• Journal of the Korean Applied Science and Technology
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• v.19 no.4
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• pp.265-272
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• 2002

$CaCO_{3}$ absorbed sodium lauryl sulfate (SLS) surfactant was prepared, Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using styrene(St) as a shell monomer and potasium persulfate (KPS) as an initiator, We found that when $CaCO_{3}$; core prepared by adding 2,0 wt% SLS, $CaCO_{3}$ core/PSt shell polymerization was carried out on the surface of $CaCO_{3}$ particle without forming the new PSt particle during St shell polymerization in the inorganic/organic core-shell polymer preparation, The structure of core-shell polymer were investigated by measuring the degree of decomposition of $CaCO_{3}$ using HCl solution, thermal decomposition of polymer composite using thermogravimetric analyzer and morphology by scanning electron microscope.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.11a
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• pp.666-670
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• 2004

VLSI 소자에서 design rule(D/R)이 작아져 각 단위 Pattern의 size가 작아짐에 따라 aspect ratio가 커지게 되었다. 산화막 contact etch를 하는데 있어 산화막 측벽을 보호하는데, 이러한 보호막은 주로 fluoro-carbon 계열의 polymer precursor들이 사용된다. Aspect ratio(A/R)가 5 이하일 때에는 측벽의 보호막에 의한 바닥 변형이 문제가 되지 않으나, 10 이상의 A/R를 가진 contact에서는 크기가 줄고, 모양이 불균형하게 변하는 바닥 변형을 쉴게 관찰할 수 있다. 이러한 바닥 변형이 커지면 contact 저항이 높아지는 것은 물론이고, 심하게는 하부 pattern과 overlap 불량을 유발할 수 있다. 본 논문에서는 바닥변형을 일으키는 원인을 분석하고 fluoro-carbon 계열의 polymer precursor의 종류$(C_4_F6\;vs.\;C_3F_8)$에 따른 polymer증착 상태 확인 및 pattern비대칭에 따른 바닥 변형의 고찰과 plasma etching 시 H/W 변형을 통해 바닥 변형이 거의 없는 조건을 찾아낼 수 있었다.

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.486-488
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• 2009

High efficiency deep blue and pure white phosphorescent organic light emitting diodes were developed using a new deep blue phosphorescent dopant, tris((3,5-difluoro-4-cyanophenyl)pyridine) iridium (FCNIr). A high quantum efficiency of 9.1 % with a color coordinate of (0.15, 0.16) at 1,000 cd/$m^2$ was obtained in the deep blue device and a high quantum efficiency of 15.2 % with a color coordinate (0.30, 0.32) was obtained in the pure white organic light-emitting diodes. The quantum efficiency of the pure white device is the best quantum efficiency value reported in the pure white device up to now.

• Nano
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• v.13 no.12
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• pp.1850139.1-1850139.10
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• 2018

$Co_3O_4$ nanocrystals have been synthesized via an ordinary one-step calcination of a cobalt-based 2D coordination polymer [Co(tfbdc)(4,4'-bpy)$(H_2O)_2$]. As an anode material for lithium-ion batteries, the obtained $Co_3O_4$ nanocrystals exhibit high reversible capacity, excellent cyclic stability and better rate capability. The reversible capacity of the $Co_3O_4$ nanocrystals maintains $713mA\;h\;g^{-1}$ after 50 cycles at a current density of $50mA\;g^{-1}$. Our results confirm that searching for metal oxides nanomaterials used as anode materials of lithium ion batteries via the calcinations of 2D coordination polymer is a new route.

• Journal of the Korean Chemical Society
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• v.55 no.5
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• pp.808-811
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• 2011

A new catalytic system has been developed in the synthesis of 2-amino-5-nitro-4,6-diarylcyclohex-1-ene-1,3,3-tricarbonitriles using carbonate on polymer support (Amberlyst A-26 $NaCO_3{^-}$). Short reaction time, simplicity of isolation, safe catalyst and high yields of product are the features.

