• 자원리싸이클링
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• 제29권6호
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• pp.125-132
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• 2020

국내 순환유동층보일러형 발전소 석탄재의 주요 광물 및 희토류의 이동특성을 분석하여 석탄재 중 희토류 성분의 농축 가능성 검토를 위해 체 분리 및 침출을 통한 주요 광물의 분리 및 제거에 따른 희토류 성분의 이동특성을 평가하였다. 석탄재의 주요 광물로는 경석고, 자철석 및 석영으로 확인되었으며, 세계 석탄재 희토류 평균값(404 ppm)의 30% 수준 함량으로 확인되었다(실험대상: 123 ppm). 석탄재에 포함된 희토류 성분 중 90% 이상은 주로 자철석과 함께 이동하는 특성을 보였고, 10% 이하의 성분이 석영과 함께 이동하는 것으로 확인되었다. 이는 발전소 연소 방식 차이에 따라 발생된 석탄재 특성에 따른 영향으로 판단된다. 이에 국내 순환유동층보일러 석탄재로부터 희토류 성분 농축을 위해서는 자철석 분리가 필요하며, 이와 관련된 선별 기술 개발 및 확보가 요구된다고 판단된다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.621-627
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• 2001

Recycling of coal combustion by-product(Ash) are becoming more important in the utilization business as a result of the increased use of NOx reduction technologies at coal-fired power plants. current disposal methods of these by-products create not only a loss of profit for the power industry, but also environmental concerns that breed negative public opinion. Since inherent characteristics make these by-product suitable for building materials, several types of artificial aggregates and construction bricks are manufactured and tested to verify the engineering properties.

• 한국연소학회지
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• 제11권4호
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• pp.22-26
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• 2006

To meet the environmental requirements, Doosan Heavy Industries & Construction Co., Ltd. (Doosan) had developed low NOx pulverized coal burner and it was applied to boiler retrofit project, 130 ton/hr coal fired cogeneration boiler, in 2003. NOx emissionand unburned carbon (UBC) in fly ash were measured during the commissioning tests. In this paper, the operation results of low NOx pulverized coal burner installed in 130 ton/hr coal fired boiler are presented. Burners emitted 160 ppm (@6 % $O_2$ basis) NOx and 3 % UBC with Chinacoal containing 0.86 % fuel nitrogen. And also it was shown that NOx emission rate of low NOx pulverized coal burner is linearly increased with fuel-nitrogen fraction of coal.

• 한국세라믹학회지
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• 제53권3호
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• pp.354-361
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• 2016

The purpose of this study was to prepare lightweight foamed concrete by mixing coal fly ash of circulating fluidized bed combustion(CFBC) with cement, and to develop uses for recycling by analyzing carbonation behavior resulting from a change in conditions for pressurized carbonation. For concrete, CFBC coal fly ash was mixed with Portland cement to the water-binder ratio of 0.5, and aging was applied at room temperature after 3 days of curing at $20^{\circ}C$, RH 60%. For carbonation, temperature was fixed at $60^{\circ}C$ and time at 1 h in the use of autoclave. Pressures were controlled to be $5kgf/cm^2$ and the supercritical condition of $80kgf/cm^2$, and gas compositions were employed as $CO_2$ 100% and $CO_2$ 15%+N2 85%. In the characteristics of produced lightweight concrete, the characteristics of lightweight foamed concrete resulting from carbonation reaction were affirmed through rate of weight change, carbonation depth test, air permeability, and processing analysis for the day 28 specimen. Based on these results, it is concluded that the present approach could provide a viable method for mass production of eco-friendly lightweight foamed concrete from CFBC coal fly ash stabilized by carbonation.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
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• pp.103-112
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• 1997

In the combustion of the pulverized coal compared with that of liquid fuel or gaseous fuel, serious pollutants such as ash, $NO_x$ and $SO_x$ are released to surroundings. The objective of this study is the reduction of such pollutants in the combustion process. The modeling of cyclone combustor which uses the method of two stage combustion was carried out. The main burner length, scattering angle and air/fuel ratio were considered as parameters. The results show that the shorter the main burner length is, the less the amounts of coals which exit the combustor directly are, but the scattered input of coal is required anyway in order to collect all ashes. It is recommended that the shorter the main burner length is, the less the scattering angle is. And in the case of the scattered input compared with no scattering, the temperature in the combustor is more uniform and the amount of volatile is more reduced.

