• Title/Summary/Keyword: Combustion catalyst

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Exhaust Emissions Characteristics on Driving Cycle Mode and Ignition Advance Condition Change of CNG/LPLI Bi-Fuel Vehicle (CNG/LPLI Bi-Fuel 자동차에서 주행시험 모드와 점화진각에 따른 배출가스 특성)

  • Cho, Seungwan;Kim, Seonghoon;Kwon, Seokjoo;Park, Sungwook;Jeon, Chunghwan;Seo, Youngho
    • Journal of ILASS-Korea
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    • v.19 no.1
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    • pp.40-46
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    • 2014
  • Recently rise in oil prices feet the burden on not only diesel vehicle driver but also LPG vehicle driver, and get interested in various way to reduce fuel costs. In this study discuss on exhaust emissions characteristics on driving cycle mode and ignition advance condition change of CNG/LPLI Bi-Fuel vehicle. Experimental test was performed by changing the conditions of fuel (LPG/CNG), spark advance (Base, $10^{\circ}CA$, $15^{\circ}CA$), and driving mode (FTP-75, HWFET, and NEDC). In case of CO emission, in the order of CNG Base, CNG S/A10, S/A15 condition are average reduced -21%, -35%, -29% respectively compared to LPG fuel. The active emission reduction from the initial engine start, spark retard is likely to be beneficial in catalyst warm-up and improve combustion stability rather than spark advance.

PCDD/PCDFs Emission and Operating Conditions of Domestic MSW Incinerators (국내 도시 쓰레기 소각로에서의 운전조건과 다이옥신 배출량과의 상관관계에 관한 연구)

  • Yang, Won;Shin, Donghoon;Choi, Jinhwan;Choi, Sangmin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.12
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    • pp.1755-1762
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    • 1998
  • In order to minimize emission of polychlorinated dibenzo dioxins and polychlorinated dibenzo furans (PCDD/PCDFs) from municipal solid waste incinerators, it is important to maintain optimized operating conditions along with the system modification/improvement. Operating conditions of MSW incinerator make very complicated influence on formation of PCDD/PCDFs in each unit apparatus. For revealing these influences, concentrations of PCDD/PCDFs are measured from the stack and from the fly ash, while monitoring the plant operating conditions. The effects are grouped into 3 main categories, combustion conditions, de Novo synthesis effects, and adsorption/destruction effects in the flue gas treatment system. Interpretation of the results showed that de Novo synthesis effect, reformation by metalic catalyst, especially Cu in fly ash in the temperature range of $250{\sim}500^{\circ}C$, is found to influence most dominantly on the concentration of PCDD/PCDFs. A plausible mathmatical model for predicting concentration of PCDD/PCDFs is proposed, and discussed.

The effect of dynamic operating conditions on nano-particle emissions from a light-duty diesel engine applicable to prime and auxiliary machines on marine vessels

  • Lee, Hyungmin;Jeong, Yeonhwan
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.4 no.4
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    • pp.403-411
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    • 2012
  • This study presents the nano-sized particle emission characteristics from a small turbocharged common rail diesel engine applicable to prime and auxiliary machines on marine vessels. The experiments were conducted under dynamic engine operating conditions, such as steady-state, cold start, and transient conditions. The particle number and size distributions were analyzed with a high resolution PM analyzer. The diesel oxidation catalyst (DOC) had an insignificant effect on the reduction in particle number, but particle number emissions were drastically reduced by 3 to 4 orders of magnitude downstream of the diesel particulate filter (DPF) at various steady conditions. Under high speed and load conditions, the particle filtering efficiency was decreased by the partial combustion of trapped particles inside the DPF because of the high exhaust temperature caused by the increased particle number concentration. Retarded fuel injection timing and higher EGR rates led to increased particle number emissions. As the temperature inside the DPF increased from $25^{\circ}C$ to $300^{\circ}C$, the peak particle number level was reduced by 70% compared to cold start conditions. High levels of nucleation mode particle generation were found in the deceleration phases during the transient tests.