• Journal of Electrochemical Science and Technology
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• v.10 no.2
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• pp.250-255
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• 2019

Poly(ethylene oxide) (PEO)-based solid polymer electrolytes (SPEs) show promise for improving the lithium ion battery safety. However, due to oxidation of the PEO group and corrosion of the Al current collector, PEO-based SPEs have not previously been effective for use in $LiCoO_2$ (LCO) cathode materials at room temperature. In this paper, a semi-interpenetrating polymer network (semi-IPN) PEO-based SPE was applied to examine the performance of a LCO/SPE/Li metal cell at different voltage ranges. The results indicate that the SPE can be applied to LCO-based lithium polymer batteries with high electrochemical performance. By using a carbon-coated aluminum current collector, the Al corrosion was mostly suppressed during cycling, resulting in improvement of the cell cycle stability.

• Journal of the Korean Electrochemical Society
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• v.13 no.2
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• pp.110-115
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• 2010

The plasticized polymer electrolytes based on polyvinylidene fluoride-co-hexafluoropropylene (P(VdF-co-HFP)), tetra (ethylene glycol) dimethyl ether (TEGDME), and lithium perchlorate ($LiClO_4$) are prepared for the lithium sulfur batteries by solution casting with a doctor-blade. The polymer electrolyte with EO : Li ratio of 16 : 1 shows the maximum ionic conductivity, $6.5\;{\times}\;10^{-4}\;S/cm$ at room temperature. To understand the effect of the salt concentration on the electrochemical performance, the polymer electrolytes are characterized using electrochemical impedance spectroscopy (EIS), infrared spectroscopy (IR), viscometer, and differential scanning calorimeter (DSC). The optimum concentration and mobility of the charge carriers could lead to enhance the utilization of sulfur active materials and the cyclability of the Li/S unit cell.

• Journal of Electrochemical Science and Technology
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• v.14 no.2
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• pp.139-144
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• 2023

In this study, carbon-coated porous nanofibers were prepared via electrospinning and the performance of Li[Ni_0.93Co_0.07]O₂ (NC) synthesized by electrospinning (E-NC) and co-precipitation (C-NC) was compared. E-NC had a discharge capacity of 206 mAh g^-1 at 0.1C (17 mA/g), which is 10% higher than that of C-NC (189.2 mAh g^-1). E-NC shows a high-rate performance of 118.32 mAh g^-1 (61.7%) at 5C (850 mA/g), which is 50% higher than that of C-NC (78.22 mAh g^-1 = 45.7%). Charge transfer of the carbon-coated porous nanofiber E-NC decreased by 35% compared to C-NC after 20 cycles as observed using electrochemical impedance spectroscopy. The results of this study show that the nanofiber structure with carbon coating shortens the Li-ion diffusion path, improves electrical conductivity, resulting in excellent rate performance.

• KSBB Journal
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• v.22 no.3
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• pp.146-150
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• 2007

Poly(3-hydroxybutyrate-co-4-hydroxybutyrate) [P(3HB-co-4HB)] microspheres were prepared using solvent evaporation technique. P(3HB-co-4HB) with 3.9 mol% 4HB was synthesized by fed-batch culture of Ralstonia eutropha. The effects of concentration and type of surfactant (Tween 80, sodium dodecylsulfate, and polyvinyl alcohol), addition of dispersion stabilizer (Acacia), concentration of polymer and model drug (bovine serum albumin) on particle size of the microspheres and their in vitro drug release characteristics were investigated. The average particle size of the microspheres decreased with the addition of dispersion stabilizer and increased with the concentration of surfactant, drug and polymer. Amount of drug release increased with decreasing particle size of the microspheres.

• International Journal of Precision Engineering and Manufacturing
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• v.9 no.4
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• pp.71-73
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• 2008

The development of polymer/inorganic nanocomposites has attracted a great deal of interest due to the improved hybrid properties derived from the two different components. Various nanoscale fillers have been used to enhance polymer mechanical and thermal properties, such as toughness, stiffness, and heat resistance. The effects of the filler on the final properties of the nanocomposites are highly dependent on the filler shape, particle size, aggregate size, surface characteristics, polymer/inorganic interactions, and degree of dispersion. In this paper, we describe the influence of different $CaCO_3$ dispersion methods on the thermal properties of polyethylene terephthalate (PET)/$CaCO_3$ composites: i.e., the adsorption of $CaCO_3$ on the modified PET surface, and the hydrophobic modification of the hydrophilic $CaCO_3$ surface. We prepared PET/$CaCO_3$ nanocomposites using a twin-screw extruder, and investigated their thermal properties and morphology.