• Title/Summary/Keyword: Coking

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Effect of CeO2 Coating on the Grain Growth of Cu Particles (CeO2 코팅을 통한 Cu 입자의 입성장 억제 효과에 관한 연구)

  • Yoo Hee-Jun;Moon Ji-Woong;Oh You Keun;Moon Jooho;Hwang Hae Jin
    • Journal of Powder Materials
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    • v.12 no.6 s.53
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    • pp.413-421
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    • 2005
  • Copper is able to work as a current collector under wide range of hydrocarbon fuels without coking in Solid oxide fuel cells (SOFCs). The application of copper in SOFC is limited due to its low melting point, which result in coarsening the copper particle. This work focuses on the sintering of copper powder with ceria coating layer. Ceria-coated powder was prepared by thermal decomposition of urea in $Ce(NO_3)_3\cdot6H_2O$ solution, which containing CuO core particles. The ceria-coated powder was characterized by XRD, ICP, and SEM. The thermal stability of the ceria-coated copper in fuel atmosphere $(H_2)$ was observed by SEM. It was found that the ceria coating layer could effectively hinder the grain growth of the copper particles.

Bretylium on the Pressor Action of Tyramine in Conditions of Monoamine Oxidase Inhibition (Monoamine Oxidase 억제하(抑制下)에서의 Bretylium의 Tyramine 승압효과(昇壓效果)에 미치는 영향(影響))

  • Sohn, Tai-Hyoo
    • The Journal of the Korean life insurance medical association
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    • v.1 no.1
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    • pp.84-87
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    • 1984
  • 1. Effect of bretylium on the pressor response of the whole and spinal rabbits to tyramine was observed in conditions of monoamine oxidase inhibition brought about by catron administration. 2. Bretylium increased the prossor response to tyramine in the whole and spinal rabbits. 3. Bretylium failed to increase the tyramine effect if bretylium was given after administration of catron, a monoamine oxidase inhibitor. Actually the tyramine effect was decreased by bretylium in this situation. 4. The increase of the tyramine effect by bretylium will be due to its monoamine oxidase inhibitory property, and the decrease of the tyramine effect will be due to its adrenergic neurone b1coking property.

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Agglomeration of fine anthracite using oil and modified styrene (Oil과 Modified Styrene을 사용(使用)한 미립(微粒) 무연탄(無煙炭)의 응집(凝集))

  • Lee, Jae-Jang;Jang, Dong-Sung
    • Journal of Industrial Technology
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    • v.7
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    • pp.27-47
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    • 1987
  • Fine anthracite is very difficult to upgrade by conventional processes such as gravity concentration or froth flotation, because large quantities of fine coals are generated at the mining and preparation stages and a significant portion of these fine coals are mixed with gangue minerals. This study, therefore, was carried out for the purpose of improving recovery of low ash clean coal, effective beneficiation of low-grade coking coal and removal of sulphur from high-sulphur coals by employing the method of selective agglomeration using oil or polystrene flocculants, for coals which are generally hydrophobic in nature will be extracted by using flocculants. Studies were performed by varying solid concentration, concetration of bridging liquid, mixing speed and mixing time, balling speed and balling time, dispersant dosage, flocculant dosage, pulp pH, and particle size. The results were : when the methods of the oil agglomeration and selective flocculation were employ(in the two process the sample was ground to the size of -74 micron), 1) ash content of the agglomerated coal was 9.85, 7.83%, 2) combustibel recovery of it was 98.5%, 93.5%, respectively. It was observed in selective flocculation that polystyrene is an effective flocculant for coal, De-entrapment of shale from the concentrate flocculated by mechanical agitation was necessary for substantional reductions in final ash content.

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Development of Monolithic Catalyst System with Co-Ru-Zr for CO2 (dry) Reforming of Methane : Enhanced Coke Tolerance

  • Kim, Hyojin;You, Young-Woo;Heo, Iljeong;Chang, Tae-Sun;Hong, Ji Sook;Lee, Ki Bong;Suh, Jeong Kwon
    • Clean Technology
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    • v.23 no.3
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    • pp.314-324
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    • 2017
  • To verify the viability of Co, Ru and Zr-based catalyst for $CO_2$ (dry) reforming reaction, catalysts were fabricated using cordierite, silicon carbide and rota monolithic substrates, and they were compared with the conventional $Co-Ru-Zr/SiO_2$ catalyst in terms of performance and durability. Cordierite monolith was showed high activity with the least amount of active component. In addition, when Cordierite monolith was coated with Co-Ru-Zr in various ways, most excellent performance was showed at a precursor solution coating method. In particular, when 0.9 wt% Co-Ru-Zr/Cordierite was used for reaction, it was observed that 95% $CO_2$ conversion was maintained for 300 h at $900^{\circ}C$.

PCR-DGGE as a Supplemental Method Verifying Dominance of Culturable Microorganisms from Activated Sludge

  • Zhou, Sheng;Wei, Chaohai;Ke, Lin;Wu, Haizhen
    • Journal of Microbiology and Biotechnology
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    • v.20 no.11
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    • pp.1592-1596
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    • 2010
  • To verify the dominance of microorganisms in wastewater biological treatment, PCR-DGGE (denaturing gradient gel electrophoresis) was performed as a supplementary support method for screening of the dominant microorganisms from activated sludge. Results suggest that the dominant microorganisms in activated sludge are primarily responsible for strengthening its effectiveness as a biological treatment system, followed by the non-main dominant microorganisms, whereas the non-dominant microorganisms showed no effects. The degree of microbial abundance present on the profile of PCR-DGGE was in line with the treatment efficiency of augmented activated sludge with isolated cultures, suggesting that PCR-DGGE can be used as an effective supplementary method for verifying culturable dominant microorganisms in activated sludge of coking wastewater.