• 청정기술
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• 제20권3호
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• pp.298-305
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• 2014

석탄에 포함되어 있는 회분은 환경오염을 유발시킬 수 있으며, 고온에서 운전되는 발전 설비에 융착되어 열전달 효율을 저하시키는 문제점을 가지고 있다. 이러한 문제를 해결하기 위해서 알칼리나 산, 또는 유기 용매를 이용하여 석탄 내의 회분을 제거하기 위한 연구와 함께 무회분 석탄을 이용한 석탄화력 발전 및 석탄가스화 복합발전에 대한 타당성 연구가 활발히 진행 중이다. 따라서 본 연구에서는 200 ppm급 무회분 석탄을 석탄가스화 발전에 이용하기 위해서 필요한 가스화기 운전조건을 ASPEN $Plus^{(R)}$ 공정모사의 민감도 해석을 바탕으로 도출하였다. 특히 석탄가스화 공정은 열분해, 휘발분 연소, 촤 가스화 공정으로 나누어 해석을 진행하였으며, 1.5 톤일급 비용융(non-slagging) 가스화기의 크기 및 운전 조건을 반영하여 모델링 하였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.1015-1020
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• 2002

Recycling of coal combustion by-product(Ash) are becoming more improtant in the utilization business as a result of the increased use of NOx reduction technologies at coal-fired power plants. Current disposal methods of these by-products create not only a loss of profit for the power industry, but also environmental concerns that breed negative public opinion. This research made Precast block for environment-friendly secondary product and compare strength special quality of this block with existent common use brick and analyze application possibility in situ with a reserve experiment that measure strength property and manufacture method to handle coal ash produced in Bo-ryung thermoelectric power plant.

• 한국구조물진단유지관리공학회 논문집
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• 제17권3호
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• pp.108-117
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• 2013

석탄화력 발전의 부산물 중에서 플라이애쉬는 콘크리트 혼화재료로서 많은 공학적 장점을 가지고 있으므로 다양하게 활용되고 있다. 그러나 바텀 애쉬를 포함한 나머지 부산물 등은 주로 매립되어 공학적 활용성이 떨어진다. 본 연구에서는 매립된 부산물인 매립회 (PA: Pond Ash)를 이용하여 시멘트 모르타르를 제조하였으며, 매립회 시멘트 모르타르의 공학적 특성을 평가하였다. 이를 위해 두 매립지로부터 유연탄 및 무연탄 매립회를 채취하였으며, 2가지 물-시멘트 비 (0.385, 0.485)와 3가지 잔골재 치환률 (0%, 30%, 60%)을 고려하여 시공성, 역학성능, 내구성능을 평가하였다. 흡수율이 높은 무연탄 매립회의 경우, 적절한 시공성, 우수한 강도발현과 내구성능을 확보하였는데, 매끈한 표면과 내부의 풍부한 자유수로 인해 조직구조가 치밀한 시멘트 모르타르가 제조되었기 때문이다. 매립회 중에서도 우수한 성능을 가진 무연탄 매립회의 경우 일반 잔골재의 성능을 확보하고 있으므로, 자원의 재활용이 가능하리라 판단된다.

• 공업화학
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• 제5권2호
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• pp.337-344
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• 1994

높은 연소효율과 환경오염물질을 적게 배출하는 75kw급 소형 접선방향 연료주입식 수직형 사이클론 연소기를 이용하여 성상이 다른 수입 유연탄(역청탄, 아역청탄)을 시료로 하여 공기비 0.4~1.6 범위에서 각각의 연소 특성 및 연소 후 회분의 포집효율을 조사하였다. 로 내 온도 분포는 전영역에서 역청탄이 아역청탄보다 약 $100^{\circ}C$ 이상 높게 나타났고 로 내에서는 로 하부와 축선이 높게 나타났다.

• Asian Journal of Atmospheric Environment
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• 제2권2호
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• pp.102-108
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• 2008

In China, energy and environmental problems are becoming serious owing to rapid economic development. Coal is the most problematic energy source because it causes indoor and outdoor air pollution, acid rain, and global warming. One type of clean coal technology that has been developed is the coal-biomass briquette (or bio-briquette, BB) technique. BBs, which are produced from pulverized coal, biomass (typically, agricultural waste), and a sulfur fixation agent (slaked lime, $Ca(OH)_2$) under high pressure without any binder, have a high sulfur-fixation effect. In addition, BB combustion ash, that is, the waste material, can be used as a neutralization agent for acidic soil because of its high alkalinity, which originates from the added slaked lime. In this study, we evaluated the suitability of alternative biomass sources, namely, aquatic plants, as a BB constituent from the perspective of their use as a source of energy. We selected three types of aquatic plants for use in BB preparation and compared the fuel, handling, and environmental characteristics of the new BBs with those of conventional BBs. Our results showed that air-dried aquatic plants had a higher calorific value, which was in proportion to their carbon content, than agricultural waste biomass; the compressive strength of the new BBs, which depends on the lignin content of the biomass, was high enough to bear long-range intracontinental transport in China; and the new BBs had the same emission control capacity as the conventional BBs.