• Title/Summary/Keyword: Co-contaminants

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An Experimental Study on Oil Separation Characteristics of $CO_2$/P AG Oil Mixture in an Oil Separator

  • Kang, Byung-Ha;Kim, Kyung-Jae;Lee, Sung-Kwang
    • International Journal of Air-Conditioning and Refrigeration
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    • v.17 no.3
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    • pp.88-93
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    • 2009
  • Lubricant oil is needed in air conditioning and refrigeration system because the compressor requires oil to prevent surface to surface contact between its moving parts, to remove heat, to provide sealing, to keep out contaminants, to prevent corrosion, and to dispose of debris created by wear. Thus, the oil separation in an oil separator is one of the most important characteristics for proper compressor operation. In this study, a gravity type of oil separator is used. Oil separation characteristics have been investigated for $CO_2$/PAG mixture in the range of oil concentration 0 to 5 weight-percent and the mixture temperature range of $0^{\circ}C$ to $15^{\circ}C$ at 50 bar and $70^{\circ}C$ to $90^{\circ}C$ at 80 bar. The results obtained indicate that the oil separation is increased with an increase in the oil concentration. It is also found that the oil separation in liquid state is increased with an increase in the mixture temperature while the oil separation in gas state is decreased.

Adsorptive and kinetic studies of toxic metal ions from contaminated water by functionalized silica

  • Kumar, Rajesh;Verma, Sunita;Harwani, Geeta;Patidar, Deepesh;Mishra, Sanjit
    • Membrane and Water Treatment
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    • v.13 no.5
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    • pp.227-233
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    • 2022
  • The objective of the study, to develop adsorbent based purifier for removal of radiological and nuclear contaminants from contaminated water. In this regard, 3-aminopropyl silica functionalized with ethylenediamine tetraacetic acid (APS-EDTA) adsorbent prepared and characterized by Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD). Prepared APS-EDTA used for adsorptive studies of Cs(I), Co(II), Sr(II), Ni(II) and Cd(II) from contaminated water. The effect on adsorption of various parameters viz. contact time, initial concentration of metal ions and pH were also analyzed. The batch method has been employed using metal ions in solution from 1000-10000 ㎍/L, contact time 5-60 min., pH 4-10 and material quantities 50-200 mg at room temperature. The obtained adsorption data were used for drawing Freundlich and Langmuir isotherms model and both models were found suitable for explaining the metal ions adsorption on APS-EDTA. The adsorption data were followed pseudo second order reaction kinetics. The maximum adsorption capacity obtained 1.3037-1.4974 mg/g for above said metal ions. The results show that APS-EDTA have great potential to remove Cd(II), Co(II), Cs(I), Ni(II) and Sr(II) from aqueous solutions through chemisorption and physio-sorption.

Development of Wafer Cleaning Equipment Using Nano Bubble and Megasonic Ultrasound (나노 버블과 메가소닉 초음파를 이용한 반도체 웨이퍼 세정장치 개발)

  • Nohyu Kim;Sang Hoon Lee;Sang Yoon;Yong-Rae Jung
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.4
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    • pp.66-71
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    • 2023
  • This paper describes a hybrid cleaning method of silicon wafer combining nano-bubble and ultrasound to remove sub-micron particles and contaminants with minimal damage to the wafer surface. In the megasonic cleaning process of semiconductor manufacturing, the cavitation induced by ultrasound can oscillate and collapse violently often with re-entrant jet formation leading to surface damage. The smaller size of cavitation bubbles leads to more stable oscillations with more thermal and viscous damping, thus to less erosive surface cleaning. In this study, ultrasonic energy was applied to the wafer surface in the DI water to excite nano-bubbles at resonance to remove contaminant particles from the surface. A patented nano-bubble generator was developed for the generation of nano-bubbles with concentration of 1×109 bubbles/ml and nominal nano-bubble diameter of 150 nm. Ultrasonic nano-bubble technology improved a contaminant removal efficiency more than 97% for artificial nano-sized particles of alumina and Latex with significant reduction in cleaning time without damage to the wafer surface.

