• Title/Summary/Keyword: Coated structure

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3-D Structured Cu2ZnSn (SxSe1-x)4 (CZTSSe) Thin Film Solar Cells by Mo Pattern using Photolithography (Mo 패턴을 이용한 3-D 구조의 Cu2ZnSn (SxSe1-x)4 (CZTSSe) 박막형 태양전지 제작)

  • Jo, Eunjin;Gang, Myeng Gil;Shin, hyeong ho;Yun, Jae Ho;Moon, Jong-ha;Kim, Jin Hyeok
    • Current Photovoltaic Research
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    • v.5 no.1
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    • pp.20-24
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    • 2017
  • Recently, three-dimensional (3D) light harvesting structures are highly attracted because of their high light harvesting capacity and charge collection efficiencies. In this study, we have fabricated $Cu_2ZnSn(S_xSe_{1-x})_4$ based 3D thin film solar cells on PR patterned Molybdenum (Mo) substrates using photolithography technique. Specifically, Mo patterns were deposited on PR patterned Mo substrates by sputtering and the thin Cu-Zn-Sn stacked layer was deposited over this Mo patterns by sputtering technique. The stacked Zn-Sn-Cu precursor thin films were sulfo-selenized to form CZTSSe pattern. Finally, CZTSSe absorbers were coated with thin CdS layer using chemical bath deposition and ZnO window layer was deposited over CZTSSe/CdS using DC sputtering technique. Fabricated 3-D solar cells were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF) analysis, Field-emission scanning electron microscopy (FE-SEM) to study their structural, compositional and morphological properties, respectively. The 3% efficiency is achieved for this kind of solar cell. Further efforts will be carried out to improve the performance of solar cell through various optimizations.

Effects of Curing Conditions on the Chemical Compositions of Positive Plate for Lead Acid Battery Plates (납축전지 극판의 숙성 조건이 양극판의 화학적 조성에 미치는 영향)

  • Ku, Bon-Keun;Jeong, Soon-Wook
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.4
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    • pp.347-354
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    • 2006
  • Generally, it has been known that positive plate efficiency is the most influential effect on the initial current capacity of lead acid battery. Thus, in this study, we have investigated the curing effect of the positive plate, which is one of the important lead acid battery processes. The curing process of the positive plate is performed either with the separation of each plate with 1mm gap or with no gap of plate. As a result, when there is no interval between each plate, the higher temperature current happened than expected, resulting in the changes in the initial current efficiency of the lead acid battery. The chemical composition and crystal structure of a material coated on the positive plate were identified with XRD and SEM. It was resulted that were only there not a lot of 4BS (tetrabasic-lead sulfate, $4PbO{\cdot}PbSO_4)$ on the plate in case of curing of plates without interval, but a large quantity of $Pb_3O_4$ also formed on the surface. On the other hand, it was observed that 3BS (tribasic-lead sulface, $3PbO{\cdot}PbSO_4{\cdot}H_2O)$ was the main product on the plate in case of typical curing process with some interval. From the initial current capacity test, the positive plate having 3BS was approximately 40% higher in initial current capacity than that having 4BS. It was concluded that 4BS and $Pb_3O_4$ on the plate surface were harmful to the initial current capacity of lead acid battery.

Synthesis and Catalytic Characteristics of Thermally Stable TiO2/Pt/SiO2 Hybrid Nanocatalysts (고온에서 안정적인 TiO2/Pt/SiO2 하이브리드 나노촉매의 제작 및 촉매 특성)

  • Reddy, A. Satyanarayana;Jung, Chan-Ho;Kim, Sun-Mi;Yun, Jung-Yeul;Park, Jeong-Young
    • Journal of Powder Materials
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    • v.18 no.6
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    • pp.532-537
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    • 2011
  • Thermally stable $TiO_2$/Pt/$SiO_2$ core-shell nanocatalyst has been synthesized by chemical processes. Citrated capped Pt nanoparticles were deposited on amine functionalized silica produced by Stober process. Ultrathin layer of titania was coated on Pt/$SiO_2$ for preventing sintering of the metal nanoparticles at high temperatures. Thermal stability of the metal-oxide hybrid catalyst was demonstrated heating the sample up to $600^{\circ}C$ in air and by investigating the morphology and integrity of the structure by transmission electron spectroscopy. The surface analysis of the constituent elements was performed by X-ray photoemission spectroscopy. The catalytic activity of the hybrid catalysts was investigated by CO oxidation reaction with oxygen as a model reaction.

