• Clean Technology
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• v.28 no.2
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• pp.131-137
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• 2022

The semiconductor process currently emits various by-products and unused gases. Emissions containing pollutants are generally classified into categories such as organic, acid, alkali, thermal, and cabinet exhaust. They are discharged after treatment in an atmospheric prevention facility suitable for each exhaust type. The main components of organic exhaust are volatile organic compounds (VOC), which is a generic term for oxygen-containing hydrocarbons, sulfur-containing hydrocarbons, and volatile hydrocarbons, while the main components of alkali exhaust include ammonia and tetramethylammonium hydroxide. The purpose of this study was to determine the combustion characteristics and analyze the NO_X reduction rate by maintaining a direct combustion and temperature to process organic and alkaline exhaust gases simultaneously. Acetone, isopropyl alcohol (IPA), and propylene glycol methyl ether acetate (PGMEA) were used as VOCs and ammonia was used as an alkali exhaust material. Independent and VOC-ammonia mixture combustion tests were conducted for each material. The combustion tests for the VOCs confirmed that complete combustion occurred at an equivalence ratio of 1.4. In the ammonia combustion test, the NO_X concentration decreased at a lower equivalence ratio. In the co-combustion of VOC and ammonia, NO was dominant in the NO_X emission while NO₂ was detected at approximately 10 ppm. Overall, the concentration of nitrogen oxide decreased due to the activation of the oxidation reaction as the reaction temperature increased. On the other hand, the concentration of carbon dioxide increased. Flameless combustion with an electric heat source achieved successful combustion of VOC and ammonia. This technology is expected to have advantages in cost and compactness compared to existing organic and alkaline treatment systems applied separately.

• Journal of the Korean Society of Safety
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• v.25 no.6
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• pp.210-215
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• 2010

In this study, when the forest fire occurred, in order to estimate greenhouse gas emissions, tree glow in Gangwon Youndong area, Juglans mandshurica, Alnus japonica, Acer palmatum of carbon dioxide and carbon monoxide emissions were about. Water content were measured before the experiment, Juglans mandshurica 196.24%, Alnus japonica 169.17% Acer palmatum 210.10% moisture content showed a big difference, Living leaves of Acer palmatum were a lot of moisture. Also, 50g weight of carbon dioxide on the Juglans mandshurica 53.3644g, Alnus japonica 49.4256g, was released about Acer palmatum 51.3394g, Juglans mandshurica living leaves were the most carbon dioxide emissions. Carbon monoxide emissions result, About weight 50g Juglans mandshurica 1.5329g, Alnus japonica 1.7189g, 2.5002g about Acer palmatum was released, Acer palmatum living leaves were the most carbon monoxide emissions.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.7
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• pp.868-876
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• 2014

The objective of this study is focused on the analyzing combustion, carbon monoxide and hydrocarbon emission characteristics of marine diesel oil, utilized for naval propulsion engine, with varying pre-post injection timing of an optically accessible single cylinder engine. And also the combustion process is analyzed by means of a high speed camera visualization. On the result of retarding pre-injection timing toward main injection timing, the mean effective pressure and maximum pressure of combustion chamber are increased; however, the heat release rate is decreased. Furthermore, the emission rates of carbon monoxide and hydrocarbon are reduced in this case. In hence, when a post-injection timing is advanced, the mean effective pressure and maximum pressure are increased, because the combustion has been performed under the high temperature and high pressurized environment during main injection time, and the emission rates of carbon monoxide and hydrocarbon are increased. From the experimental results, it considered that retarding of pre-injection timing affects to shorten the ignition delay of main injection clearly, and to raise the flame intensity comparing to the advanced state. The ignition delay during post-injection is not appeared at any post-injection time, but the flame intensity has been weakened gradually according to the retarding of post-injection timing.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.28 no.7
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• pp.275-282
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• 2016

MILD (Moderate and Intense Low-oxygen Dilution) combustion using oxygen as an oxidizer is considered as one of the most promising combustion technologies for high energy efficiency and for reducing nitrogen oxide and carbon dioxide emissions. In order to investigate the effects of nozzle angle and oxygen velocity conditions on the formation of oxygen-MILD combustion, numerical and experimental approaches were performed in this study. The numerical results showed that the recirculation ratio ($K_V$), which is an important parameter for performing MILD combustion, was increased in the main reaction zone when the nozzle angle was changed from 0 degrees to 15 degrees. Also, it was observed that a low and uniform temperature distribution was achieved at an oxygen velocity of 400 m/s. The perfectly invisible oxy-MILD flame was observed experimentally under the condition of a nozzle angle of $10^{\circ}$ and an oxygen velocity of 400 m/s. Moreover, the NOx emission limit was satisfied with NOx regulation of less than 80 ppm.

• Plant Journal
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• v.6 no.2
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• pp.70-77
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• 2010

This study investigated the characteristics of co-combustion of mixed anthracite (domestic and Vietnam) and bituminous coal (Sonoma, Australia) at circulating fluidized bed boiler in Donghae thermal power plant when mixing ratio of bituminous coal is variable. Co-combustion of bituminous coal contributes to improvement in general combustion characteristics such as moderately retaining temperature of furnace and recycle loop, reducing unburned carbon powder, and reducing discharge concentration of NOx and limestone supply owing to improvement in anthracite combustibility as the mixing ratio was increased. However, bed materials were needed to be added externally when the mixing ratio exceeded 40% because of reduction in generating bed materials based on reduction in ash production. When co-combustion was conducted in the section of 40 to 60% in the mixing ratio while the supplied particles of bituminous coal was increased from 6 mm to 10 mm, continuous operation was shown to be possible with upper differential pressure of 100 mmH2O (0.98 kPa) and more without addition of bed materials for the co-combustion of mixed anthracite and bituminous coal (to 50% or less of the ratio) and that of domestic coal and bituminous coal (to 60% of the ratio).