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The Production of Metal-biochar through Co-pyrolysis of Lignin and Red Mud and Utilization for the Removal of Contaminants in the Water (리그닌과 적니의 공동 열분해를 통한 금속-바이오차 생산 및 수중 오염물질 제거를 위한 활용)

  • Kim Eunji;Kim Naeun;Park Juyeong;Lee Heuiyun;Yoon Kwangsuk
    • Journal of Soil and Groundwater Environment
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    • v.29 no.2
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    • pp.1-10
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    • 2024
  • With industrial development, the inevitable increase in both organic and inorganic waste necessitates the exploration of waste treatment and utilization methods. This study focuses on co-pyrolyzing lignin and red mud to generate metalbiochar, aiming to demonstrate their potential as effective adsorbents for water pollutant removal. Thermogravimetric analysis revealed mass loss of lignin below 660℃, with additional mass loss occurring (>660℃) due to the phase change of metals (i.e., Fe) in red mud. Characterization of the metal-biochar indicated porous structure embedded with zero-valent iron/magnetite and specific functional groups. The adsorption experiments with 2,4-dichlorophenol and Cd(II) revealed the removal efficiency of the two pollutants reached its maximum at the initial pH of 2.8. These findings suggest that copyrolysis of lignin and red mud can transform waste into valuable materials, serving as effective adsorbents for diverse water pollutants.

Characteristics of Heavy Metals (Ba, Cr) Distribution in Soil (토양 중 중금속(Ba, Cr)의 분포특성 평가)

  • Yoon, Jeong-Ki;Kim, Rog-Young;Kim, Ji In;Noh, Hoe-Jung;Yu, Soon-Ju;Kim, Tae Seung;Lee, Myung Gyu;Yun, Dae-Geun;Lee, Hong-gil;Kim, In Ja;Park, Gyoung-Hun
    • Journal of Soil and Groundwater Environment
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    • v.20 no.7
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    • pp.61-69
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    • 2015
  • This study was performed to provide fundamental data to establish the new soil pollution standards and the soil contamination management plans in a rational manner. The distribution characteristics of new soil contaminants such as barium (Ba) and chromium (Cr) in soils (n=140) were investigated in relation to land-use classification and geological features. Also, the sequential extraction test was conducted to evaluate fate and mobility of new soil contaminants. The soil samples taken from 140 sites were analyzed to survey distribution levels of selected new soil contaminants. The average concentration and range for hazardous metals (Ba, Cr) were Ba 128.946 (26.757~489.587) mg/kg, Cr 30.121 (2.579~132.783) mg/kg. Based on land use classification, the highest Ba concentration was found in factory soils, followed by dry field and park soils, while Cr concentration was highest in rice paddy soils, followed by dry field and factory soils. Within 10 geological units investigated the highest Ba and Cr concentrations were observed in the soils from Okcheon group and metamorphic rocks, respectively. The BCR (European Community Bureau of Reference) sequential extraction was conducted to identify chemical distributional existence of 2 elements of soils from each geological unit. Ba in soils is mainly assumed to exists as reducible form (such as BaSO4, BaCO3) and Cr in soils mainly is assumed to exist as residual form (such as Cr2O3, CrxFe1-x(OH)3(x < 1)).

Study on the Amendment of Standard Regulations of Food Additives and Contaminants for Infant Formulas in Korea (우리나라 영.유아용 조제식의 식품첨가물과 오염물질 기준 개선방안 연구)

  • Moon, Ji-Hea;Lee, Heon-Ok;Shim, Jae-Young;Kim, In-Hye;Shin, Hye-Seoung;Won, Sun-Im;Paik, Min-Kyoung;Shin, Hyoung-Soo;Om, Ae-Son
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.9
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    • pp.1214-1221
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    • 2008
  • The aim of this study is to propose suggestions for establishing Korean regulatory standards of infant formula. Accordingly, the regulatory standards for food contaminants and additives in Korean infant formulas were compared and analyzed with those in CODEX, EU, Australia and New Zealand. Several suggestions for regulations were found from different countries. Firstly, it is advisable that additives for nutrient supplement of infant formula be classified as types of nutrients. Secondly, it is proposed that guidelines should be set on the maximum amount of additives in infant formula. Thirdly, pathogens such as Staphylococci and Salmonella of infant formula should be regulated. Finally, present regulations need to establish the maximum permissible levels of some pesticides, Pb and Al, that other countries are already regulating. These proposed recommendations would broaden the scope of infant formula regulatory standards needed for infants' health.

