Nano

SKKU Advanced Institute of Nano Technology (성균관대학교 성균나노과학기술원)
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2D Coordination Polymer Derived Co3O4 Nanocrystals as High Performance Anode Material of Lithium-Ion Batteries

  • Wen, Hao (School of Petrochemical Engineering and Jiangsu Key Laboratory of Fine Petro-chemical Technology Changzhou University) ;
  • Shi, Changdong (School of Petrochemical Engineering and Jiangsu Key Laboratory of Fine Petro-chemical Technology Changzhou University) ;
  • Gao, Yuanrui (Department of Chemistry, College of Science Shanghai University) ;
  • Rong, Hongren (School of Petrochemical Engineering and Jiangsu Key Laboratory of Fine Petro-chemical Technology Changzhou University) ;
  • Sha, Yanyong (School of Petrochemical Engineering and Jiangsu Key Laboratory of Fine Petro-chemical Technology Changzhou University) ;
  • Liu, Hongjiang (Department of Chemistry, College of Science Shanghai University) ;
  • Liu, Qi (School of Petrochemical Engineering and Jiangsu Key Laboratory of Fine Petro-chemical Technology Changzhou University)
  • Received : 2018.07.09
  • Accepted : 2018.10.30
  • Published : 2018.12.31
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Abstract

$Co_3O_4$ nanocrystals have been synthesized via an ordinary one-step calcination of a cobalt-based 2D coordination polymer [Co(tfbdc)(4,4'-bpy)$(H_2O)_2$]. As an anode material for lithium-ion batteries, the obtained $Co_3O_4$ nanocrystals exhibit high reversible capacity, excellent cyclic stability and better rate capability. The reversible capacity of the $Co_3O_4$ nanocrystals maintains $713mA\;h\;g^{-1}$ after 50 cycles at a current density of $50mA\;g^{-1}$. Our results confirm that searching for metal oxides nanomaterials used as anode materials of lithium ion batteries via the calcinations of 2D coordination polymer is a new route.

Keywords

Acknowledgement

Supported by : National Natural Science Foundation of China, Jiangsu Colleges and Universities

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