT by dissolution of catalyst particles is plausible. This may allow the growth termination mechanism by evolution of catalyst morphology to be applicable to not only CNT forest growth, but also to other growth methods (for example, floating-catalyst chemical vapor deposition), which do not use any supporting layer or substrate beneath a catalyst layer.