• Title/Summary/Keyword: Co-Cr alloys

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Evaluation of Breaking Performance of New Contact Material for the Vacuum Interrupter (진공인터럽터용 신규 접점소재에 대한 차단 성능 평가)

  • Cha, Young-Kwang;Lee, Il-Hoi;Ju, Heung-Jin;Shin, Tae-Yong;Park, Kyong-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.1
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    • pp.50-55
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    • 2021
  • Copper-chromium alloys have been used as contact materials of vacuum interrupters in circuit breakers, but new materials with highly stable performance are required to break the high voltage and high current barrier due to the recent increase in breaking capacity. In this paper, a new contact material was fabricated from a ternary alloy instead of existing Cu-Cr alloys. Its breaking performance and endurance were verified from a synthetic test and compared with that of various contact materials. The test results verified that the breaking performance of the new contact material was excellent.

The effect of substitution elements(Co, Cr, Fe) on the properties of Zr-based hydrogen storage alloy electrode for Ni-MH secondary battery (Ni-MH 2차 전지용 Zr계 수소저장합금전극의 특성에 미치는 치환원소(Co, Cr, Fe)의 영향)

  • Choi, Seung-Jun;Jung, So-Yi;Seo, Chan-Yeol;Choi, Jeon;Park, Choong-Nyeon
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.3
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    • pp.185-189
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    • 1999
  • Effects of alloy modification with the $Zr_{0.6}Ti_{0.4}V_{0.4}Ni_{1.2}Mn_{0.4}$ alloy for an electrode use have been investigated. For the alloy composition, a part of Mn was substituted by Co, Cr and Fe. The experimental results showed that Co accelerated activation of alloy, and Fe and Cr improved the discharge capacity. These results agree with P-C-T curves of each alloy. But substituting Fe for Mn showed the decrease of the discharge capacity when discharged at high rate (60mA, about 1C rate). Considering both the discharge capacity and the high rate discharge property, $Zr_{0.6}Ti_{0.4}V_{0.4}Ni_{1.2}Mn_{0.3}Cr_{0.1}$ alloy was found to be the best alloy among the alloys subjected to the test.

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Structural and Magnetic Properties of Epitaxial FexCo100-x Alloys Grown on Cr Substrate

  • Hossain, M.B.;Kim, C.G.;Chun, B.S.;Kim, W.D.;Hwang, C.
    • Journal of Magnetics
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    • v.19 no.1
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    • pp.1-4
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    • 2014
  • We report the correlation between the magnetic properties and lattice parameter of $Fe_xCo_{100-x}$ alloys as a function of constituent concentration. The saturation magnetization increases with Fe content and has a maximum value at approximately x=70 at.%. However, collapse in relative saturation magnetization is observed at approximately 30 at.% to 70 at.% of Fe in $Fe_xCo_{100-x}$ alloys. The collapse is due to the formation of Co-Co and Fe-Fe antibonding states instead of Fe-Co bonds. The lattice parameter also shrinks at approximately 30 at.% to 70 at.% of Fe. This shrinkage is due to an increase in the number of nearest neighbor antisite atoms, which then leads to a decrease in the long range order parameter.