Oxidative-Coupling Reaction of Aromatic Compounds by Mn Oxide and Its Application for Contaminated Soil Remediation (망간산화물에 의한 방향족 유기화합물의 산화-공유결합반응 및 이를 이용한 오염토양 정화기법)

  • Kang, Ki-Hoon;Shin, Hyun-Sang;Nam, Kyoung-Phile
    • Journal of Soil and Groundwater Environment
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    • v.12 no.5
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    • pp.115-123
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    • 2007
  • Immobilization of contaminants in subsurface environment is one of the major processes that determine their fate. Especially, immobilization by oxidative-coupling reactions, which is irreversible in the bio-chemical reactions and results in a significant reduction of toxicity, can be successfully applied for the remediation of contaminated soil and groundwater more effectively than conventional degradation. As a catalyst of this oxidative-coupling reaction, manganese oxide has many advantages in practical aspects as compared to microorganisms or oxidoreductive enzymes extracted from microorganisms, fungi, or plants. This paper is to present recent research achievements on the treatment mechanisms of various organic contaminants by manganese oxide. Especially, treatment methods of non-reactive organic compounds to Mn oxide are the main focus; i.e., application of reaction mediator, PAHs treatment method, combination with an appropriate pretreatment such as reduction using $Fe^0$, which suggests the potential of a wide range of engineering application. Concerning the natural carbon cycle processes, immobilization and stabilization by oxidative coupling reaction can be effectively applied as a environmentally-friend remediation method especially for aromatic contaminants which possess a high resistance to degradation.

Effect of Aflatoxin on Feed Conversion Ratio in Broilers: A Meta-analysis

  • Suganthi, R. Umaya;Suresh, K.P.;Parvatham, R.
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.12
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    • pp.1757-1762
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    • 2011
  • Aflatoxins are natural contaminants of poultry feeds and feed ingredients and cause liver damage, immunosuppression, reduction in performance and mortality in broilers. A number of studies have been carried out to study the effects of aflatoxin on feed conversion ratio in broilers. The results on feed conversion ratio of 10 research articles in broilers fed with aflatoxin from first day of age to six weeks of age were compiled and were subjected to meta-analysis. Chi-square test and $Tau^2$ (heterogeneity co-efficient) were applied to test for significance of heterogeneity of studies. To integrate results, fixed effect model by Inverse Variance method (IV method) was used when heterogeneity was insignificant and otherwise random effect model by DerSimonian and Laird Method (DL method) was used. The results of meta-analysis showed that the adverse effect of aflatoxin on feed conversion ratio at the end of first week was negligible, second week was medium and third to six weeks was very large.

A Study On Heavy Metal Contamination in the Different Size Fractions of Deposited Road Particles(DRPs) (노면퇴적물의 입자 크기에 따른 중금속 오염에 관한 연구)

  • Kim, Boo-Gil;Lee, Byung-Cheol
    • Journal of Environmental Science International
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    • v.15 no.12
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    • pp.1171-1175
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    • 2006
  • Deposited road particles (DRPs) were analysed for heavy metal concentrations at four different roads in a city, Korea. The samples were collected using a roadway surface vacuum cleaning vehicle which was commonly used in collecting roadway surface particles. Six particle size ranges were analyzed separately for twelve heavy metal elements (Cd, Cr, Pb, Ni, Al, As, Co, Cu, Fe, Mn, Zn and Hg). At all sampling sites, the high concentration of the heavy metals occurred in the <74um particle size range, which conventional roadway cleaning vehicles do not remove efficiently. The Pb concentration significantly increased with decreasing particle size of DRPs, and other toxic heavy metals (Cd, Cr and Ni) also showed similar results. The heavy metal concentrations in the smaller size fraction of DRPs is important because they are contaminants that are preferentially transported by road runoff during rainfall.

A Study on the Water Pollution of Mountain Wells and Mineral Wells around Seoul Area (서울근교(近郊)의 산악수(山岳水) 및 약수(藥水)에 관(關)한 연구(硏究))

  • Park, Yang-Won;Lee, Pyong-Kap;Kim, Hyung-Suk;Park, Soon-Young
    • Journal of Preventive Medicine and Public Health
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    • v.5 no.1
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    • pp.37-42
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    • 1972
  • Mountain Wells are very important water source for the most of the climbers in Seoul area. But the facilities around the wells are not modernized to prevent from contamination of microorganism and the other pollutants. We focussed our intention on the detection of some harmful chemical ingredients and contaminants. A total of 58 wells were examined according to the Standard Methods(APHA) and the following results were obtained: 1) Among the examined 58 wells, only 10 wells were adequate to the drinking water standard, 2) 7.9mg of liberated $CO_2$ was found in the Tchun-Ho-Dong Mineral Well, 3) Chemically harmful ingredients were not found, 4) The Mountain Wells were contaminated by Coliform groups as many as 18 times than rural wells.

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