Carbon nanotubes synthesis using diffusion and premixed flame methods: a review

  • Mittal, Garima;Dhand, Vivek;Rhee, Kyong Yop;Kim, Hyeon-Ju;Jung, Dong Ho
    • Carbon letters
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    • v.16 no.1
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    • pp.1-10
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    • 2015
  • In recent years, flame synthesis has absorbed a great deal of attention as a combustion method for the production of metal oxide nanoparticles, carbon nanotubes, and other related carbon nanostructures, over the existing conventional methods. Flame synthesis is an energy-efficient, scalable, cost-effective, rapid and continuous process, where flame provides the necessary chemical species for the nucleation of carbon structures (feed stock or precursor) and the energy for the production of carbon nanostructures. The production yield can be optimized by altering various parameters such as fuel profile, equivalence ratio, catalyst chemistry and structure, burner configuration and residence time. In the present report, diffusion and premixed flame synthesis methods are reviewed to develop a better understanding of factors affecting the morphology, positioning, purity, uniformity and scalability for the development of carbon nanotubes along with their correlated carbonaceous derivative nanostructures.

Effect of Flow Uniformity Device on the Catalytic Combustor for 5 kW High Temperature Fuel Cell System (5 kW급 고온형 연료전지 촉매 연소기 유동 균일화 장치가 연소 특성에 미치는 영향)

  • Lee, Sang-Min;Woo, Hyun-Tak;Ahn, Kook-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.6
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    • pp.878-883
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    • 2011
  • Effect of flow uniformity on the reaction characteristics of a catalytic combustor for high temperature fuel cell system has been experimentally investigated in the present study. One of the most important factor in designing catalytic combustion is to avoid hot spot in catalysts. In this regard, it is very important to secure flow uniformity of combustor inlet. A couple of perforated plates were applied at the front of catalyst region as flow uniformity device with minimal pressure drop. Results show that the velocity and temperature profile became more uniform when applying the flow uniformity device. CO and $CH_4$ emissions at the combustor exit were decreased and the average exit temperature was slightly increased with the flow uniformity device.

An Experiment of SCR System On-board Ship

  • Choi Jae-Sung;Cho Kwon-Hae;Lee Jae-Hyun;Lee Jin-Wook;Kim Jeong-Gon;Jang Sung-Hwan;Yang Hee-Sung;Ko Jun-Ho;Park Ki-Yong
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.3
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    • pp.306-312
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    • 2005
  • IMO $NO_x$ levels are generally possible to meet by means of primary on-engine measures. Further significant follow-on reductions are likely to require a secondary after-treatment technique. SCR(Selective Catalytic Reduction) technology is used almost exclusively for $NO_x$ removal in stationary combustion systems. In order to develop a practical SCR system for marine application on board ship, a primary SCR system using urea was made. The SCR system was set up on the ship, 'HANNARA' as a test vessel. employed a two-stroke cycle diesel engine as main propulsion, which is a training ship of Korea Maritime University. The purpose of this paper is to report the results about the basic effects of the below system parameters, The degree of $NO_x$ removal depends on some parameters, such as the amount of urea solution added, space velocity, reaction gas temperature and activity of catalyst.

A Study on the Comparison of Emissions and Fuel Efficiency Performance of 2.0 Liter LPG Hybrid Engine and Vehicle (2.0 리터급 LPG 하이브리드 엔진 및 차량의 배출가스 및 연비성능 비교에 관한 연구)

  • Seokjoo Kwon;Bonseok Koo;Jaehoon Kang;Kangmyeon Kim;Sedoo Oh;Youngho Seo
    • Journal of ILASS-Korea
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    • v.28 no.4
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    • pp.191-197
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    • 2023
  • LPG direct injection (LPDi) technology is a method of improving the weaknesses of existing LPG vehicles by directly injection into the combustion chamber. This study was conducted on the comparison of emissions and fuel efficiency performance of the engine and vehicle by applying LPDi technology. The LPDi hybrid engine's maximum output and maximum torque were measured at an equivalent level of less than 1% compared to conventional gasoline fuel. The fuel amount was corrected using the LCU controller, and the THC, CO, and NOx emissions were reduced to 90% in the operating range of the three-way catalyst through air-fuel ratio control. The analysis of THC+NOx and CO emissions in FTP-75 (CVS-75) driving mode satisfied the US LEV III SULEV30 regulation.

