• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2015년도 춘계학술대회
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• pp.179-180
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• 2015

The variety of organic and inorganic pollutants are introduced to coastal sediment and making highly contaminated due to rapid development of industralization and economic development. Numerous contaminants are release into marine sediment and it significantly affect marine aquatic environment. In the present study stated the optimize the biostimulant ball (BSB) in coastal sedimentand stabilse the heavy metals present in the sediment. The effective variables like BSB size, distance and month variables on Cu stabilization was determined by using Response surface methodology(RSM). The analysis of variance (ANOVA) and coefficient determination (R2) of Cu reduction 0.9610 and maximum stabilisation was obtained in 3cm ball size and 5.5cm distance and 4 month interval time. This result revealed that the BSB in effective for Cu reduction in coastal sediment.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2014년도 추계학술대회
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• pp.87-88
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• 2014

The Coastal sediment is highly contaminated due to ship transportation, industries discharges and urban sources. Various contaminants release into seawater and settle in marine sediment and it significantly affect marine eco system. In the present study evaluated the optimization of slow release biostimulant ball (BSB) in coastal sediment in busan. The effective variables like BSB size, distance and month variables on VS reduction was determined by using Response surface methodology(RSM). The analysis of variance (ANOVA) and coefficient determination (R2) of VS was 0.9369 and maximum reduction of VS was obtained in 3cm ball size and 5.5cm distance and 4 month interval time. This result revealed that the BSB in effective VS reduction in coastal sediment.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2016년도 춘계학술대회
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• pp.130-131
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• 2016

Although many metals contaminated sediment from coastal area contain both anionic and cationic heavy metals, the current remediation technologies are not effective for stabilize heavy metals of both anionic and cationic elements from contaminated coastal region. the present work investigated the efficiency and mechanism of immobilization of Fe, Zn, Cr, Cu, Pb and Cd metal solutions in modified zeolite based biostimulant ball. Biostimulant ball containing acetate, nitrate and sulphate which are enhance the activity of marine microorganisms and it can act as electron donors and electron acceptors. Modified zeolite and chelating agent is greatly enhance the metal stabilization due to increased immobility of the analysed metals. The XRD, FT-IR and SEM of modified zeolite which cheating agents containing heavy metals were investigated. The results indicated that heavy metals could be effectively immobilized in modified zeolite and chelating agents in BSB added sediment. The immobilization of heavy metals in modified zeolite and chelating agents along with BSB could be due to stabilize of heavy metal cations. Immobilization of heavy metals using BSB with modified zeolite and chelating agent has lower cost effect and enhance the sediment quality.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2015년도 춘계학술대회
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• pp.177-178
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• 2015

Sediments play a major role in determining pollution pattern in aquatic systems and reflecting the pollutant deposition. In the present study analysis the depth effect of organic pollutants and heavy metals using slow release biostimulant ball (BSB) in coastal sediment. BSB size fixed at 3cm, depth varied from 0cm to 10cm depth and 1 and 3 month interval period was carried out for the study. The organic pollutants of chemical oxygen demand, total solids and volatile solids were significantly changed at the surface sediment (0cm)in 1 month and 3 month interval time using BSB. In contrast, sediment depth increase upto 10cm the reduction percentage decrease like to control. Vertical distribution of heavy metals are not consistent from the surface layer toward the bottom layers. Heavy metals fractions were significantly changes, the exchangeable fraction was reduced and other organic and residual fractions were stabilized percentage are increased. This finding concluded BSB is effective for reduce organic pollutants, heavy metals stabilization from the contaminated sediment.

• 해양환경안전학회지
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• 제25권7호
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• pp.914-919
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• 2019

알칼리성 산업부산물의 혼합에 따른 연안 오염퇴적물의 성상 변화를 평가하기 위해 해수 교환을 고려한 mesocosm 실험을 수행하였다. 실험시작 1개월 후 실험구의 인산인 농도는 대조구 대비 간극수와 직상수에서 각각 19.0, 0.4 mg/L 낮게 검출되었다. 이는 GCA에서 용출된 칼슘이온과 인산인의 흡착반응을 통한 간극수 내의 인 고정 및 직상수로의 용출 억제에 따른 결과로 판단된다. 실험구의 간극수 내 황화수소 농도는 5.0 mg/L로 112.5 mg/L인 대조구에 비해 매우 낮게 나타났으며, 실험구 직상수의 DO 농도는 대조구에 비해 3.47 mg/L 높게 나타났다. 이상의 결과로부터 알칼리성 산업부산물인 GCA는 연안 오염퇴적물의 개선에 효과적인 재료임을 확인하였다.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2014년도 추계학술대회
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• pp.83-84
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• 2014

생물활성촉진제를 이용하여 연안 오염저질의 정화 효율을 평가하기 위하여 해역에서 칼럼 실험을 수행하였다. 오염도가 낮은 해양저질에 황산염, 질산염 및 아세테이트 등의 생물활성물질을 첨가하여 작은 볼 형태로 만들었으며, 생물활성촉진물질의 용출율을 조절하기 위하여 볼 표면을 폴리머(Cellulose acetate, CA and Polysufone, PS)로 코팅한 생물활성촉진제를 제작하였다. 생물활성촉진제를 연안에서 채취한 오염저질과 혼합한 후 컬럼에 주입하여 연안의 수중에 침지시켰으며, 시간에 따른 오염물질의 변화특성을 평가하였다. pH는 실험 종료일 까지 큰 변화 없이 약 7.6~8로 유지되었으며, COD, TP, TN농도변화는 생물활성촉진제를 투여한 칼럼에서 더 낮게 평가되었다. 중금속(Fe, Zn, Cd, Cr, Pb, Cu) 분포는 생물활성촉진제를 투여한 칼럼에서 매우 안정적인 형태로 변환되었으며, PS 코팅 생물활성촉진제를 투여한 칼럼이 유무기 오염물질 정화에 더 효과적인 것으로 평가되었다.

