• Clean Technology
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• v.28 no.4
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• pp.316-322
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• 2022

The flow pattern at the inlet of the catalyst layer in a selective catalytic reduction (SCR) system is one of the key parameters influencing the performance of the denitrification process. In the curved diffusing parts between the ammonia injection grids and the catalyst layers, guide vanes are installed to improve flow uniformity. In the present study, a numerical simulation has been performed to investigate the effect of the geometrical configuration of the guide vanes on the aerodynamic characteristics of a denitrification facility. This application has been made to the existing SCR process in a large-scaled coal-fired power plant. The flow domain to be solved covers the whole region of the flow passages from the exit of the ammonia injection gun to the exit of the catalyst layers. ANSYS-Fluent was used to calculate the three-dimensional steady viscous flow fields with the proper turbulence model fitted to the flow characteristics. The root mean square of velocity and the pressure drop inside the flow passages were chosen as the key performance parameters. Four types of guides vanes were proposed to improve the flow quality compared to the current configuration. The numerical results showed that the type 4 configuration was the most effective at improving the aerodynamic performance in terms of flow uniformity and pressure loss.

• Applied Chemistry for Engineering
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• v.17 no.2
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• pp.125-131
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• 2006

Dimethyl ether (DME) is a new clean fuel as an environmentally-benign energy resource. DME can be manufactured from various energy sources including natural gas, coal, biomass and spent plastic. In addition to its environmentally friendly properties, DME has similar characteristics to those of LPG. Therefore, it is considered as an excellent substitute fuel for LPG, fuel cells, power plant, and especially diesel and is expected to be the alternative fuel by 2010. The experimental study of the direct synthesis of DME was investigated under various conditions over a temperature range of $220{\sim}280^{\circ}C$, syngas ratio 1.2~3.0. All experiments were carried out with a hybrid catalyst, composed of a methanol synthesis catalyst ($Cu/ZnO/Al_2O_3$) and a dehydration catalyst (${\gamma}-Al_2O_3$). The observed reaction rate follows qualitatively a Langmiur-Hinshellwood model as the reaction mechanism. Such a mechanism is considered with three reactions; methanol synthesis, methanol dehydration and water gas shift reaction. From a surface reaction with dissociative adsorption of hydrogen, methanol, and water, individual reaction rate was determined.

• Korean Journal of Materials Research
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• v.22 no.2
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• pp.71-77
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• 2012

When a new bonding agent using coal ash is utilized as a substitute for cement, it has the advantages of offering a reduction in the generation of carbon dioxide and securing the initial mechanical strength such that the agent has attracted strong interest from recycling and eco-friendly construction industries. This study aims to establish the production conditions of new hardening materials using clean bottom ash and an alkali activation process to evaluate the characteristics of newly manufactured hardening materials. The alkali activator for the compression process uses a NaOH solution. This study concentrated on strength development according to the concentration of the NaOH solution, the curing temperature, and the curing time. The highest compressive strength of a compressed body appeared at 61.24MPa after curing at $60^{\circ}C$ for 28 days. This result indicates that a higher curing temperature is required to obtain a higher strength body. Also, the degree of geopolymerization was examined using a scanning electron microscope, revealing a micro-structure consisting of a glass-like matrix and crystalized grains. The microstructures generated from the activation reaction of sodium hydroxide were widely distributed in terms of the factors that exercise an effect on the compressive strength of the geopolymer hardening bodies. The Si/Al ratio of the geopolymer having the maximum strength was about 2.41.

• Transactions of the Korean Society of Automotive Engineers
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• v.18 no.5
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• pp.115-123
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• 2010

Cool-down performance after soaking is important because it affects passenger's thermal comfort. The cooling capacity of HVAC system determines initial cool down performance in most cases, the performance is also affected by location, and shape of panel vent, indoor seat arrangement. Therefore, optimal indoor designs are required in developing a new car. In this paper, initial cool down performance is predicted by CFD(computational fluid dynamics) analysis. Experimental time-averaging temperature data are used as inlet boundary condition. For more reliable analysis, real vehicle model and human FE model are used in grid generation procedure. Thermal and aerodynamic characteristics on re-circulation cool vent mode are investigated using CFX 12.0. Thermal comfort represented by PMV(predicted mean vote) is evaluated using acquired numerical data. Temperature and velocity fields show that flow in passenger's compartment after soaking is considerably unstable at the view point of thermodynamics. Volume-averaged temperature is decreased exponentially during overall cool down process. However, temperature monitored at different 16 spots in CFX-Solver shows local variation in head, chest, knee, foot. The cooling speed at the head and chest nearby panel vent are relatively faster than at the knee and foot. Horizontal temperature contour shows asymmetric distribution because of the location of exhaust vent. By evaluating the passenger's thermal comfort, slowest cooling region is found at the driver's seat.