Synthesis of Titanium Dioxides Using Low Temperature Combustion Method and Photocatalytic Decomposition of Methylene Blue (저온연소법에 의한 이산화티탄의 합성 및 메틸렌블루의 광촉매 분해반응)

  • Baek, Seung Hee;Jung, Won Young;Lee, Gun Dae;Park, Seong Soo;Hong, Seong-Soo
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.329-334
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    • 2009
  • Yttrium ions doped $TiO_2$ particles have been prepared using a low temperature combustion method. The physical properties were investigated, together with the activity of $TiO_2$ particles as a photocatalyst for the decomposition of methylene blue. From XRD results, the major phase of all the $TiO_2$ particles prepared under basic condition was an anatase structure but a rutile peak was observed when they are prepared under acidic condition. The crystallite size of $TiO_2$ particles was decreased as the molar ratio of CA/TTIP increased. The photocatalytic activity increased with an increase of CA/TTIP molar ratio and pH in the solution. In addition, the doping of 1.0 mole% yttrium ion on the $TiO_2$ enhanced the photocatalytic activity and showed the higher activity than commercial P-25 catalyst.

Hydrodynamic Characteristics of Absorbent and Catalyst for Pre-combustion CO2 Capture (연소 전 이산화탄소 회수를 위한 흡수제 및 촉매의 수력학적 특성)

  • Ryu, Ho-Jung;Yoon, Joo-Young;Lee, Dong-Ho;Shun, Dowon;Park, Jaehyeon;Park, Yeong-Seong
    • Clean Technology
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    • v.19 no.4
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    • pp.437-445
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    • 2013
  • To develop SEWGS (sorption enhanced water gas shift) system using dry $CO_2$ absorbent for pre-combustion $CO_2$ capture, hydrodynamic characteristics of $CO_2$ absorbents were measured and investigated. The minimum fluidization velocity of $CO_2$ absorbent was measured and the effects of the operating conditions were investigated to operate the system at bubbling fluidized bed condition. The minimum fluidization velocity decreased as pressure and temperature increased. Moreover, the minimum fluidization velocity decreased as column diameter increased. The effects of operating conditions on the solid circulation rate were measured and investigated to select appropriate operating conditions for continuous $CO_2$ capture and regeneration. The measured solid circulation rates were ranged between 10 and 65 kg/h and increased as the solid injection velocity, gas velocity in the regeneration reactor, and solid height increased.

Optimization for I-129 analytical method of radioactive waste sample using a high-temperature combustion tube furnace (고온연소로를 이용한 방사성 폐기물 내 I-129 정량 분석법 최적화 연구)

  • Chae-yeon, Lee;Jong-Myoung, Lim;Hyuncheol, Kim;Ji-Young, Park;Jin-Hong, Lee
    • Analytical Science and Technology
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    • v.35 no.6
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    • pp.256-266
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    • 2022
  • It is important to determine the concentration of long-lived radionuclides (e.g., 129I) in nuclear waste to ensure safety when handling it. To analyze nuclides in a solid sample (e.g., concrete and soil), it is essential to effectively separate and purify the nuclides of interest in the sample. This study reports the comprehensive efforts made to validate the analytical procedure for 129I detection in solid samples, using a high-temperature combustion furnace. 129I volatilized from the sample collected in 0.01 M HNO3 solution with a reducing agent (e.g., NaHSO3) and was rapidly measured by ICP-MS. Analytical conditions, such as pyrolysis temperature and types of mobile phase gas, catalyst, and trapping solution, were optimized to obtain a high recovery rate of spiked 129I. Finally, the optimized method was applied for the simultaneous analysis of other volatile radionuclides, such as 3H and 14C. The performance test results for the optimized method confirmed that the LSC (for 3H and 14C) and ICP-MS (for 129I) measurements, with the separation of volatile nuclides using a high-temperature combustion furnace, were reliable.