• 한국수산과학회지
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• 제46권5호
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• pp.626-637
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• 2013

We measured the grain size, ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS) and trace metals (Al, Fe, Cu, Pb, Zn, Cd, Cr, Mn, Hg, and As) of intertidal surface sediment collected from 11 islands (62 stations) in the southern region of Jeollanam Province. The objective of this research was to evaluate the organic matter and trace metals contaminations of sediments from coastal island tidal flats. Surface sediment texture was characterized as follows: mud, sandy silt, muddy sand, and slightly gravelly sand facies. The finer sediments are mainly dominated in the northern part of each island. The concentrations of IL, COD, AVS and some trace metals (Al, Fe, Zn, Cr, Cu, and Hg) were higher in the northwestern part of Wan Island and the area between Gogeum and Sinji Islands, and were associated with relatively finer sediment, as compared to other locations. The concentrations of Mn, Pb, Cd, and As were higher in the northwestern and southeastern parts of Geoguem and Pyungil Islands, but were not correlated with mean grain size. Based on sediment quality guidelines (SQGs), the concentrations of trace metals were lower than the values of effect range low (ERL), used in United States, and threshold effects level (TEL), used in Korea, with exception of As. Similarly, the intertidal sediments were moderately contaminated with As, based on the the enrichment factor (EF) and the geoaccumulation index ($I_{geo}$). The high concentration of As in intertidal sediments from this study region may be due to the input of naturally or artificially contaminated submarine groundwater, contaminated waste from seaweed aquaculture operations and/or land-based seaweed processing facilities. Further studies are needed to identify the sources of As in this study region, and to determine the effects of As contamination on coastal ecosystem.

• 한국환경과학회지
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• 제12권10호
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• pp.1121-1129
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• 2003

We report the distributions of Sb and As in the surface sediment of the Yellow Sea and the coastal areas of Korea. The mean concentrations of Sb and As range from 0.68 ppm to 1.01 ppm and from 7.4 ppm to 15.8 ppm, respectively, and show relatively the high concentrations at the coast of Weolseong in the East Sea for Sb and at the coast of Gadeok Island in the South Sea far As. This may be due to the anthropogenic input of these elements via river and atmosphere from industry complex and agriculture regions around the study areas. Because of the difference of clay to silt proportion, the correlation between silt plus clay contents and Sb, As in the coastal surface sediment of Korea is not shown, the concentrations of Sb and As vary widely for the sample in which the silt plus clay contents are the same. Therefore, we suggest that the distribution patterns of Sb and As in surface sediment of the Yellow Sea and the coastal areas of Korea are mainly controlled by the anthropogenic inputs and the sediment characteristics. On the other hand, the Sb concentrations are lower than those of the lowest effect level which is the standard of judgment for contamination, while the As concentrations are higher than those of the lowest effect level. This implies that the surface sediments of the Yellow Sea and the coastal areas of Korea are considerably contaminated for As.

• 한국항해항만학회지
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• 제39권4호
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• pp.345-351
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• 2015

실험실 규모의 관 실험을 통하여 연안오염퇴적물의 생물정화 효능에 대한 생물활성촉진제 주입 깊이의 영향을 평가하였다. 생물활성촉진제를 실험관에 충진 된 오염퇴적물의 표면과 표면으로부터 3cm, 6cm, 10cm 위치에 주입한 후 1개월 및 3개월 후 퇴적물의 유기물 및 중금속의 특성 변화를 조사하였다. 시험 오염퇴적물의 화학적 산소요구량, 총고형물 및 휘발성고형물 함량은 생물활성촉진제를 주입하지 않은 대조구에 비해 1개월 후 및 3개월 후에서 크게 감소하였으며, 생물활성촉진제 주입 깊이 3cm에서 최대값을 보였다. 그러나, 오염퇴적물에 주입한 생물활성촉진제의 깊이를 6cm 및 10cm로 증가하였을 때 유기오염물질 감량정도는 점차 감소하였다. 중금속 존재형태변화는 생물활성촉진제 주입 깊이 3cm에서 안정한 형태인 유기물 결합분율과 광물내 잔류분율이 현저하게 증가하였다. 오염퇴적물의 현장생물정화를 위한 최적의 생물활성촉진제 주입 깊이는 퇴적물의 상부 표면으로부터 3cm로 평가되었다.

• Fisheries and Aquatic Sciences
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• 제13권3호
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• pp.244-253
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• 2010

The quality of marine sediments from the industrialized coastal areas of Korea (Ulsan Bay, Masan Bay, and artificial Lake Shihwa) was investigated using a bacterial bioluminescence toxicity test. Sediment toxicity results were compared with the levels of chemical contamination (trace metals, organic wastewater markers, acid volatile sulfides, total organic carbon). Effective concentration 50% (EC50) of sediments ranged from 0.014 to 1.126 mg/mL, which is comparable to or lower than values in contaminated lakes, rivers, and marine sediments of other countries. Sediment reference index (SRI) ranged from 13 to 1044, based on the EC50 of the negative control sample. Mean average SRI values in Masan Bay and Lake Shihwa were approximately 8 and 9 times as high as that in Ulsan Bay, indicating higher sediment toxicity and greater contamination in the two former regions. Sediment toxicity were strongly associated with the concentrations of some chemicals, suggesting that this test may be useful for determining potential chemical contamination in sediments.