Evaluation of shear bond strength of repair acrylic resin to Co-Cr alloy

  • Kulunk, Safak;Kulunk, Tolga;Sarac, Duygu;Cengiz, Seda;Baba, Seniha
    • The Journal of Advanced Prosthodontics
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    • v.6 no.4
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    • pp.272-277
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    • 2014
  • PURPOSE. The purpose of this study was to investigate the impact of different surface treatment methods and thermal ageing on the bond strength of autopolymerizing acrylic resin to Co-Cr. MATERIALS AND METHODS. Co-Cr alloy specimens were divided into five groups according to the surface conditioning methods. C: No treatment; SP: flamed with the Silano-Pen device; K: airborne particle abrasion with $Al_2O_3$; Co: airborne particle abrasion with silica-coated $Al_2O_3$; KSP: flamed with the Silano-Pen device after the group K experimental protocol. Then, autopolymerized acrylic resin was applied to the treated specimen surfaces. All the groups were divided into two subgroups with the thermal cycle and water storage to determine the durability of the bond. The bond strength test was applied in an universal test machine and treated Co-Cr alloys were analyzed by scanning electron microscope (SEM). Two-way analysis of variance (ANOVA) was used to determine the significant differences among surface treatments and thermocycling. Their interactons were followed by a multiple comparison' test performed uing a post hoc Tukey HSD test (${\alpha}=.05$). RESULTS. Surface treatments significantly increased repair strengths of repair resin to Co-Cr alloy. The repair strengths of Group K, and Co significantly decreased after 6,000 cycles (P<.001). CONCLUSION. Thermocycling lead to a significant decrease in shear bond strength for air abrasion with silica-coated aluminum oxide particles. On the contrary, flaming with Silano-Pen did not cause a significant reduction in adhesion after thermocycling.

Corrosion Behavior of Superalloys in Hot Molten Salt under Oxidation Atmosphere (고온용융염계 산화분위기에서 초합금의 부식거동)

  • 조수행;임종호;정준호;이원경;오승철;박성원
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.285-291
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    • 2004
  • As a part of assessment of the structural material for the molten salt handling system, corrosion behavior of Inconel 718, X-750, Haynes 75 and Haynes 263 alloys in the molten salt of LiCl-Li$_2$O-O$_2$was investigated in the range of temperature; $650^{\circ}C$, time; 24~168h, $Li_2O$; 3wt%, mixed gas; Ar~10%$O_2$. In the molten salt of LiCl-$Li_2O-O_2$, the order corrosion rate was Haynes 263 < Haynes 75 < Inconel X-750 < Inconel 718. Haynes 263 alloy showed the highest corrosion resistance among the examined alloys. Corrosion products of alloys were as fellows: Haynes 75: $Cr_2O_4$, $NiFe_2O_4$, $LiNiO_2$, $Li_2NiFe_2O_4$, Inconel 718; $Cr_2O_4$, $NiFe_2O_4$, Haynes 263; $Li(Ni,Co)O_2$, $NiCr_2O_4$, $LiTiO_2$, Inconel X-750; $Cr_2O_3$, $NiFe_2O_4$,$FeNi_3$, (Al,Nb,Ti)$O_2$. Haynes 263 showed local corrosion behavior and Haynes 75, Inconel 718 and Inconel X-750 showed uniform corrosion behavior.

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Effect of polishing solution temperature and times by electro-polishing in dental casting Co-Cr-Mo alloy (치과 주조용 Co-Cr-Mo alloy에서 전해용액 온도와 전해시간에 따른 전해연마의 특성)

  • Jang, Jae-Young;Song, Jae-Sang;Nah, Jung-Sook
    • Journal of Technologic Dentistry
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    • v.34 no.2
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    • pp.145-153
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    • 2012
  • Purpose: The purpose of this study was to investigate to effect of the electro-polishing condition according to electrolyte temperature and current and polishing time on surface morphology and composition by scanning electron microscopy(SEM) and energy dispersive X-ray spectrometer(EDS) in dental casting Co-Cr-Mo alloys. Methods: 16 specimens were divided into 4 groups which have each 4 specimens. The size of specimens were 10mm wide and 5mm height. the electro-polishing of specimens are by polishing solution temperature and times in Co-Cr-Mo alloy by SEM and EDS analysis. Results: The results shows that most smooth surface is obtained when electro-polishing is performed at $49^{\circ}C$ for 30-40sec with electro gap of 10mm and 8 voltage. Conclusion: The morphologies of specimens after electro-polishing were scratch absent and significant between at $40^{\circ}C$ for 45sec and at $49^{\circ}C$ for 45sec.

