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http://dx.doi.org/10.7464/ksct.2017.23.3.314

Development of Monolithic Catalyst System with Co-Ru-Zr for CO2 (dry) Reforming of Methane : Enhanced Coke Tolerance  

Kim, Hyojin (Korea Research Institute of Chemical Technology)
You, Young-Woo (Korea Research Institute of Chemical Technology)
Heo, Iljeong (Korea Research Institute of Chemical Technology)
Chang, Tae-Sun (Korea Research Institute of Chemical Technology)
Hong, Ji Sook (Korea Research Institute of Chemical Technology)
Lee, Ki Bong (Korea University)
Suh, Jeong Kwon (Korea Research Institute of Chemical Technology)
Publication Information
Clean Technology / v.23, no.3, 2017 , pp. 314-324 More about this Journal
Abstract
To verify the viability of Co, Ru and Zr-based catalyst for $CO_2$ (dry) reforming reaction, catalysts were fabricated using cordierite, silicon carbide and rota monolithic substrates, and they were compared with the conventional $Co-Ru-Zr/SiO_2$ catalyst in terms of performance and durability. Cordierite monolith was showed high activity with the least amount of active component. In addition, when Cordierite monolith was coated with Co-Ru-Zr in various ways, most excellent performance was showed at a precursor solution coating method. In particular, when 0.9 wt% Co-Ru-Zr/Cordierite was used for reaction, it was observed that 95% $CO_2$ conversion was maintained for 300 h at $900^{\circ}C$.
Keywords
$CO_2$ reforming; Cobalt-ruthenium-zirconium; Monolith catalysts; Coking; Catalyst durability;
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