• Journal of Energy Engineering
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• v.13 no.1
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• pp.75-81
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• 2004

ZZFCa sorbents for hot gas desulfurization in IGCC were prepared by adding calcium oxide to ZZF sorbent in order to improve its attrition resistance in this study. ASTM attrition test for the sorbent was performed at several different weight percentages of CaO to investigate the attrition characteristics of ZBFCa sorbents as a function of CaO content. Attrition index of ZZF without CaO was 28.3% and its collected attrition index was 10.8％. ZZFCa-3 containing 3 wt% CaO showed the lowest attrition index (AI=17.3％, CAI=8.8％) in the test. From the results of SEM morphologies and particle size distribution measurements, ZZFCa-3 maintained a fine shape and a desirable average particle size even after attrition test. In the experiments of sulfidation/regeneration for ZZFCa-3 sorbent concentration of hydrogen sulfide in coal gas was lowered from 10000 ppm to below 1 ppm. Sulfur removing capacity was about 28.8 g S/100 g sorbent. Neither formation of CaSO$_4$ was observed in XRD measurement nor SO$_2$ slippage was observed during sulfidation process.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.1
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• pp.53-61
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• 2006

Recently, lots of researchers have been attracted to develop various alternative fuels and to use renewable fuels in order to solve the exhaust emission problems. DME (Dimethylether) is synthetic fuel, and can be produced from natural gas, coal and biomass. The emission is clean because it contains little sulfur and aromatic components In this study, the fuel was tested to investigate the applicability as an alternative fuel for diesel. This study was carried out by comparing the exhaust emissions and performance of diesel engine with DME, ULSD (ultra low sulfur diesel), LSD (low sulfur diesel) respectively. In order to measure regulated emissions, CO, $NO_{3}$, HC from vehicle different fuel types were used on chassis dynamometer CVS (constant volume sampler)-75 mode and EPA TO-I1A method was chosen for aldehydes analysis.

• Journal of Energy Engineering
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• v.26 no.2
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• pp.23-31
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• 2017

Numerical study was conducted for the effects of various burner array on the workpiece and the gas temperature in a continuos reheating furnace. Under the same conditions which were the total heat of combustion, the heat capacity of unit burner, the number of burner and burner array were changed to be applied the furnace. The behavior of workpiece temperature and gas temperature in a furnace were evaluated for the effects as function of the changed conditions. A continuous reheating furnace designed for 110 tons/day of production capacity was applied in this study. The furnace which has several gas burners is designed to heat a workpiece. By this study, the better condition was confirmed than the existing designed condition.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.4
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• pp.483-491
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• 2008

The filtration characteristics of $CYBAGFILTER^{(R)}$ unit with pleated filter bags were evaluated by comparing the performance of the unit with the lower part of cyclone shape with that of the unit with conventional lower part. Results from the test were also compared with those from the previous research with the $CYBAGFILTER^{(R)}$ in which round filter bags were installed. $CYBAGFILTER^{(R)}$ is the unit which combines the centrifugal separation mechanism and the fabric filtration mechanism in a single unit for efficient removal of particulate matters. The pleated filter bags are made of pleated fabric with an extension of the filtration area about 3 times compared with the conventional round filter bags. The results from the test using pleated filter bags showed an overall collection efficiency of over 99.9% regardless of the shape of lower part installed. When the lower part of cyclone shape was installed, the filter cleaning interval was over 2 times longer compared with that when the conventional lower part was installed. At the same conditions of filtration velocity and filter pressure drop, the $CYBAGFILTER^{(R)}$ with the lower part of cyclone shape, in which the pleated filter bags are installed, can be operated with a flow rate of round 3 times higher than that with conventional round filter bags.

• Journal of the Korean Professional Engineers Association
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• v.28 no.4
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• pp.14-20
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• 1995

Discourses on global environment are not only limited to the matter of simple environmen-tal protection but also going to an imperative that every country should take the environ-mental aspects into more consideration, and if necessary even proceed to modify its own strategies for economic growth. It is because scores of existing International conventions and agreements on environmental caused tend to combine the environmental issues with trade sanctions and financial assistances in order to ensure a mandatory power in pushing themselves through on a global dimension. Particularly noteworthy is the so -called Green Round(GR) which substantially associates the Issues of environmental protection with some sanctions in international trade, its rationale is quite simple. The differentiated production costs rising from the difference in environmental standards among different countries may affect national competitiveness in in-ternational trade, therefore a need does exist to countervail this difference. In reality, however, severe dissention seems to have been exposed between the developed and developing countries around this matter, because national interests and priorities in national goals considerably differ among respective countries. Greenhouse gases such as carbon dioxide which caused global warming are mostly released from the combustion of fossil fuels. The perfect removal of released $CO_{2}$ is impossible with existing technologies, and moreover, it's not payable in economical terms. Therefore it will be more effective and desirable to make more efforts to prevent the release of the $CO_{2}$ it- self through energy conservation involving the development and promotion of clean and high-efficient energy technologies and energy sources, and the development and promotion of new & renewable energy resources, and so on. One of important national tasks In our country is to establish an Energy Policy consider-ing environmental impacts since Korea depends most of its energy consumption on the fossil fuels such as oil and coal.

• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.473-478
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• 2008

In this experimental, selective catalytic reduction (SCR) of NO with NH3 over manganese sulfates and manganese sulfates was investigated with catalytic activity, kinetics, temperature programmed reduction (TPR) and TGA. Manganese oxides showed high catalytic activity for SCR at temperature below $200^{\circ}C$. In case of manganese sulfates, the temperature at which SCR of nitric oxide appears shifted to high temperature with sulfation degree, and the maximum catalytic efficiency decreased. The temperature of the onset of reduction for manganese oxides and manganese sulfates is about $160^{\circ}C$ and over $280^{\circ}C$, respectively. We suggest that the onset of reduction in TPR correlates with the onset of SCR activity. Because the pre-exponential factor of manganese sulfates is lower as 1/1000 times than that of other catalysts, catalytic activity of manganese sulfates for NO showed low. The reduction temperature of natural manganese ore which consists of various metal oxides showed lower than that of pure manganese oxides.