• Applied Chemistry for Engineering
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• v.18 no.3
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• pp.227-233
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• 2007

Carbon/carbon (C/C) composites as unique materials possess exceptional thermal resistance with light weight, high stiffness, and strength even at high temperature. However, one serious obstacle for application of the C/C composites is their poor oxidation resistance in high temperature oxidizing environments. SiC coating has been employed to protect the composites from oxidation. This study explored combustion characteristics of 4-directional (4D) carbon/carbon composites using liquid fuel rocket engine to investigate ablative motion of the materials. C/C composites were made of coal tar pitch as a matrix precursor, and heat-treated at $2300^{\circ}C$. Throughout repeated densification process, the density of the material reached $1.903g/cm^3$. After machining 4D C/C composites, the nozzle surface was coated by a SiC layer by pack-cementation method to improve oxidation resistance. Erosion characteristics of SiC-coated C/C composites were measured as function of the ratio of oxygen to fuel. The morphological change of the composites after combustion test was investigated using SEM and erosion mechanism also was discussed.

• Asian Journal of Atmospheric Environment
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• v.7 no.2
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• pp.95-104
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• 2013

The study of carbonaceous aerosols in the atmosphere is critical to understand the role of aerosols in human health and climate. Using standardized thermal optical transmittance methods, organic carbon (OC), elemental carbon (EC), and water soluble organic carbon (WSOC) were determined using a combustion sampling system for four types of agricultural crop residues (rice straw, red pepper stems, soybean stems, and green perilla stems) and eight types of forest trees (pine stems, pine needles, ginkgo stems, ginkgo leaves, maple stems, maple leaves, cherry stems, and cherry leaves). The aerosol particles between 0.056 and $5.6{\mu}m$ in size were analyzed using a Micro-Orifice Uniform Deposit Impactor (MOUDI). In the current study, the Carbonaceous Thermal Distribution (CTD) by carbon analyzer was discussed in order to understand the carbon fractions from the twelve types of biomass burning. Also, the concentration of OC, EC, WSOC, and water insoluble organic carbon (WIOC) detected in the emissions were described.

• Carbon letters
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• v.12 no.1
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• pp.39-43
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• 2011

Synthesis of carbon fibers from cotton fiber by pyrolysis process has been described. Synthesis parameters are optimized using Taguchi optimization technique. Synthesized carbon fibers are used for studying hydrogen adsorption capacity using Seivert's apparatus. Transmission electron microscopy analysis and X-ray diffraction of carbon fiber from cotton suggested it to be very transparent type material possessing graphitic nature. Carbon synthesized from cotton fibers under the conditions predicted by Taguchi optimization methodology (no treatment of cotton fiber prior to pyrolysis, temperature of pyrolysis $800^{\circ}C$, Argon as carrier gas and paralyzing time for 2 h) exhibited 7.32 wt% hydrogen adsorption capacity.

• Journal of Environmental Science International
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• v.11 no.8
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• pp.773-781
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• 2002

The natural carbon cycle has been perturbed since the mid-19th century by anthropogenic CO$_2$emissions from fossil fuel combustion and deforestation due to population growth and industrialization. The current study simulated the global carbon cycle for the past 42 years using an eight-box carbon cycle model. The results showed that since the terrestrial biospheric carbon sink was roughly offset by the deforestation source, the fossil fuel emission source was partitioned between the atmospheric and oceanic sinks. However, the partitioning ratio between the atmosphere and the ocean exhibited a change, that is, the carbon accumulation rate was faster in the atmosphere than in the ocean, due to a decrease in the so-called ocean buffering capacity. It was found that the ocean buffering capacity to take up excess CO$_2$decreased by 50% in terms of the buffer factor over the past 42 years. Accordingly, these results indicate that if the current CO$_2$emission trend continues, the future rate of increase in the atmospheric CO$_2$concentration will accelerate.

• Fire Science and Engineering
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• v.14 no.2
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• pp.7-13
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• 2000

We had investigated thermal stability, Ignition temperature and fire gas for polyurethane foams used for manikin, cushion and interior finishing material. Decomposition of polyurethane foams with temperature was investigated using a DSC and the weight loss with temperature increase using a TGA in order to find the thermal hazard of polyurethane foams, and the ignition temperature of polyurethane foams according to species. We studied constant temperature among ignition temperature measuring methods. In addition, noxious gases for polyurethane foams according to combustion condition were analyzed using gas analyzer and GASTEC. As results, initial decomposition temperature of polyurethane foam used for interior finishing material was lower than those for manikin and cushion, and exothermic energy was higher. Ignition temperature of polyurethane foam of interior finishing material was $420^{\circ}$. All of combustion forms at $427^{\circ}$ and under were smoldering combustion, and it was combustion at $500^{\circ}$. As furnace temperature was increased, concentration of noxious gases such as carbon oxide, carbon dioxide, and hydrogen cyanide was increased. And nitrogen oxide at combustion condition($500^{\circ}$) was over 10 ppm.