Effect of Annealing Temperature on the Microstructure and Mechanical Properties of CoCrFeMnNi High Entropy Alloy (CoCrFeMnNi 고엔트로피 합금에서 어닐링 온도가 미세조직 및 기계적 특성에 미치는 영향)

  • Junseok Lee;Tae Hyeong Kim;Jae Wung Bae
    • Journal of the Korean Society for Heat Treatment
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    • v.37 no.2
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    • pp.58-65
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    • 2024
  • In the present study, the effect of annealing condition on the microstructures and mechanical properties of the cold-rolled CoCrFeMnNi high entropy alloys were studied. Annealing treatment was performed under six different temperatures. Microstructural analyses confirmed that annealing below 800℃ resulted in the formation of intermetallic sigma (σ) phase within face-centered cubic (FCC) matrix, and this σ phase has beneficial effects on the formation of fine-grained structures through retardation of grain growth and recrystallization due to Zener pinning effect. This led to the enhanced yield strength and tensile strength of ~646 and ~855 MPa, respectively. The microstructures annealed above 800℃ demonstrated single FCC phase, and fully-recrystallized single FCC microstructure resulted in a slight increase in ductility with a considerable decrease in strength. The evolution of mechanical properties, such as strength, ductility, and strain hardening exponent, will be discussed.

Annealing Effect on the Mechanical Properties of Hot-Rolled Fe55Co17.5Ni10Cr12.5Mo5 High-Entropy Alloy (열간압연 된 Fe55Co17.5Ni10Cr12.5Mo5 고엔트로피합금의 소둔 조건에 따른 기계적 특성 변화)

  • Park, H.D.;Bae, D.H.;Won, J.W.;Moon, J.;Kim, H.S.;Seol, J.B.;Sung, H.;Bae, J.W.;Kim, J.G.
    • Transactions of Materials Processing
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    • v.31 no.5
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    • pp.273-280
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    • 2022
  • Although the mechanical properties of high-entropy alloys depend on the annealing conditions, limited works were established to investigate the annealing effect on the mechanical properties of Mo-added high-entropy alloys. Therefore, in the present work, the annealing effects on the microstructural evolution and mechanical properties of Mo-added high-entropy alloy were investigated. As a result, incomplete recrystallization from the limited annealing time not only suppresses deformation-induced phase transformation during cryogenic tensile test but also induces a deformation instability that results into the ductility reduction compare with the fully recrystallized sample. This result represents adjustment of annealing time is useful to control both transformation-induce plasticity and deformation instability of high-entropy alloys, and this can be applied to control the mechanical properties of metallic alloys by combining pre-straining and subsequent annealing.

Anodic Polarization Properties of Ti-Zr-Pd Based Alloys for Biomedical Applications (생체용 Ti-Zr-Pd계 합금의 양극분극특성)

  • Jung, Jong-Hyun
    • Journal of Technologic Dentistry
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    • v.23 no.1
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    • pp.21-30
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    • 2001
  • For biomedical applications. Ti-X%Zr-Y%Pd(X: $10{\sim}20$, Y:0.2 or 0.4) based alloys not containing harmful Al and V were newly designed, and polarization curves for their alloys were measured at $37^{\circ}C$ in 5% HCl solution in order to understand effects of Zr on the corrosion. From the results of anodic polarization behavior, it was found that the corrosion resistance increased with increasing Zr content. The results show their potential to develope Ti-based alloys for biomedical materials. The Ti-20%Zr-0.2%Pd alloy shows excellent corrosion resistance and was superior to those of the Ti. Ti-6%Al-4%V ELI alloy, Co-30%Cr-6%Mo alloy and STS 316L stainless steel.

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Corrosion characteristics of separator for MCFC (용융탄산염형 연료전지의 분리판 부식특성)

  • Kim, G.Y.;Eom, S.W.;Moon, S.I.;Moon, G.H.;Choi, Y.T.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1407-1408
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    • 1996
  • The development of MCFC is going to the second stage of development and recent studies have been focusing on long-term durability of cell component. Systematic investigation on corrosion behavior of Fe-based alloys has been done in (62+38) mol % (Li+K) $CO_3$ melt at 923K by using steady-state polarization and electrochemical impedance spectroscopy method. It was found that the corrosion current t of these Fe-based alloys decreased with increasing Cr, Al content.

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