Experimental Study on the Thermal Performance of a Domestic Solar Air Heater with Protruding Triangular Openings on the Absorber Plate (흡열판에 돌출형 삼각 개구부가 설치된 가정용 태양열 공기가열기의 열성능에 대한 실험적 연구)

  • Kim, Hyun Gon;Boo, Joon Hong
    • Journal of the Korean Solar Energy Society
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    • v.36 no.2
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    • pp.41-51
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    • 2016
  • A solar air heater was designed for supplementary domestic heating. The absorber plate had a series of protruding notches which had triangular openings on the front surface of the absorber plate to direct partial air flow to the rear surface and to enhance the convective heat transfer to the flowing air. The height of the opening as well as the opening configuration was determined by preceding numerical simulations. The experimental model had an absorber plate of 0.78-m width and 1.0-m length which was coated with black paint. The air temperature increased as much as $18^{\circ}C$ for $90-m^3/h$ flow rate when the absorber plate was inclined by $45^{\circ}$ for a clear-day solar irradiation of about $906W/m^2$. The collector efficiency ranged from 69 to 74%. Considering the simplicity of the structure and low manufacturing cost, the solar air heater might have competence as an auxiliary heating device for domestic use. On-site experimental results are presented with discussion for various solar irradiations and air flow conditions.

Assessing the Effects of Acrylic Resin (Paraloid B-72) on Buddhist Mural-painting conservation - Focusing on Outside Mural Paintings of Mireuk Hall in Geumsan Temple - (아크릴계 수지(Paraloid B-72)가 사찰벽화 보존에 미치는 영향에 관한 연구 - 금산사 미륵전 외벽화를 중심으로 -)

  • Lee, Kyeong-Min;Han, Kyeong-Soon;Lee, Hwa-Soo
    • 보존과학연구
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    • s.29
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    • pp.65-90
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    • 2008
  • This study examines the status and the physical features of Paraloid B-72 layers with examination of microstructure and analysis of organic matters. Paraloid B-72 layers were coated on samples from the colour layer of outer wall painting in Mireuk hall in Geumsan temple. On the basis of the previous examination result, it has made the samples which are similar to outer wall in Mireuk hall in Geumsan temple. The samples can be divided into two, one; 5% Paraloid B-72 coating and another is without coating. Then samples have been experimented under the compulsive environments of infrared radiation and immersion, thereafter compared the results of the damages and physical features between two samples. As a result of the comparison, the sample with Paraloid B-72 had more serious cracks, exfoliations and peeling layers than that of without Paraloid B-72. Otherwise, in the examination of ultraviolet radiation, the sample with Paraloid B-72 coating showed weaker physical properties, less density in structure of colour layer and less hardness in surface of colour layer than the sample without coating. The percentage of moisture content after the ultraviolet radiation was higher in the sample without Paraloid B-72 than the sample with Paraloid B-72 coating. Observing the conditions before the ultraviolet radiation, the sample with Paraloid B-72 coating demonstrated lower rate in moisture evaporation rate than the sample without Paraloid B-72. As a consequence, in examination of this samples, the change of physical features are increased in the sample with Paraloid B-72 coating than that without Paraloid B-72 when compulsive environment of heat, moisture and ultraviolet rays for a short term are imposed.

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Tin Sulphide Thin Films Formed by Sulphidising D.C. Magnetron Sputtered Layers of Tin Using $H_2S$ ($H_2S$ 가스를 이용한 황화주석 박막 증착에 관한 연구)

  • Leach, M.;Jang, D.Y.;Miles, R.
    • Tribology and Lubricants
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    • v.26 no.6
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    • pp.317-321
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    • 2010
  • Thin films of tin sulphide (SnS) have been formed by a novel 2-stage process where-in D.C. magnetron sputtering was used to deposit to thin films of tin (Sn) and the layers then sulphidised using 5% hydrogen sulphide ($H_2S$) gas in Argon. Although it was not found possible to deposit high quality thin films of tin directly onto glass substrates, excellent layers of tin were produced by using molybdenum (Mo) coated glass as the substrate material. The chemical and physical properties of the SnS layers formed were determined using scanning electron microscopy, energy dispersive x-ray analysis, x-ray diffraction studies and using reflectance versus wavelength measurements and these related to the conditions of synthesis. The data shows that it should be possible to produce conventional "substrate structure" devices based on the use of this technology.