Pt-Ru, Pt-Ni bi-metallic catalysts for heavy hydrocarbon reforming (고 탄화수소 개질을 위한 Pt-Ru, Pt-Ni 이원금속촉매에 관한 연구)

  • Lee, Sanghp;Bae, Joongmyeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.97.2-97.2
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    • 2011
  • Pt-Ru and Pt-Ni bimetallic catalysts were prepared and tested for heavy hydrocarbon reforming. Metals were supported on CGO($Ce_{0.8}Gd_{0.2}O_{2.0-x}$) by incipient wetness method. The prepared catalysts were characterized by Temperature programmed reduction(TPR). Oxidative steam reforming of n-dodecane was conducted to compare the activity of the catalysts. The reforming temperature was varied from $500^{\circ}C$ to $800^{\circ}C$ at fixed $O_2$/C of 0.3, $H_2O$/C of 3.0 and GHSV of 5,000/h.Reduction peaks of metal oxide, surface CGO and bulk CGO were detected. Reduction temperature of metal oxide decreased over the bi-metallic catalysts. It is considered that interaction between metals leads to decrease interaction between metal and oxygen. On the other hands, reduction temperatures of surface CGO were dectected in the order of Pt-Ru > Pt-Ni > Pt. low reduction temperatures of surface CGO indicates the low activation energy for oxygen ion conduction to metal. Oxygen ion conduction is known as de-coking mechanism of ionic conducting supports such as CGO. In activity test, fuel conversion was in the same order of Pt-Ru > Pt-Ni > Pt. Especially, 100% of fuel conversion was obtained over Pt-Ru catalysts at $500^{\circ}C$.

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The Tmie used for Household Work by Urban Homemaker (도시주부의 생활시간에 관한 연구)

  • 임정빈
    • Journal of the Korean Home Economics Association
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    • v.19 no.2
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    • pp.73-85
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    • 1981
  • The present trend is to classify time as a human resource. Time is considered as a human resource and refers not only to "clock time" that man possesses in equal amounts, but also to person's characteristic methods of assimilating and perceiving the passage of time. People differ in their ability to gauge the passage of time or to estimate the amount of time that an activity will take. The time used for household work by homemaker was analysed in that viewpoint. Specially the aim of this study was to find and analyse any differences from the style of house, the kind of fuel for cooking, the system of the family, the age and educated degree of homemaker and income degree. For analysis useable responses of 247 returned were used. The conclusion is as follows. 1. Homemakers spent 11.8∼13.4 hours for household work for a day. 2. Husband contributed 1∼1.4 hours, daughters and sons 0.6∼2.4 hours for household work a day. 3. There were large differences of the time spent on all food activities and care of clothes by the style of house and kitchen and the kind of fuel for coking. 4. The homemaker who has many children and preschool children spent much time for preparing the meal and care of clothes than others. 5. High educated homemaker spent less time for household work than others. 6. There are not any differences between time spent and income. 7. There are not also differences between time spent and having household equipment. It is assumed that many household equipment in the house aren't used effectively.

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추력 30톤급 연소기의 냉각 성능

  • Cho, Won-Kook;Lee, Soo-Yong;Cho, Gwang-Rae
    • Aerospace Engineering and Technology
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    • v.3 no.1
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    • pp.197-204
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    • 2004
  • A design of regenerative cooling system of 30 ton level thrust combustion chamber for ground test has been performed. The 1-D design code has been validated by comparing with the heat flux of the NAL calorimeter for high chamber pressure and water-cooling performance of the ECC engine of MOBIS. The present design code has been confirmed to predict accurately the heat flux and water-cooling performance for high chamber pressure condition. The maximum hot-gas-side wall temperature is predicted to be about 720 K without thermal barrier coating and the coolant-side wall temperature is less than the coking temperature of RP-1. The coolant temperature rises nearly 100 K with thermal barrier coating when Jet-A1 is used as coolant.

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Optimal Condition of Specific Impulse for a Liquid Rocket Engine with Film Cooling (막냉각이 적용된 액체로켓엔진의 비추력 최적조건)

  • Cho, Won-Kook;Park, Soon-Young;Seol, Woo-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.135-140
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    • 2007
  • An analysis has been conducted of the optimal condition to maximize the specific impulse for a liquid rocket engine with film cooling. The present engine performance has been compared with the published conceptual design to be verified satisfactorily accurate. The optimal combination of film coolant flow rate and the regenerative cooling capacity has been found for maximum specific impulse. The optimal fuel pump pressure increases and the optimal film coolant flow decreases for a larger thrust engine. Higher turbine inlet temperature increases both the fuel pump pressure and the film coolant flow rate as the optimal condition. The coking temperature has the same qualitative effect as the turbine inlet temperature.

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Mechanical Properties and Durability of Concrete Incorporating Air-Cooled Slag (서냉슬래그 미분말을 적용한 콘크리트의 역학적 성능 및 내구성 평가)

  • Lee, Seung-Tae;Park, Kwang-Pil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.3
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    • pp.356-363
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    • 2017
  • Blast furnace slag(BFS) is a by-product generated during the manufacture of pig ion, and is divided into water-cooled slag(WS) and air-cooled slag(AS) by the coking method of BFS. In this study, concrete specimens with ternary binders were produced at the various replacement levels of cement by AS. Various mechanical properties of concrete, such as compressive and split tensile strengths, absorption and water permeable pore, were measured. In addition, the chloride ions penetration resistance and carbonation resistance were tested to evaluate the durability of concrete incorporating AS. The experimental data indicated that the use of AS up to a maximum of 10% replacement level enhanced the concrete performance. However, a higher replacement of AS exhibited poor mechanical properties and concrete durability.