Solar Energy Utilization in a Greenhouse Bulk Curing and Drying System(I) (Greenhouse Bulk건조기에 의한 태양열이용에 관한 연구 (제I보))

  • 진정의;이승철;이상하
    • Journal of the Korean Society of Tobacco Science
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    • v.2 no.1
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    • pp.61-67
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    • 1980
  • The greenhouse hulk curing and drying system utilizing the direct solar energy was tested to see how much fuel could be saved for curing flue-cured tobacco at the Daegu Experiment Station, Korea Tobacco Research Institute (North latitute: 35$^{\circ}$49'), in 1979. The structure consists of transparent fiberglass exterior, polyurethan boards covered with galvanized iron as the heat absorbers and insulation boards, air duct in which the air is introduced to the furnace room of bulk curing barn, and gravel heat storage system. All exterior surface of heat absorbers, air duct, and gravels were coated with black paint. The air temperature and total radiation were 20.5 to 35.5$^{\circ}C$ and 1004.2 to 1436.2 cal/$\textrm{cm}^2$ during the 3 replicated curing tests, respectively. The greenhouse bulk curing and drying system was able to cut fuel consumption by 25 percent compared with the conventional bulk curing barn. The maximum temperatures for the top absorber and the inlet air of the system were 89$^{\circ}C$ and 64$^{\circ}C$, respectively, and the average temperature of inlet air was higher than that of conventional one by 18$^{\circ}C$.

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THE HISTOLOGIC STUDY OF THE GRAFTED hBMP-I FOR IMMEDIATE IMPLANT FIXATION (발치 후 즉시 임플란트 식립시 이식된 hBMP-I의 조직학적 고찰)

  • Lee, Eun-Young;Kim, Kyoung-Won;Choi, Hee-Won;Um, In-Woong;Chung, Ho-Yong
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.30 no.4
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    • pp.316-322
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    • 2004
  • A low molecular weight component named bone morphogenetic protein(BMP) chemically isolated from the organic matrix of bone, induce postfetal connective tissue cells surrounding small blood vessels to differentiate into cartilage and bone. The end product of BMP is a spherical ossicle of lamella bone filled with red bone marrow for the functional loading. This is a important point that the graft material is embedded the defect site during the implant surgery. Because present knowledge of the relationship between BMP and bone regeneration arises mainly from studies of induced bone formation in heterotopic sites, it would be helpful to determine whether BMP plays any part in the process of bone healing. The BMPs have been shown to play crucial roles in normal skeletal development as well as bone healing and are able to activate transcription of genes involved in cellular migration, proliferation, and differentiation. The delivery of BMP on matrices has been efficacious in the treatment of defect bone in implant surgery. The purpose of the histologic study was to evaluate the effect of DLB(demineralized lyophilized bone) coated with purified human BMP(hBMP-I) in immediate implant surgery with bony defect to obtain the functional structure of implant asap. The ability of a graft of hBMP-I to accelerate bony defect repair provides a rationale for its use in immediate implant surgery that have large bone defect in edentulous area.

Syntheses of Improved Polymer/Organic Materials for Electroluminescence(EL) Device and Electro-Optical Characteristics(Ⅱ) Properties of EL Device using Squarylium Dye as Emitting Material (고기능 EL소자용 고분자/유기 재료의 합성 및 전기 광학적 특성(Ⅱ) Squarylium 색소를 이용한 EL소자의 특성)

  • Kim, Sung Hoon;Bae, Jin Seok;Hwang, Seok Hwan;Park, Lee Soon
    • Journal of the Korean Chemical Society
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    • v.41 no.3
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    • pp.144-149
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    • 1997
  • Organic electroluminescence devices(ELD) were fabricated using by molecularly doped method with N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine(TPD) as a hole transport agent, squarylium dye as an emitting agent, and side chain liquid crystalline polymer(MCH) as matrix for TPD. An indium-tin-oxide(ITO) coated glass and an Mg electrode were used as the hole and the electron injecting electrode, respectively. The highest stability of ELD was obtained by spin coating method using dichloroethane as a solvent at a polymer/TPD concentration of 0.005 wt%. For the EL cell with ITO/polymer-TPD/SQ dye/Mg structure, we achieved light red luminescence at a current of 102 mA/$cm^2$ with an applied voltage of 23 V.

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Microstructures of HAp and HAp-Ag Composite Coating Layer Prepared by RS Magnetron Sputtering (RE Magnetron Sputtering에 의해 제조된 HAp와 HAp-Ag복합코팅층의 미세조직)

  • Lee, Hee-Jung;Oh, Ik-Hyun;Park, Sang-Shik;Lee, Byong-Taek
    • Journal of the Korean Ceramic Society
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    • v.41 no.4
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    • pp.328-333
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    • 2004
  • Hydroxyapatite (HAp) and HAp-Ag composite layers were coated on ZrO$_2$and Si wafer substrates by RF magnetron sputtering technique. The thickness of coating layers was in the range of 0.7∼1.0$\mu\textrm{m}$ and its roughness was 3∼4nm. The heat treated HAp coating layers were composed with nano-sized crystallines. However, the HAp-Ag composite layers showed the mixed structure with crystalline and amorphous phases. The Ca/P ratio of the as-received HAp coating layer was 1.9, but, the value was decreased as the Ag content with increased. Also, the Vickers hardness of HAp coating layer decreased as the Ag content increase.